phenyl N-ethyl-N-phenylcarbamate | 17671-34-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl N-ethyl-N-phenylcarbamate
• CAS: 17671-34-0
• 化学式: C₁₅H₁₅NO₂
• mdl: MFCD00591817
• 分子量: 241.29
• InChiKey: PWRPYSIEWHRXDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.133
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  氯甲酸苯酯 、 N,N-二乙基苯胺 在 [bmim]Cl 作用下， 反应 24.0h， 以99%的产率得到phenyl N-ethyl-N-phenylcarbamate
  参考文献：
  名称：

  Efficient Demethylation of N,N-Dimethylanilines with Phenyl Chloroformate in Ionic Liquids

  摘要：

  我们在各种离子液体、乙腈以及无溶剂条件下对 N,N-二甲基苯胺进行了脱甲基化反应。我们已经证明，它们的反应活性极大地取决于所使用的离子液体；[bmim]Cl 显示出最佳的反应活性。

  DOI：

  10.1055/s-2006-951490

文献信息

• Burn rate modifier
  申请人：Thales Australia Limited

  公开号：US10087116B2

  公开（公告）日：2018-10-02

  The invention relates generally to burn rate modifiers, plasticizers and propellants comprising a burn rate modifier and/or a plasticizer. The invention also relates to methods of producing a propellant comprising a burn rate modifier and/or a plasticizer as well as an ammunition cartridge comprising the propellant. The burn rate modifier and/or plasticiser comprises a compound of formula (1) (Formula (1)) and the propellant comprises a compound of formula 1 and an energetic material.

  本发明一般涉及燃烧速率调节剂、增塑剂和包含燃烧速率调节剂和/或增塑剂的推进剂。本发明还涉及生产包含燃烧速率改性剂和/或增塑剂的推进剂以及包含该推进剂的弹药筒的方法。燃速改性剂和/或增塑剂包括式(1)化合物(式(1))，推进剂包括式1化合物和高能材料。
• BURN RATE MODIFIER
  申请人：Thales Australia Limited

  公开号：EP3044190A1

  公开（公告）日：2016-07-20
• Method for producing a funtional, high-energy material
  申请人：Ryf Kurt

  公开号：US20090208647A1

  公开（公告）日：2009-08-20

  The method for producing a propellant powder (TLP) with a layered grain structure starts with a green powder, which is impregnated in a watery emulsion with an energetic plasticizer and a polymeric deterrent. Propellant powders (TLP) can be produced in industrial quantities by avoiding the dangerous direct introduction of a blasting oil. The propellant powders (TLP) produced in this way have similar characteristics and a similar structure as the known propellant powders (TLP).
• Propulsion system for the acceleration of projectiles
  申请人：Schaedeli Ulrich

  公开号：US20120138201A1

  公开（公告）日：2012-06-07

  The propulsion system for the acceleration of projectiles is based on nitrocellulose and contains a crystalline energy carrier on a nitramine base and an inert plasticising additive. The nitramine compound contains a structural element of the general chemical structure formula R—N—NO 2 , where R is a residual. The nitramine compound is present in a concentration in the range from 1 to 35% by weight, in particular in the range from 5 to 25% by weight. The nitramine compound is preferably RDX. The inert plasticising additive is a water-insoluble polyoxo compound, if necessary in combination with a substance containing carboxyl groups. In layers near the surface an increased concentration can be present. The inert plasticising additive is present in a concentration of 1 to 5% by weight.
• PROPELLANT STABILIZER
  申请人：Thales Australia Limited

  公开号：US20190210938A1

  公开（公告）日：2019-07-11

  The invention relates generally to propellant stabilizers. The invention also relates to methods of producing a propellant comprising a propellant stabilizer as well as an ammunition cartridge comprising the stabilized propellant. The propellant stabilizer comprises a compound of formula 1 and the propellant comprises a compound of formula 1 and an energetic material.