(fluoren-9-ylidenel)isopropylamine | 64605-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: (fluoren-9-ylidenel)isopropylamine
• 英文别名: (fluoren-9-ylidene)isopropylamine；N-Isopropylfluorenimin；N-propan-2-ylfluoren-9-imine
• CAS: 64605-47-6
• 化学式: C₁₆H₁₅N
• 分子量: 221.302
• InChiKey: IDKGSGWRXWHPTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (fluoren-9-ylidenel)isopropylamine 在 间氯过氧苯甲酸 作用下， 以 氘代甲醇 为溶剂， 反应 2.0h， 以100%的产率得到2'-Propan-2-ylspiro[fluorene-9,3'-oxaziridine]
  参考文献：
  名称：

  Boyd, Derek R.; Coulter, Peter B.; McGuckin, M. Rosaleen, Journal of the Chemical Society. Perkin transactions I, 1990, # 2, p. 301 - 306

  摘要：

  DOI：

文献信息

• Fluorenylidene−Pyrroline Biomimetic Light-Driven Molecular Switches
  作者：Laura Rivado-Casas、Diego Sampedro、Pedro J. Campos、Stefania Fusi、Vinicio Zanirato、Massimo Olivucci

  DOI：10.1021/jo802792j

  日期：2009.7.3

  A new family of biomimetic photoactivated molecular switches based in the retinal chromophore is described. Expedient synthesis allows a library of compounds with a different substitution pattern, including chiral substituents, to be obtained. The effect of substitution, solvent, and light source on the photoisomerization step has been assessed. The absorption maximum has been red-shifted ca. 50 nm with respect to related systems and rotation is now easily achieved by using visible light.
• Normal, abnormal and pseudo-abnormal reaction pathways for the imine-peroxyacid reaction
  作者：Derek R. Boyd、Peter B. Coulter、Narain D. Sharma、W.Brian Jennings、Valerie E. Wilson

  DOI：10.1016/s0040-4039(00)98582-4

  日期：1985.1
• Mesoionic Pyrrolium Complexes and Dihydropyrroles by Cycloaddition of (Non-enolizable) Imines to an [(1-Alkynyl)carbene]tungsten Complex
  作者：Rudolf Aumann、Zhengkun Yu、Roland Fröhlich、Frank Zippel

  DOI：10.1002/(sici)1099-0682(199811)1998:11<1623::aid-ejic1623>3.0.co;2-p

  日期：1998.11
• BOYD, D. R.;COULTER, P. B.;SHARMA, NARAIN, D.;JENNINGS, W. B.;WILSON, V. +, TETRAHEDRON LETT., 1985, 26, N 13, 1673-1676
  作者：BOYD, D. R.、COULTER, P. B.、SHARMA, NARAIN, D.、JENNINGS, W. B.、WILSON, V. +

  DOI：——

  日期：——
• PHOTOACID GENERATOR COMPOUNDS AND COMPOSITIONS
  申请人：Ober Christopher K.

  公开号：US20090258315A1

  公开（公告）日：2009-10-15

  The invention provides various photoacid generator compounds and ionic components thereof. Photoresist compositions that include the ions and non-ionic photoacid generator compounds are also provided. The invention further provides methods of making and using the photoacid generator compounds and photoresist compositions disclosed herein. The compounds and compositions are useful as photoactive components in chemically amplified resist compositions for use in, for example, various microfabrication applications.