4,4'-bis[2-(4-(N,N-diphenylamino)phenyl)vinyl]biphenyl

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-bis[2-(4-(N,N-diphenylamino)phenyl)vinyl]biphenyl
• 英文别名: 4,4'-Bis[4-(diphenylamino)styryl]biphenyl；N,N-diphenyl-4-[(E)-2-[4-[4-[(E)-2-[4-(N-phenylanilino)phenyl]ethenyl]phenyl]phenyl]ethenyl]aniline
• 化学式: C₅₂H₄₀N₂
• 分子量: 692.903
• InChiKey: YPJRZWDWVBNDIW-MBALSZOMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.6
• 重原子数：
  54
• 可旋转键数：
  11
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4'-二溴联苯 、 N,N-二苯基-4-乙烯基苯胺 在 palladium diacetate sodium acetate 、 四苯基溴化膦 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以81%的产率得到4,4'-bis[2-(4-(N,N-diphenylamino)phenyl)vinyl]biphenyl
  参考文献：
  名称：

  Synthesis and Spectroscopic Properties of Finite Ph₂N-Containing Oligo(arylenevinylene) Derivatives That Emit Blue to Red Fluorescence

  摘要：

  [GRAPHIC]A series of oligo(phenylenevinylene) (OPV) derivatives with finite conjugation units were prepared in short steps from few building blocks. The central and terminal aryl groups of these OPV dyes contain cyano and Ph2N substituents, respectively, which affect color of fluorescence. The wavelength ranges from 472 nm (blue) to 614 nm (red) depending on the position of the cyano group.

  DOI：

  10.1021/ol034246v

文献信息

• COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200270283A1

  公开（公告）日：2020-08-27

  Provided is a compound represented by Formula 1 and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1.

  提供的是由公式1表示的化合物以及包括该化合物的有机发光设备。所述有机发光设备包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，所述有机层包括发射层和由公式1表示的化合物。
• ORGANIC LIGHT-EMITTING DEVICE AND COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20180166634A1

  公开（公告）日：2018-06-14

  An organic light-emitting device including a first electrode, a second electrode facing the first electrode, and an organic layer disposed between the first electrode and the second electrode, wherein the organic layer includes an emission layer, and wherein the emission layer includes a fluorescent compound represented by a specific formula described in the specification.

  一种有机发光器件，包括第一电极，面向第一电极的第二电极，以及设置在第一电极和第二电极之间的有机层，其中有机层包括一个发射层，该发射层包括一个在规范中描述的特定公式代表的荧光化合物。
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011105700A1

  公开（公告）日：2011-09-01

  Provided are novel organic electroluminescent compounds, and organic electroluminescent devices comprising the same. Since the organic electroluminescent compounds exhibit high luminous efficiency in blue color, and excellent life property of the material, they may be used to manufacture OLEDs having very good operation life.

  提供了新颖的有机电致发光化合物，以及包含这些化合物的有机电致发光器件。由于这些有机电致发光化合物在蓝色方面表现出高发光效率，并且材料具有优秀的寿命特性，因此它们可以用于制造具有非常良好使用寿命的OLED。
• ORGANIC METAL COMPOUND, ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DEVICE HAVING THE COMPOUND
  申请人：LG Display Co., Ltd

  公开号：US20210074932A1

  公开（公告）日：2021-03-11

  The present disclosure relates to an organic metal compound having the following structure, and an organic light emitting diode (OLED) and an organic light emitting device including the organic metal compound of the following structure. Incorporating the organic metal compound of the following structure into an emitting unit makes the OLED with improved luminous efficiency, luminous color purity and luminous lifetime.

  本公开涉及具有以下结构的有机金属化合物，以及包括以下结构有机金属化合物的有机发光二极管（OLED）和有机发光装置。将以下结构的有机金属化合物引入发光单元中，能使OLED的发光效率、发光色纯度和发光寿命得到提高。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND DIAGNOSTIC COMPOSITION INCLUDING THE ORGANOMETALLIC COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20200392173A1

  公开（公告）日：2020-12-17

  Provided are an organometallic compound represented by Formula 1, an organic light-emitting device including the organometallic compound, and a diagnostic composition including the organometallic compound. M 1 (L 11 ) n11 (L 12 ) n12 L 11 in Formula 1 is a ligand represented by Formula 1-1, and other substituents are the same as described in the detailed description of the specification:

  提供的是由化学式1表示的有机金属化合物，包括该有机金属化合物的有机发光器件，以及包括该有机金属化合物的诊断组合物。 M 1 (L 11 ) n11 (L 12 ) n12 <化学式1> 化学式1中的L 11 是由化学式1-1表示的配体，其他取代基与规范的详细描述中描述的相同。