copper(ΙΙ) 1,3,8,10,15,17,22,24-octanitrophthalocyanine | 124826-73-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: copper(ΙΙ) 1,3,8,10,15,17,22,24-octanitrophthalocyanine
• 英文别名: octa-3,5-nitrophthalocyanin；copper(II) 1,3,8,10,15,17,22,24-octanitrophthalocyanine；Copper;5,7,14,16,23,25,32,34-octanitro-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 124826-73-9
• 化学式: C₃₂H₈CuN₁₆O₁₆
• 分子量: 936.059
• InChiKey: IEKMFWRBCFTNFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.39
• 重原子数：
  65
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  443
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  copper(ΙΙ) 1,3,8,10,15,17,22,24-octanitrophthalocyanine 在 sodiumsulfide nonahydrate 作用下， 以 水 为溶剂， 以6.30 g的产率得到copper(II) 1,3,5,8,10,15,17,22,24-octaaminophthalocyanine
  参考文献：
  名称：

  Synthesis and Characterization of Substituted Metal(II)-octa- MethoxyphenylImino Phthalocyanine Pigments

  摘要：

  描述了通过八氨基酞菁与邻茴香醛缩合得到的对称取代金属 (II) – 八甲氧基苯基亚氨基酞菁的合成、光谱和磁化率。通过电子、红外、元素分析、磁化率、粉末 X 射线衍射和热重分析 (TGA) 研究对深绿色八氨基酞菁衍生物进行表征，以检查颜料的结构完整性、纯度和结晶特性。磁矩随场强 2.20 至 4.01 kG 的变化表明存在分子间协同效应。

  DOI：

  10.13005/ojc/330548
• 作为产物：
  描述：

  copper diacetate 、 3,5-dinitrophthalonitrile 以 N,N-二甲基甲酰胺 为溶剂， 以41%的产率得到copper(ΙΙ) 1,3,8,10,15,17,22,24-octanitrophthalocyanine
  参考文献：
  名称：

  Negrimovskii, V. M.; Derkacheva, V. M.; Luk'yanets, E. A., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1502 - 1503

  摘要：

  DOI：

文献信息

• Achar, B. N.; Bhandari, J. M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1993, vol. 23, p. 133 - 148
  作者：Achar, B. N.、Bhandari, J. M.

  DOI：——

  日期：——
• Negrimovskii, V. M.; Derkacheva, V. M.; Kaliya, O. L., Journal of general chemistry of the USSR, 1991, vol. 61, p. 419 - 428
  作者：Negrimovskii, V. M.、Derkacheva, V. M.、Kaliya, O. L.、Luk'yanets, E. A.

  DOI：——

  日期：——
• SYNTHESIS, MAGNETIC, SPECTRAL, AND THERMAL STUDIES ON METAL(II) 1,3,8,10,15,17,22,24-OCTAAMINOPHTHALOCYANINES
  作者：K. R. Venugopala Reddy、J. Keshavayya

  DOI：10.1081/sim-120014300

  日期：2002.9.18

  Symmetrically octasubstituted metal(II) [M = Cu, Ni, Co, and Zn] 1,3,8,10,15,17,22,24-aminophthalocyanines have been synthesized by an efficient, simple and novel method. The aminophthalocyanines were synthesized by the reduction of the corresponding nitrophthalocyanines. The dark blue-green octaaminosubstituted phthalocyanine derivatives were characterized by elemental analyses, magnetic susceptibility, electronic, IR, thermal, and powder X-ray diffraction studies to check the purity, structural integrity, thermal stability and crystallinality of the complexes. Magnetic susceptibility studies on the above octaaminophthalocyanine complexes show a variation of the magnetic moments as a function of field strength indicating the presence of intermolecular cooperative effects. Thermal studies revealed that the complexes are stable up to 400 degreesC in air, and powder X-ray diffraction studies have shown that they are crystalline in nature.
• NEGRIMOVSKIJ, V. M.;DERKACHEVA, V. M.;KALIYA, O. L.;LUKYANETS, E. A., ZH. OBSHCH. XIMII, 61,(1991) N, S. 460-470
  作者：NEGRIMOVSKIJ, V. M.、DERKACHEVA, V. M.、KALIYA, O. L.、LUKYANETS, E. A.

  DOI：——

  日期：——
• Synthesis and Characterization of Substituted Metal(II)-octa- MethoxyphenylImino Phthalocyanine Pigments
  作者：Fasiulla Fasiulla、M. P. Yashoda

  DOI：10.13005/ojc/330548

  日期：2017.10.28

  The synthesis, spectral and magnetic susceptibility on symmetrically substituted metal (II) – octa-methoxyphenyl imino phthalocyanine by condensing  octa amino phthalocyanines with o-anisaldehyde  are described. The dark green colour octa amino  phthalocyanine derivatives were characterized by electronic, IR, elemental analysis, magnetic susceptibility, powder X-ray diffraction and thermo gravimetric analysis (TGA) studies to structural integrity, check the purity and crystalline properties of the pigments. The variation of magnetic moment as function of field strength 2.20 to 4.01 kG indicated the presence of intermolecular co-operative effect.

  描述了通过八氨基酞菁与邻茴香醛缩合得到的对称取代金属 (II) – 八甲氧基苯基亚氨基酞菁的合成、光谱和磁化率。通过电子、红外、元素分析、磁化率、粉末 X 射线衍射和热重分析 (TGA) 研究对深绿色八氨基酞菁衍生物进行表征，以检查颜料的结构完整性、纯度和结晶特性。磁矩随场强 2.20 至 4.01 kG 的变化表明存在分子间协同效应。