2,2'-(Butane-1,1-diyl)bis(6-tert-butyl-4-ethylphenol) | 77695-09-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-(Butane-1,1-diyl)bis(6-tert-butyl-4-ethylphenol)
• 英文别名: 2-tert-butyl-6-[1-(3-tert-butyl-5-ethyl-2-hydroxyphenyl)butyl]-4-ethylphenol
• CAS: 77695-09-1
• 化学式: C₂₈H₄₂O₂
• 分子量: 410.6
• InChiKey: VTDFJEYLSWSRPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Process for producing phosphite
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20040225145A1

  公开（公告）日：2004-11-11

  There is provided a process for producing a phosphite of the formula (I): 1 wherein R 1 , R 2 , R 4 and R 5 each independently represent a hydrogen atom, a C1-8 alkyl group, a C5-8 cycloalkyl group, a C6-12 alkylcycloalkyl group, a C7-12 aralkyl group or a phenyl group or a phenyl group substituted with an alkyl or an alkoxy group; R 3 represents a hydrogen atom or a C1-8 alkyl group; A represents a C2-8 alkylene group or a *—C(═O)— or *—C(═O)—R 7 — group in which R 7 represents a C1-8 alkylene group, and the bond marked with* is the bond connected with the oxygen atom; and one of Y and Z represents a hydroxyl group, a C1-8 alkoxy group or a C7-12 aralkyloxy group and the other one represents a hydrogen atom or a C1-8 alkyl group.

  提供了一种制备式(I)磷酸酯的方法，其中R1、R2、R4和R5各自独立地表示氢原子、C1-8烷基、C5-8环烷基、C6-12烷基环烷基、C7-12芳基烷基或苯基或被烷基或烷氧基取代的苯基；R3表示氢原子或C1-8烷基；A表示C2-8烷基或*—C(═O)—或*—C(═O)—R7—，其中R7表示C1-8烷基，标记为*的键连接着氧原子；Y和Z中的一个表示羟基、C1-8烷氧基或C7-12芳基烷氧基，另一个表示氢原子或C1-8烷基。
• Curable resin composition and cold-setting adhesive
  申请人：Mori Shigeki

  公开号：US20060189736A1

  公开（公告）日：2006-08-24

  Disclosed is a moisture-curing type curable resin composition containing: a curable resin intramolecularly having a silicon-containing functional group; and a Lewis acid or a complex of the Lewis acid as a curing catalyst, the Lewis acid being selected from the group consisting of metal halides and boron halides, which is rapidly cured at room temperature. The silicon-containing functional group is represented by general formula: —SiX 1 X 2 X 3 or —SiR 1 X 1 X 2 (wherein, X 1 , X 2 and X 3 respectively represent a hydrolytic group and may be the same as or different from each other, and R 1 represents a substituted or unsubstituted organic group having 1 to 20 carbons). If the silicon-containing functional group is —SiR 1 X 1 X 2 , the curable resin further contains intramolecularly a polar component that is one of urethane, thiourethane, urea, thiourea, substituted urea, substituted thiourea, amide, and sulfide bonds, and hydroxyl, secondary amino and tertiary amino groups. Two-part type adhesive is constitutible with separating the curable resin from the curing catalyst.

  本发明公开了一种含有湿气硬化型可硬化树脂组分，包括：具有含硅官能团的可硬化树脂分子内部；以及一种Lewis酸或Lewis酸的复合物作为固化催化剂，所述Lewis酸选自金属卤化物和硼卤化物组成的群体，该组分在室温下迅速固化。所述含硅官能团由下式表示：—SiX1X2X3或—SiR1X1X2（其中，X1、X2和X3分别表示水解基团，可以相同也可以不同，R1表示具有1到20个碳的取代或未取代的有机基团）。如果所述含硅官能团为—SiR1X1X2，则可硬化树脂还包括分子内部的极性成分，该极性成分是尿素、硫脲、脲、硫代脲、取代脲、取代硫脲、酰胺和硫化物键以及羟基、二级胺和三级胺基之一。两部分型粘合剂可通过将可硬化树脂与固化催化剂分离而形成。
• Curable Resin Composition and Cold Setting Adhesive
  申请人：Mori Shigeki

  公开号：US20090264602A1

  公开（公告）日：2009-10-22

  Disclosed is a moisture-curing type curable resin composition containing: a curable resin intramolecularly having a silicon-containing functional group; and a Lewis acid or a complex of the Lewis acid as a curing catalyst, the Lewis acid being selected from the group consisting of metal halides and boron halides, which is rapidly cured at room temperature. The silicon-containing functional group is represented by general formula: —SiX 1 X 2 X 3 or —SiR 1 X 1 X 2 (wherein, X 1 , X 2 and X 3 respectively represent a hydrolytic group and may be the same as or different from each other, and R 1 represents a substituted or unsubstituted organic group having 1 to 20 carbons). If the silicon-containing functional group is —SiR 1 X 1 X 2 , the curable resin further contains intramolecularly a polar component that is one of urethane, thiourethane, urea, thiourea, substituted urea, substituted thiourea, amide, and sulfide bonds, and hydroxyl, secondary amino and tertiary amino groups. Two-part type adhesive is constitutible with separating the curable resin from the curing catalyst.

  本发明公开了一种含有湿度固化型可固化树脂组成物，包括：具有硅含有官能团的可固化树脂分子内部；以及作为固化催化剂的路易斯酸或路易斯酸的复合物，所述路易斯酸选择自金属卤化物和硼卤化物的组中，该组成物在室温下快速固化。硅含有官能团由通式表示：—SiX1X2X3或—SiR1X1X2（其中，X1、X2和X3分别表示一个水解基团，可以相同或不同，R1表示具有1到20个碳的取代或未取代的有机基团）。如果硅含有官能团为—SiR1X1X2，则可固化树脂还包含分子内部的极性组分之一，该极性组分为脲、硫脲、尿素、硫代尿素、取代尿素、取代硫脲、酰胺和硫化物键以及羟基、次级氨基和三级氨基基团。可将可固化树脂与固化催化剂分离以构成两部分型粘合剂。
• Phosphites, process for producing the same and their use
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0823435A2

  公开（公告）日：1998-02-11

  A phosphite of formula (I): wherein R1, R2, R4 and R5 represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R3 represents hydrogen atom or an alkyl group; X represents a direct bond, sulfur atom, or a -CHR6- group in which R6 represents hydrogen atom, an alkyl group or a cycloalkyl group; A represents an alkylene group having 2 to 8 carbon atoms or a *-COR7-group in which R7 represents a direct bond or an alkylene group, and * indicates the bond to the oxygen; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group and the other one represents hydrogen atom or an alkyl group, is suitably used as a stabilizer for an organic material.

  式(I)的亚磷酸酯： 其中 R1、R2、R4 和 R5 代表氢原子、烷基、环烷基、烷基环烷基、芳基或苯基；R3 代表氢原子或烷基；X 代表直接键、硫原子或-CHR6-基团，其中 R6 代表氢原子、烷基或环烷基；A 代表具有 2 至 8 个碳原子的亚烷基或 *-COR7- 基团，其中 R7 代表直接键或亚烷基，* 表示与氧的键合；Y 和 Z 中的一个代表羟基、烷氧基或芳氧基，另一个代表氢原子或烷基。
• CURING RESIN, METHOD FOR PRODUCING SAME AND CURING RESIN COMPOSITION
  申请人：KONISHI CO., LTD.

  公开号：EP1616886A1

  公开（公告）日：2006-01-18

  An object of the present invention is to provide a curable resin having a silyl group at the terminal that is also moisture-hardening resin which has lower in viscosity when it is used and provides superior adhesiveness when it is utilized for adhesive, sealant, and paint. The object of the invention could be achieved by a curable resin that has silicon atom-containing groups having a silicon atom bound to one or more hydrolysable groups such as alkoxy groups, acetoxy groups and oxim groups at the ends of the molecule , thioether and hydroxyl groups in the molecule, and a polymer having a polyoxyalkylene, (meth)acrylic ester, or hydrocarbon polymer as the main chain skeleton.

  本发明的目的是提供一种末端带有硅基的可固化树脂，它也是一种湿硬化树脂，使用时粘度较低，用于粘合剂、密封剂和涂料时具有优异的粘合性。本发明的目的可以通过以下方法实现：一种可固化树脂，其含有硅原子，硅原子与一个或多个可水解基团结合，如分子末端的烷氧基、乙酰氧基和肟基，分子中的硫醚和羟基，以及以聚氧亚烷基、（甲基）丙烯酸酯或烃类聚合物作为主链骨架的聚合物。