1,3-bis-(4-carbomethoxy-2,6-dichlorophenoxymethyl)-2,4,5,6-tetrabromobenzene | 64879-84-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis-(4-carbomethoxy-2,6-dichlorophenoxymethyl)-2,4,5,6-tetrabromobenzene
• 英文别名: methyl 3,5-dichloro-4-[[2,3,4,6-tetrabromo-5-[(2,6-dichloro-4-methoxycarbonylphenoxy)methyl]phenyl]methoxy]benzoate
• CAS: 64879-84-1
• 化学式: C₂₄H₁₄Br₄Cl₄O₆
• 分子量: 859.8
• InChiKey: SMLQSNFEMDQUMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  38
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  乙二醇甲醚 、 3.5-二氯-4-羟基苯甲酸甲酯 、 sodium hydroxide 、 1,2,3,5-四溴-4,6-二(溴甲基)苯 、 水 生成 1,3-bis-(4-carbomethoxy-2,6-dichlorophenoxymethyl)-2,4,5,6-tetrabromobenzene
  参考文献：
  名称：

  Linear or unsaturated polyesters prepared from bis-carbalkoxy compounds

  摘要：

  本发明涉及具有重复通式##STR1##的卤代聚酯，其中至少部分的R，例如1至100摩尔％，优选100摩尔％或2至10摩尔％，具有以下通式##STR2##和0至99摩尔％，优选0或90至98摩尔％的R对应于苯基基团和/或萘基基团和/或3至10个碳原子的烷基基团和/或环烷基团，其中R表示有机基团，该有机基团包含双价饱和醇中的分支或非分支饱和烷基基团，碳原子数为2至10，和/或环烷基团和/或源自含有羟基的烯二甲酸酯，优选为寡聚乙二酸酯和/或寡聚丙二酸酯和/或寡聚丁二酸酯，其中Z表示以下基团##STR3##，X表示氢、溴或氯，其中至少一部分的X为溴或氯，其中在某些情况下，聚酯中的一部分R是不饱和二羧酸衍生物的残基，该衍生物与乙烯基不饱和共聚物，优选为苯乙烯，能够形成过氧化物可固化的不饱和聚酯树脂（UP树脂）溶液，以及它们的制备以及作为阻燃成型组合物或制品的用途，以及某些可用于聚酯制备以及这些二羧酸酯制备的二羧酸酯。优选的是（2）中的二甲苯核被Br.sub.4.0至2.8和Cl.sub.0至1.2取代。

  公开号：

  US04152511A1

文献信息

• Linear or unsaturated polyesters prepared from bis-carbalkoxy compounds
  申请人：Dynamit Nobel Aktiengesellschaft

  公开号：US04152511A1

  公开（公告）日：1979-05-01

  The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g. 1 to 100 mole-%, preferably 100 mole-%, or 2 to 10 mole-%, are of the general formulas ##STR2## and 0 to 99 mole-%, preferably 0 or 90 to 98 mole-%, of the R's correspond to a phenylene radical and/or a naphthylene radical and/or an alkylene radical of 3 to 10 carbon atoms and/or a cycloalkylene radical, and the R's represent an organic moiety which is contained in bivalent saturated alcohols and corresponds to a branched or unbranched saturated alkylene radical of 2 to 10 carbon atoms and/or to a cycloalkylene radical and/or which is derived from an alkyleneterephthalate containing hydroxyl groups, preferably an oligomeric ethyleneterephthalate and/or an oligomeric propyleneterephthalate and/or an oligomeric butyleneterephthalate, wherein Z represents the groups ##STR3## and X represents hydrogen, bromine or chlorine, wherein at least some of the X's are bromine or chlorine, and in which polyesters, in some cases, a portion of the R's are residues of unsaturated dicarboxylic acid derivatives which, together with ethylenically unsaturated comonomers, preferably styrene, are capable of forming peroxide-curable unsaturated polyester resin (UP resin) solutions, and their preparation as well as their use as fire-retardant molding compositions or articles, and also dicarboxylic acid esters some of which can be used in the preparation of the polyesters as well as the preparation of these dicarboxylic acid esters. Preferably the xylene nucleus in (2) is substituted by Br.sub.4.0 to 2.8 and Cl.sub.0 to 1.2.

  本发明涉及具有重复通式##STR1##的卤代聚酯，其中至少部分的R，例如1至100摩尔％，优选100摩尔％或2至10摩尔％，具有以下通式##STR2##和0至99摩尔％，优选0或90至98摩尔％的R对应于苯基基团和/或萘基基团和/或3至10个碳原子的烷基基团和/或环烷基团，其中R表示有机基团，该有机基团包含双价饱和醇中的分支或非分支饱和烷基基团，碳原子数为2至10，和/或环烷基团和/或源自含有羟基的烯二甲酸酯，优选为寡聚乙二酸酯和/或寡聚丙二酸酯和/或寡聚丁二酸酯，其中Z表示以下基团##STR3##，X表示氢、溴或氯，其中至少一部分的X为溴或氯，其中在某些情况下，聚酯中的一部分R是不饱和二羧酸衍生物的残基，该衍生物与乙烯基不饱和共聚物，优选为苯乙烯，能够形成过氧化物可固化的不饱和聚酯树脂（UP树脂）溶液，以及它们的制备以及作为阻燃成型组合物或制品的用途，以及某些可用于聚酯制备以及这些二羧酸酯制备的二羧酸酯。优选的是（2）中的二甲苯核被Br.sub.4.0至2.8和Cl.sub.0至1.2取代。
• Bis-carbalkoxy compounds and their preparation
  申请人：Dynamit Nobel Aktiengesellschaft

  公开号：US04288607A1

  公开（公告）日：1981-09-08

  The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g. 1 to 100 mole-%, preferably 100 mole-%, or 2 to 10 mole-%, are of the general formulas ##STR2## and 0 to 99 mole-%, preferably 0 or 90 to 98 mole-%, of the R's correspond to a phenylene radical and/or a naphthylene radical and/or an alkylene radical of 3 to 10 carbon atoms and/or a cycloalkylene radical, and the R's represent an organic moiety which is contained in bivalent saturated alcohols and corresponds to a branched or unbranched saturated alkylene radical of 2 to 10 carbon atoms and/or to a cycloalkylene radical and/or which is derived from an alkyleneterephthalate containing hydroxyl groups, preferably an oligomeric ethyleneterephthalate and/or an oligomeric propyleneterephthalate and/or an oligomeric butyleneterephthalate, wherein Z represents the groups ##STR3## and X represents hydrogen, bromine or chlorine, wherein at least some of the X's are bromine or chlorine, and in which polyesters, in some cases, a portion of the R's are residues of unsaturated dicarboxylic acid derivatives which, together with ethylenically unsaturated comonomers, preferably styrene, are capable of forming peroxide-curable unsaturated polyester resin (UP resin) solutions, and their preparation as well as their use as fire-retardant molding compositions or articles, and also dicarboxylic acid esters some of which can be used in the preparation of the polyesters as well as the preparation of these dicarboxylic acid esters. Preferably the xylene nucleus in (2) is substituted by Br.sub.4.0 to 2.8 and Cl.sub.0 to 1.2.

  本发明涉及具有经常性一般式##STR1##的卤代聚酯，其中至少部分的R，例如1到100摩尔％，优选100摩尔％，或2到10摩尔％，具有以下一般式##STR2##和0到99摩尔％，优选0或90到98摩尔％，的R对应于苯基基团和/或萘基基团和/或3到10个碳原子的烷基基团和/或环烷基团，其中R表示存在于二价饱和醇中的有机基团，对应于2到10个碳原子的支链或直链饱和烷基基团和/或环烷基团和/或源自含有羟基的烷基对苯二甲酸酯，优选为寡聚乙烯对苯二甲酸酯和/或寡聚丙烯对苯二甲酸酯和/或寡聚丁烯对苯二甲酸酯，其中Z表示以下基团##STR3##，X表示氢、溴或氯，其中至少一些X为溴或氯，而在某些情况下，聚酯中的一部分R是不饱和二羧酸衍生物的残基，这些衍生物与乙烯基不饱和共聚物（优选为苯乙烯）一起能够形成过氧化物可固化的不饱和聚酯树脂（UP树脂）溶液，以及它们的制备以及它们作为阻燃成型组合物或制品的用途，还有一些二羧酸酯，其中一些可以用于聚酯的制备以及这些二羧酸酯的制备。优选的是（2）中的二甲苯核被Br.sub.4.0到2.8和Cl.sub.0到1.2取代。
• US4152511A
  申请人：——

  公开号：US4152511A

  公开（公告）日：1979-05-01
• US4288607A
  申请人：——

  公开号：US4288607A

  公开（公告）日：1981-09-08