4,4'-bis(4-aminophenylthio)diphenyl sulfone | 100072-82-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 4,4'-bis(4-aminophenylthio)diphenyl sulfone
• 英文别名: 4-[4-[4-(4-Aminophenyl)sulfanylphenyl]sulfinylphenyl]sulfanylaniline
• CAS: 100072-82-0
• 化学式: C₂₄H₂₀N₂OS₃
• 分子量: 448.634
• InChiKey: XRYQVUITNZUFBS-UHFFFAOYSA-N

物化性质

• 沸点：
  747.5±60.0 °C(Predicted)
• 密度：
  1.43±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  139
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,4'-bis(4-aminophenylthio)diphenyl sulfone 生成 [4-[4-[4-[4-(cyanoamino)phenyl]sulfanylphenyl]sulfinylphenyl]sulfanylphenyl]cyanamide
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  4,4'-二氯二苯基亚砜 、 4-氨基苯硫酚 在 potassium carbonate 、 sodium hydroxide 作用下， 生成 4,4'-bis(4-aminophenylthio)diphenyl sulfone
  参考文献：
  名称：

  Thermal cross-link behavior of an amorphous poly (para-arylene sulfide sulfone amide)

  摘要：

  Cross-link behavior of an amorphous poly (para-arylene sulfide sulfone amide) synthesized via low temperature solution polycondensation was observed for the first time, when the polymer was subject to a series of thermal curing at 260 degrees C in air condition. The formation of cross-link network was demonstrated by the DSC and TGA results that T-g of the polymer enhanced from 259.17 degrees C to 268.89 degrees C, and the 1% weight loss temperature increased remarkably from 243.75 degrees C to 345.87 degrees C. EPR analysis further suggested that two kinds of free radicals, CO center dot and C-center dot, induced by thermal curing were responsible for this cross-link behavior. According to FT-IR spectrum, the origin of these free radicals was confirmed as amide C=O group in the polymer backbone. The cross-linking type was attributed to conventional radical cross-link reaction and the cross-link mechanism was discussed in detail subsequently. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2011.01.001

文献信息

• Aromatic polythioetheramides and process for their production
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0162606A1

  公开（公告）日：1985-11-27

  Aromatic polythioetheramides have repeating units represented by one or both of the following formulae and wherein X is C1-C10 divalent hydrocarbon, -0-, -S-, - SO-, - SO2- or -CO-; a is 0 or 1; Y is C,-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aralkyl, C6-C20 aryl, halogen or nitro; b, c, e and f, 0 to 4; d, 0-20 and Ar is a C6-C30 aromatic ring. Repeating units derived from C6-C30 aromatic diamines may replace up to 50 mol% of the above thioetheramide units, and from 51 to 99 mol% when Ar is isophthalyl or terephthalyl. The polymers have excellent moldability, flame retardance, heat resistance and chemical resistance, and are suitable for use as engineering plastics.

  芳香族聚硫醚酰胺的重复单元由以下一个或两个式子表示 和 其中 X 为 C1-C10 二价烃、-0-、-S-、-SO-、-SO2- 或-CO-；a 为 0 或 1；Y 为 C,-C20烷基、C3-C20 环烷基、C6-C20 芳基、C6-C20 芳基、卤素或硝基；b、c、e 和 f 为 0 至 4；d 为 0 至 20；Ar 为 C6-C30 芳环。 由 C6-C30 芳族二胺衍生的重复单元可取代高达 50 摩尔%的上述硫醚酰胺单元，当 Ar 为间苯二甲酸酯或对苯二甲酸酯时，可取代 51 至 99 摩尔%的上述硫醚酰胺单元。这些聚合物具有优异的成型性、阻燃性、耐热性和耐化学性，适合用作工程塑料。
• Aromatic polythioetherimide
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0294848A1

  公开（公告）日：1988-12-14

  An aromatic polythioetherimide is disclosed, which comprises at least 50 mol% of a repeating unit represented by formula (I): wherein Ar is as defined in the specification, with the total of the repeating unit(s) being 100 mol%. The polythioetherimide has an excellent balance between heat resistance and mechanical properties as well as improved moldability.

  本发明公开了一种芳香族聚硫醚酰亚胺，它由至少 50 摩尔%的式 (I) 所代表的重复单元组成： 其中 Ar 如说明书中所定义，重复单元的总量为 100 摩尔%。这种聚硫醚酰亚胺在耐热性和机械性能之间取得了极佳的平衡，并改善了成型性。
• ——
  作者：ARITOMI MITSUTOSI、 FUDZIVARA EHJSUKEH

  DOI：——

  日期：——
• Aromatic poly(thioetheramide-imides)
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0210036B1

  公开（公告）日：1993-02-10
• US4621134A
  申请人：——

  公开号：US4621134A

  公开（公告）日：1986-11-04