7,7,14,14-tetraphenyl-7,14-dihydro[1,6]distannecino[2,3-b:5,4-b':7,8-b'':10,9-b''']tetrathiophene | 1201804-35-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 7,7,14,14-tetraphenyl-7,14-dihydro[1,6]distannecino[2,3-b:5,4-b':7,8-b'':10,9-b''']tetrathiophene
• CAS: 1201804-35-4
• 化学式: C₄₀H₂₈S₄Sn₂
• 分子量: 874.346
• InChiKey: AQNBTGLCZOJURP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.63
• 重原子数：
  46
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  7,7-diphenyl-7H-stannolo[2,3-b:5,4-b']dithiophene 、 7,7,14,14-tetraphenyl-7,14-dihydro[1,6]distannecino[2,3-b:5,4-b':7,8-b'':10,9-b''']tetrathiophene 、 lithium 以 乙醚 为溶剂， 生成 triphenylstannyllithium 、 2,2'-dilithio-3,3'-bithiophene
  参考文献：
  名称：

  Synthesis and structure of the dithienostannole anion

  摘要：

  Novel dithienostannoles were synthesized by the reactions of the corresponding dilithiobithiophenes with dichlorodiphenylstannane. A unique byproduct, 10-membered ring compound was also obtained. Reduction of type A dithienostannole with lithium afforded 2,2'-dilithio-3,3'-bithiophene, while reduction of type B dithienostannole with lithium afforded the corresponding dithienostannole anion. The structure and aromaticity of the dithienostannole anion are also discussed. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.08.026
• 作为产物：
  描述：

  7,7-diphenyl-7H-stannolo[2,3-b:5,4-b']dithiophene 在 copper(I) iodide 作用下， 以 乙醚 为溶剂， 生成 7,7,14,14-tetraphenyl-7,14-dihydro[1,6]distannecino[2,3-b:5,4-b':7,8-b'':10,9-b''']tetrathiophene
  参考文献：
  名称：

  Synthesis and structure of the dithienostannole anion

  摘要：

  Novel dithienostannoles were synthesized by the reactions of the corresponding dilithiobithiophenes with dichlorodiphenylstannane. A unique byproduct, 10-membered ring compound was also obtained. Reduction of type A dithienostannole with lithium afforded 2,2'-dilithio-3,3'-bithiophene, while reduction of type B dithienostannole with lithium afforded the corresponding dithienostannole anion. The structure and aromaticity of the dithienostannole anion are also discussed. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.08.026

文献信息

• Synthesis and structure of the dithienostannole anion
  作者：Masaichi Saito、Munenori Shiratake、Tomoyuki Tajima、Jing Dong Guo、Shigeru Nagase

  DOI：10.1016/j.jorganchem.2009.08.026

  日期：2009.12

  Novel dithienostannoles were synthesized by the reactions of the corresponding dilithiobithiophenes with dichlorodiphenylstannane. A unique byproduct, 10-membered ring compound was also obtained. Reduction of type A dithienostannole with lithium afforded 2,2'-dilithio-3,3'-bithiophene, while reduction of type B dithienostannole with lithium afforded the corresponding dithienostannole anion. The structure and aromaticity of the dithienostannole anion are also discussed. (C) 2009 Elsevier B. V. All rights reserved.