9-(Z)-octadecenylmethylsulphide | 143262-31-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 9-(Z)-octadecenylmethylsulphide
• 英文别名: (Z)-1-methylsulfanyloctadec-9-ene
• CAS: 143262-31-1
• 化学式: C₁₉H₃₈S
• 分子量: 298.577
• InChiKey: AIDPXYJTFXPSIQ-KHPPLWFESA-N

物化性质

• 沸点：
  387.5±21.0 °C(Predicted)
• 密度：
  0.853±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(Z)-octadecenylmethylsulphide 在 Schwartz's reagent 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以38%的产率得到正十八烷
  参考文献：
  名称：

  Hydrozirconation of oleyl sulphides and oleyl phenylsulphone

  摘要：

  The hydrozirconation of 9-(Z)-octadecenylmethyl-sulphide, 9-(Z)-octadecenyl phenyl sulphide and 9-(Z)-octadecenyl phenyl sulphone have been studied. These compounds underwent substantial elimination of the functional group, yielding after hydrolysis, along with saturated and unsaturated sulphides and sulphones, large amounts of octadecane. The saturated analogues (dodecylmethyl-sulphide, octadecyl phenyl sulphide and octadecyl phenyl sulphone) were unaffected by the hydrozirconation reagent under similar conditions.

  DOI：

  10.1016/0022-328x(92)80095-f
• 作为产物：
  描述：

  1-溴-顺-9-十八碳烯 、 甲氧基二硫代甲酸钾 在 氢氧化钾 、 甲基三辛基氯化铵 作用下， 生成 9-(Z)-octadecenylmethylsulphide
  参考文献：
  名称：

  Hydrozirconation of oleyl sulphides and oleyl phenylsulphone

  摘要：

  The hydrozirconation of 9-(Z)-octadecenylmethyl-sulphide, 9-(Z)-octadecenyl phenyl sulphide and 9-(Z)-octadecenyl phenyl sulphone have been studied. These compounds underwent substantial elimination of the functional group, yielding after hydrolysis, along with saturated and unsaturated sulphides and sulphones, large amounts of octadecane. The saturated analogues (dodecylmethyl-sulphide, octadecyl phenyl sulphide and octadecyl phenyl sulphone) were unaffected by the hydrozirconation reagent under similar conditions.

  DOI：

  10.1016/0022-328x(92)80095-f

文献信息

• US5550241A
  申请人：——

  公开号：US5550241A

  公开（公告）日：1996-08-27
• US5646098A
  申请人：——

  公开号：US5646098A

  公开（公告）日：1997-07-08
• Hydrozirconation of oleyl sulphides and oleyl phenylsulphone
  作者：Susanne Karlsson、Anders Hallberg、Salo Gronowitz

  DOI：10.1016/0022-328x(92)80095-f

  日期：1992.6

  The hydrozirconation of 9-(Z)-octadecenylmethyl-sulphide, 9-(Z)-octadecenyl phenyl sulphide and 9-(Z)-octadecenyl phenyl sulphone have been studied. These compounds underwent substantial elimination of the functional group, yielding after hydrolysis, along with saturated and unsaturated sulphides and sulphones, large amounts of octadecane. The saturated analogues (dodecylmethyl-sulphide, octadecyl phenyl sulphide and octadecyl phenyl sulphone) were unaffected by the hydrozirconation reagent under similar conditions.