1,3,5-tris-(2-chlorophenyl) benzene | 136612-94-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3,5-tris-(2-chlorophenyl) benzene
• 英文别名: 1,3,5-Tris(2-chlorophenyl)benzene
• CAS: 136612-94-7
• 化学式: C₂₄H₁₅Cl₃
• 分子量: 409.742
• InChiKey: NHSVMVFHSBCCQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  邻氯苯乙酮 在 乙二胺 、 三氟乙酸 作用下， 以 硝基甲烷 为溶剂， 反应 36.0h， 以72%的产率得到1,3,5-tris-(2-chlorophenyl) benzene
  参考文献：
  名称：

  胺和三氟乙酸催化的芳基甲基酮的三重缩合：在温和条件下可直接与1,3,5-三芳基苯接触

  摘要：

  报道了乙二胺和三氟乙酸催化的芳基甲基酮的有效三重缩合反应。以良好至优异的产率获得了广泛的1,3,5-三芳基苯。该反应为在温和条件下接触多环芳烃的有机材料提供了一种新颖而实用的方法。

  DOI：

  10.1016/j.tetlet.2012.03.008

文献信息

• Efficient Conversion of Acetophenones into 1,3,5-Triarylbenzenes Catalyzed by Bismuth(III) Trifluoromethanesulfonate Tetrahydrate
  作者：Tsuneo Sato、Fumiaki Ono、Yuichi Ishikura、Yuusuke Tada、Masato Endo

  DOI：10.1055/s-2008-1078012

  日期：——

  Bismuth(III) trifluoromethanesulfonate tetrahydrate is found to efficiently catalyze the cyclotrimerization of acetophenones into 1,3,5-triarylbenzenes in good yields.

  三氟甲磺酸铋(III)四水合物被发现能高效催化苯乙酮的环三聚反应，生成高产率的1,3,5-三芳基苯。
• Facile Synthesis of 1,3,5-Triarylbenzenes and 4-Aryl-<i>NH</i> -1,2,3-Triazoles Using Mesoporous Pd-MCM-41 as Reusable Catalyst
  作者：Arijit Saha、Chia-Ming Wu、Rui Peng、Ranjit Koodali、Subhash Banerjee

  DOI：10.1002/ejoc.201801290

  日期：2019.1.10

  Mesoporous Pd‐MCM‐41 catalyzed expeditious synthesis of 1,3,5‐triarylbenzenes and 4‐aryl‐NH‐1,2,3‐triazoles have been developed via denitrative cyclo‐trimerization of β‐nitrostyrenes and de‐nitrative [3+2] cycloaddition of β‐nitrostyrenes with TMSN3 respectively. The catalyst was reused at least up to eight times with minimum loss of catalytic activity.

  通过β-硝基苯乙烯的反硝化三聚和反硝化反应，开发了介孔Pd-MCM-41催化快速合成1,3,5-三芳基苯和4-芳基NH -1,2,3-三唑。 2]分别将β-硝基苯乙烯与TMSN 3环加成。催化剂可重复使用至少八次，且催化活性损失最小。
• Electrophotographic recording material containing a trisazo dye
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0350984A1

  公开（公告）日：1990-01-17

  An electrophotographic recording material comprising a conductive support and a photosensitive layer containing a photoconductive compound that has p-type charge generating capacity and is a trisazo compound which is the reaction product of the coupling reaction between a coupler compound that does not contain a carboxylic acid or sulphonic acid group and a diazonium salt represented by the following general formula (I) : wherein : each of L, M and Y (same or different) represents a phenylene group including a phenylene groups substituted with one or more substituents selected from the group consisting of lower alkyl (C₁-C₂), nitro, methoxy, ethoxy or halogen, or represents said phenylene group fused-on with the necessary atoms to close a saturated or unsaturated carbocyclic or heterocyclic ring or ring system including said ring or ring-system in substituted form, and X⁻ is an anion.

  一种电子照相制版记录材料，包括导电支架和光敏层，光敏层中含有一种具有 p 型电荷生成能力的光电导化合物，该化合物是一种三唑化合物，它是一种不含羧酸或磺酸基团的偶联剂化合物与由下式通式(I)代表的重氮盐偶联反应的反应产物： 其中 ： L、M 和 Y（相同或不同）各自代表一个亚苯基，包括被一个或多个选自低 级烷基（C₁-C₂）、硝基、甲氧基、乙氧基或卤素的取代基取代的亚苯基， 或代表所述亚苯基与必要的原子熔合，以封闭饱和或不饱和碳环或杂环或环系，包 括取代形式的所述环或环系，以及 X- 是阴离子。
• Highly Efficient Synthesis of Substituted Benzenes in the Presence of B(HSO₄)₃as a New and Reusable Catalyst Under Solvent-Free Conditions
  作者：Hamid Reza Safaei、Mansooreh Davoodi、Mohsen Shekouhy

  DOI：10.1080/00397911.2012.696300

  日期：2013.8.18

  A highly efficient and simple procedure for the synthesis of substituted benzenes is described. A broad range of ketones (alkyl-aryl ketones and cyclic ketones) were condensed via a cyclotrimerization reaction in the presence of catalytic amounts of boron sulfonic acid [B(HSO4)(3)], a new, highly efficient, and reusable catalyst, under solvent-free conditions. All reactions completed in short times without formation of any by-products. The catalyst was recovered and reused successfully for 15cycles of the reaction. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
• US4990421A
  申请人：——

  公开号：US4990421A

  公开（公告）日：1991-02-05