N-[(3,5-dimethylpyrazol-1-yl)methyl]-N-(furan-2-ylmethyl)-1-phenylmethanamine | 585531-94-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[(3,5-dimethylpyrazol-1-yl)methyl]-N-(furan-2-ylmethyl)-1-phenylmethanamine
• CAS: 585531-94-8
• 化学式: C₁₈H₂₁N₃O
• 分子量: 295.384
• InChiKey: UDOYNPXLARUUJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  34.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-[(3,5-dimethylpyrazol-1-yl)methyl]-N-(furan-2-ylmethyl)-1-phenylmethanamine 、 copper dichloride 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  N-tripodal ligands to generate copper catalysts for the syndiotactic polymerization of methyl-methacrylate: Crystal structures of copper complexes

  摘要：

  A library of N-tripodal ligands, based on a central nitrogen atom connected to three different functionalized arms, was investigated via a parallel approach for the polymerization of methyl-methacrylate (MMA) in presence of late transition metal salts. Copper salts CuCl2 and Cu(OAC)(2) in combination with N-(2-furanylmethyl)-N-(1-3,5-dimetliyi-1H-pyrazolylmetliyl)-N- (phenylmethyl)amine were detected as efficient catalysts for the syndiotactic polymerization of MMA ([rr] up to 78%). Kinetic studies and X-ray structures of the best catalysts were reported. (C) 2007 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2007.11.010

文献信息

• N-tripodal ligands to generate copper catalysts for the syndiotactic polymerization of methyl-methacrylate: Crystal structures of copper complexes
  作者：Clément Lansalot-Matras、Fabien Bonnette、Emmanuel Mignard、Olivier Lavastre

  DOI：10.1016/j.jorganchem.2007.11.010

  日期：2008.2

  A library of N-tripodal ligands, based on a central nitrogen atom connected to three different functionalized arms, was investigated via a parallel approach for the polymerization of methyl-methacrylate (MMA) in presence of late transition metal salts. Copper salts CuCl2 and Cu(OAC)(2) in combination with N-(2-furanylmethyl)-N-(1-3,5-dimetliyi-1H-pyrazolylmetliyl)-N- (phenylmethyl)amine were detected as efficient catalysts for the syndiotactic polymerization of MMA ([rr] up to 78%). Kinetic studies and X-ray structures of the best catalysts were reported. (C) 2007 Published by Elsevier B.V.