N,N'-bis[(pyridin-3-yl)methyl]pyridine-2,5-dicarboxamide | 548782-54-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N'-bis[(pyridin-3-yl)methyl]pyridine-2,5-dicarboxamide
• 英文别名: 2-N,5-N-bis(pyridin-3-ylmethyl)pyridine-2,5-dicarboxamide
• CAS: 548782-54-3
• 化学式: C₁₉H₁₇N₅O₂
• 分子量: 347.376
• InChiKey: KHBTWXSRVYXZFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  96.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N,N'-bis[(pyridin-3-yl)methyl]pyridine-2,5-dicarboxamide 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 生成 [Zn(5-((pyridin-3-yl)methylcarbamoyl)pyridine-2-carboxylate)2]
  参考文献：
  名称：

  Two 2D new helical coordination polymers induced by in situ hydrolysis generated 5-((pyridin-3-yl)methylcarbamoyl)pyridine-2-carboxylate

  摘要：

  Solvothermal reaction of N,N'-Bis[(pyridin-3-yl)methylipyridine-2,5-dicarboxamide (L-1) as well as Zn(OAc)(2) or Co(NO3)(2) in methanol gave rise to two new 2D complexes [Zn(L-2)(2)](n) (1) and [Co(L-2)(2)](n) (2), in which in situ formation of an anionic ligand 5-((pyridin-3-yl)methylcarbamoyl)pyridine-2-carboxylate (L-2) was observed. Single-crystal structural analysis reveals that 1 and 2 are isostructural, and the 2D helical networks are assembled from two different-handed strands with shared the common metal atoms. Fluorescent and thermal properties of complexes 1 and 2 are also investigated. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2008.07.026

文献信息

• Two 2D new helical coordination polymers induced by in situ hydrolysis generated 5-((pyridin-3-yl)methylcarbamoyl)pyridine-2-carboxylate
  作者：Xia Li、Ben-Lai Wu、Wei Liu、Hong-Yun Zhang

  DOI：10.1016/j.inoche.2008.07.026

  日期：2008.10

  Solvothermal reaction of N,N'-Bis[(pyridin-3-yl)methylipyridine-2,5-dicarboxamide (L-1) as well as Zn(OAc)(2) or Co(NO3)(2) in methanol gave rise to two new 2D complexes [Zn(L-2)(2)](n) (1) and [Co(L-2)(2)](n) (2), in which in situ formation of an anionic ligand 5-((pyridin-3-yl)methylcarbamoyl)pyridine-2-carboxylate (L-2) was observed. Single-crystal structural analysis reveals that 1 and 2 are isostructural, and the 2D helical networks are assembled from two different-handed strands with shared the common metal atoms. Fluorescent and thermal properties of complexes 1 and 2 are also investigated. (C) 2008 Published by Elsevier B.V.