p-cyano-β,β-dimethylstyrene | 93476-38-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-cyano-β,β-dimethylstyrene
• 英文别名: 4-Cyan-β,β-dimethyl-styrol；4-(2-Methylprop-1-enyl)benzonitrile
• CAS: 93476-38-1
• 化学式: C₁₁H₁₁N
• 分子量: 157.215
• InChiKey: KYJALEOSBPNYIV-UHFFFAOYSA-N

物化性质

• 沸点：
  274.3±19.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  对氰基溴化苄 在 正丁基锂 、 二异丙胺 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 生成 p-cyano-β,β-dimethylstyrene
  参考文献：
  名称：

  Photoinduced Charge Separation in Rigid Bichromophoric Compounds and Charge Transfer State Electron Transfer Reactivity

  摘要：

  Bichromophoric compounds giving, after photoexcitation, a locally excited state (LE) rapidly followed by an intramolecular charge transfer (CT) state were designed using a Paddon-Row type synthesis. The electron-accepting end of the CT state is chosen in order to play the role of an electron relay versus external accepters. In this way, electron transfer photosensitization is made available by using the CT state of bichromophores. The photophysics of the synthesized bichromophores is discussed; and the reductive dechlorination of polychlorinated benzenes is used as a test reaction. The bichromophoric sensitizer is unexpectedly found to be totally regenerated: the reaction is shown to be initiated by an electron transfer from the CT state to the chlorinated quencher. A rapidly breaking radical anion leads to the dechlorination, while the recombination of the sensitizer radical cation with the released chloride anion opens the way to the sensitizer recovery.

  DOI：

  10.1021/j100039a007

文献信息

• Toward a mild dehydroformylation using base-metal catalysis
  作者：Dylan J. Abrams、Julian G. West、Erik J. Sorensen

  DOI：10.1039/c6sc04607j

  日期：——

  biosynthesis of cholesterol and related sterols under mild conditions using base-metal catalysts. In contrast, chemists have recently developed a non-oxidative dehydroformylation method; however, it requires high temperatures and a precious-metal catalyst. Careful study of both approaches has informed our efforts to design a base-metal catalyzed, mild dehydroformylation method that incorporates benefits from

  脱氢甲酰化或醛类反应生成烯烃，氢气和一氧化碳的反应是一种有力的转化，尽管逆反应加氢甲酰化在工业上具有很高的重要性，但这种转化仍未开发。有趣的是，大自然通常在使用贱金属催化剂的温和条件下，在胆固醇和相关固醇的生物合成中进行相关的转化，即氧化脱氢甲酰化。相反，化学家们最近开发了一种非氧化脱氢甲酰化方法。但是，它需要高温和贵金属催化剂。对这两种方法的仔细研究使我们努力设计一种贱金属催化的轻度脱氢甲酰化方法，该方法综合了每种方法的优点，同时避免了它们各自的缺点。重要的，
• Electron-transfer substitution reactions: Facilitation by the cyano group
  作者：Nathan Kornblum、Michael J. Fifolt

  DOI：10.1016/0040-4020(89)80129-2

  日期：1989.1

  It is now clear that a cyane group facilitate electron-transfer substitution reactions. of particular interest is the demonstration that electron-transfer chain substitution at a staturated carbon atom has been achieved in the absence of a nitro group.

  现在清楚的是，氰基促进了电子转移取代反应。特别令人感兴趣的是证明在不存在硝基的情况下已经实现了在饱和碳原子上的电子转移链取代。
• Ruechardt,C.; Eichler,S., Chemische Berichte, 1962, vol. 95, p. 1921 - 1942
  作者：Ruechardt,C.、Eichler,S.

  DOI：——

  日期：——
• Versatile palladium-catalyzed arylation of organomanganese chlorides by aryl bromides
  作者：Eric Riguet、Mouâd Alami、Gérard Cahiez

  DOI：10.1016/s0022-328x(00)00891-3

  日期：2001.4

  In THF, a palladium-catalyzed cross-coupling reaction of organomanganese reagents with various aryl bromides including unreactive deactivated or hindered aryl bromides was performed successfully in the presence of a new catalytic system 1% PdCl2(dppp)-four equivalents DME. The scope of the reaction is very broad since many functional groups are tolerated, moreover, even hindered O,O ' -di- or trisubstituted diaryls were obtained in E;igh yields. It is interesting to note that hindered aryl bromides are more reactive than the corresponding aryl iodides. Alkyl, alkenyl and alkynylmanganese chlorides also react under similar conditions. (C) 2001 Elsevier Science B.V. All rights reserved.
• KORNBLUM, NATHAN;FIFOLT, MICHAEL J., TETRAHEDRON, 45,(1989) N, C. 1311-1322
  作者：KORNBLUM, NATHAN、FIFOLT, MICHAEL J.

  DOI：——

  日期：——