2,3,5,6-tetrafluoro-4-vinylphenol | 385422-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,5,6-tetrafluoro-4-vinylphenol
• 英文别名: 4-Hydroxy-2,3,5,6-tetrafluorostyrene；4-ethenyl-2,3,5,6-tetrafluorophenol
• CAS: 385422-30-0
• 化学式: C₈H₄F₄O
• 分子量: 192.113
• InChiKey: PJELNCULMQLNIG-UHFFFAOYSA-N

物化性质

• 沸点：
  165.7±35.0 °C(Predicted)
• 密度：
  1.470±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 海关编码：
  2908199090

反应信息

• 作为反应物：
  描述：

  1,3-丙烷磺内酯 、 2,3,5,6-tetrafluoro-4-vinylphenol 在 sodium hydroxide 作用下， 以 甲醇 、 1,4-二氧六环 为溶剂， 反应 25.0h， 以70%的产率得到sodium 3-(2,3,5,6-tetrafluoro-4-vinylphenoxy)propane-1-sulfonate
  参考文献：
  名称：

  Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group

  摘要：

  Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by H-1 NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2013.02.008
• 作为产物：
  描述：

  2,3,4,5,6-五氟苯乙烯 在 potassium hydroxide 、 盐酸 作用下， 以 叔丁醇 、 水 为溶剂， 反应 2.0h， 以58%的产率得到2,3,5,6-tetrafluoro-4-vinylphenol
  参考文献：
  名称：

  Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group

  摘要：

  Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by H-1 NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2013.02.008

文献信息

• FLUORINATED AROMATIC COMPOUND, METHOD FOR ITS PRODUCTION, CURABLE MATERIAL, ITS CURED PRODUCT, AND OPTICAL MEMBER
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20160137572A1

  公开（公告）日：2016-05-19

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, —O—, —S—, —CO—, —C(CH 3 ) 2 —, —C(CF 3 ) 2 —, —SO—, or —SO 2 —, Rf 1 is a C 1-8 fluoroalkyl group, Y 1 and Y 2 are each independently a group represented by formula (1) (s is 0 or 1, and R 1 , R 2 , R 3 , and R 4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型氟芳香化合物，一种其生产方法，包括所述氟芳香化合物的可固化材料，其固化产物以及光学部件。所述氟芳香化合物由式（A）表示，其中n为0至6的整数，a为0至5的整数，b为0至4的整数，c为0至4的整数，a+c+n为2至6，a+b为2至9，Z为单键，—O—，—S—，—CO—，—C(CH3)2—，—C(CF3)2—，—SO—，或—SO2—，Rf1为C1-8氟烷基，Y1和Y2分别独立地表示由式（1）表示的基团（s为0或1，R1、R2、R3和R4分别独立地表示氢原子或氟原子），芳香环中的F表示芳香环中的氢原子均被氟原子取代。
• Acid-degradable resin compositions containing ketene-aldehyde copolymer
  申请人：Sudo Atsushi

  公开号：US20050130057A1

  公开（公告）日：2005-06-16

  It is intended to provide compositions to be used in resists and the like for forming fine patterns with a high sensitivity and a high resolution by increasing the difference in the solubilities between exposed parts and unexposed parts. Acid-degradable compositions contain a polymer having a repeating unit represented by the following general formula (I): wherein R 1 and R 2 independently represent hydrogen atom, halogen atom, C 1-20 hydrocarbon group, a heterocyclic group, a cyano group, a nitro group, C(═O)R 4 group, S(O) n R 4 group, P(═O)(R 4 ) 2 group or M(R 4 ) 3 group; R 3 represents C 1-20 hydrocarbon group or a heterocyclic group: R 4 represents C 1-20 hydrocarbonoxy group, C 1-20 hydrocarbon group, C 1-20 hydrocarbonthio group or mono- or di-C 1-20 hydrocarbonamino group; M represents a silicon, germanium, tin or lead atom; and n is 0, 1 or 2 , and an acid or a compound capable of generating an acid in response to an external stimulus.

  本发明旨在提供用于制备高灵敏度和高分辨率细微图案的抗蚀剂等组合物，通过增加曝光部分和未曝光部分之间的溶解度差异。可降解酸性组合物包含具有以下通式（I）所表示的重复单元的聚合物：其中，R1和R2独立地表示氢原子、卤素原子、C1-20碳氢基团、杂环基团、氰基团、硝基团、C（═O）R4基团、S（O）nR4基团、P（═O）（R4）2基团或M（R4）3基团；R3表示C1-20碳氢基团或杂环基团；R4表示C1-20碳氢氧基团、C1-20碳氢基团、C1-20碳氢硫基团或单烷基或二烷基氨基基团；M表示硅、锗、锡或铅原子；n为0、1或2，以及一种酸或能够响应外部刺激产生酸的化合物。
• FLUORINE-CONTAINING COMPOUND, RESIST COMPOSITION FOR IMMERSION EXPOSURE, AND METHOD OF FORMING RESIST PATTERN
  申请人：Furuya Sanae

  公开号：US20090047602A1

  公开（公告）日：2009-02-19

  A resist composition for immersion exposure including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid, an acid-generator component (B) which generates acid upon irradiation, and a fluorine-containing compound (C) having a group represented by general formula (c) shown below and containing at least one fluorine atom: wherein Q represents a group in which one hydrogen atom has been removed from a monovalent hydrophilic group; and R 1 represents a hydrocarbon group of 2 or more carbon atoms which may have a fluorine atom.

  一种用于浸没曝光的抗蚀组合物，包括基础组分（A），在酸作用下在碱性显影液中表现出改变的溶解度，酸发生剂组分（B），在辐照下生成酸，以及含有至少一个氟原子的通式（c）所表示的基团的含氟化合物（C）：其中Q表示从一价亲水基团中去除了一个氢原子的基团; R1表示一个含有2个或更多碳原子的碳氢基团，可能具有氟原子。
• ACID-DEGRADABLE RESIN COMPOSITIONS CONTAINING KETENE-ALDEHYDE COPOLYMER
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1482361A1

  公开（公告）日：2004-12-01

  It is intended to provide compositions to be used in resists and the like for forming fine patterns with a high sensitivity and a high resolution by increasing the difference in the solubilities between exposed parts and unexposed parts. Acid-degradable compositions contain a polymer having a repeating unit represented by the following general formula (I): wherein R1 and R2 independently represent hydrogen atom, halogen atom, C1-20 hydrocarbon group, a heterocyclic group, a cyano group, a nitro group, C(=O)R4 group, S(O)nR4 group, P(=O)(R4)2 group or M(R4)3 group; R3 represents C1-20 hydrocarbon group or a heterocyclic group: R4 represents C1-20 hydrocarbonoxy group, C1-20 hydrocarbon group, C1-20 hydrocarbonthio group or mono- or di- C1-20 hydrocarbonamino group; M represents a silicon, germanium, tin or lead atom; and n is 0, 1 or 2, and an acid or a compound capable of generating an acid in response to an external stimulus.

  本发明旨在提供用于抗蚀剂等的组合物，通过增大暴露部分和未暴露部分之间的溶解度差异，形成具有高灵敏度和高分辨率的精细图案。可酸性降解组合物含有一种聚合物，其重复单元由以下通式 (I) 表示： 其中 R1 和 R2 分别代表氢原子、卤素原子、C1-20 烃基、杂环基、氰基、硝基、C(＝O)R4 基、S(O)nR4 基、P(＝O)(R4)2 基或 M(R4)3 基；R3 代表 C1-20 烃基或杂环基：R4代表C1-20烃氧基、C1-20烃基、C1-20烃硫基或单-或双-C1-20烃氨基；M代表硅、锗、锡或铅原子；n为0、1或2。
• FLUORINE-CONTAINING AROMATIC COMPOUND, METHOD FOR PRODUCING SAME, CURABLE MATERIAL, CURED PRODUCT THEREOF, AND OPTICAL MEMBER
  申请人：Asahi Glass Company, Limited

  公开号：EP3031793A1

  公开（公告）日：2016-06-15

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, -0-, -S-, -CO-, -C(CH3)2-, -C(CF3)2-, -SO-, or -SO2-, Rf1 is a C1-8 fluoroalkyl group, Y1 and Y2 are each independently a group represented by formula (1) (s is 0 or 1, and R1, R2, R3, and R4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型含氟芳香族化合物、其生产方法、包含该含氟芳香族化合物的可固化材料、其固化产物以及光学部件。氟化芳香族化合物由式 (A) 表示，其中 n 是 0 至 6 的整数，a 是 0 至 5 的整数，b 是 0 至 4 的整数，c 是 0 至 4 的整数，a+c+n 是 2 至 6，a+b 是 2 至 9，Z 是单键、-0-、-S-、-CO-、-C(CH3)2-、-C(CF3)2-、-SO- 或-SO2-、Rf1 是 C1-8 氟烷基，Y1 和 Y2 各自独立地是式 (1) 所代表的基团（s 是 0 或 1，R1、R2、R3 和 R4 各自独立地是氢原子或氟原子），芳香环中的 F 表示芳香环中的氢原子全部被氟原子取代。