(1-phenylethene-1,2-diyl)bis((4-chlorophenyl)selane) | 888027-47-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1-phenylethene-1,2-diyl)bis((4-chlorophenyl)selane)
• 英文别名: Z-(Ph)((C6H4Cl-p)Se)CC(H)(Se(C6H4Cl-p))；1-chloro-4-[(Z)-2-(4-chlorophenyl)selanyl-1-phenylethenyl]selanylbenzene
• CAS: 888027-47-2
• 化学式: C₂₀H₁₄Cl₂Se₂
• 分子量: 483.157
• InChiKey: QKZBXKFGOVYHJK-ZHZULCJRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.35
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  乙烯双(三苯基磷)铂 、 (1-phenylethene-1,2-diyl)bis((4-chlorophenyl)selane) 以 苯 为溶剂， 以92%的产率得到cis-Pt[(Z)-C(H)C(Ph)C(Se(C6H4Cl-p))](Se(C6H4Cl-p))(PPh3)2
  参考文献：
  名称：

  无环乙烯基硒化物氧化加成到M（0）络合物的第一个确定性例子

  摘要：

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When

  DOI：

  10.1016/j.jorganchem.2005.12.058
• 作为产物：
  描述：

  双(4-氯苯基)二硒化物 、 苯乙炔 以 二氯甲烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  可见光促进炔烃的立体选择性芳基杂戊基官能化

  摘要：

  在这项工作中，使用普通荧光灯发出的可见白光作为能源，在没有催化剂或添加剂的情况下，合成了一系列的双芳基杂戊基戊烯基烯烃。通过自由基加成-光异构化，以非常干净和快速的方式获得了产物，得到了具有良好立体选择性的E-烯烃。

  DOI：

  10.1002/ejoc.201801303

文献信息

• The first definitive example of oxidative addition of acyclic vinyl selenide to M(0) complex
  作者：Hitoshi Kuniyasu、Tomohiro Kato、Masafumi Inoue、Jun Terao、Nobuaki Kambe

  DOI：10.1016/j.jorganchem.2005.12.058

  日期：2006.4

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When
• Visible-Light Promoted Stereoselective Arylselanyl Functionalization of Alkynes
  作者：Andressa C. H. Weber、Felipe L. Coelho、Ricardo F. Affeldt、Paulo H. Schneider

  DOI：10.1002/ejoc.201801303

  日期：2018.12.19

  In this work a series of bis‐arylselanyl olefins were synthesized using visible white light from common fluorescent lamps as energy source, without catalyst or additives. The products were achieved in a very clean and fast way, yielding E‐olefins with good stereoselectivity, through radical addition‐photoisomerization.

  在这项工作中，使用普通荧光灯发出的可见白光作为能源，在没有催化剂或添加剂的情况下，合成了一系列的双芳基杂戊基戊烯基烯烃。通过自由基加成-光异构化，以非常干净和快速的方式获得了产物，得到了具有良好立体选择性的E-烯烃。