4-Phenyl-octen-(4) | 105937-28-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Phenyl-octen-(4)
• 英文别名: Agn-PC-0ndckb；oct-4-en-4-ylbenzene
• CAS: 105937-28-8
• 化学式: C₁₄H₂₀
• 分子量: 188.313
• InChiKey: FZSDYLIYWMIVRI-UHFFFAOYSA-N

物化性质

• 沸点：
  262.9±7.0 °C(Predicted)
• 密度：
  0.870±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-辛炔 、 苯硼酸 在 rhodium-trilithiumsalt of 3,3,3-phosphane-triylbenzenecarboxylic acid/layered double hydroxides 作用下， 以 水 、 甲苯 为溶剂， 反应 3.0h， 以87%的产率得到4-Phenyl-octen-(4)
  参考文献：
  名称：

  Arylation of alkynes over hydrotalcite docked Rh-m-TPPTC complex

  摘要：

  Rh-m-TPPTC complex was successful immobilized onto a hydrotalcite Zn-Al to convert selectively in aqueous media both the symmetric and nonsymmetric alkynes into functionalized alkenes, with boronic acids. The complex preserved its activity after the ionic exchange, leading to excellent results (similar to 87%) for the symmetric alkynes and also for the non-symmetrical alkynes (up to 99%). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cattod.2014.07.004

文献信息

• Arylation of alkynes over hydrotalcite docked Rh-m-TPPTC complex
  作者：Florentina Neaţu、Mădălina Ciobanu、Laura E. Ştoflea、Ligia Frunză、Vasile I. Pârvulescu、Véronique Michelet

  DOI：10.1016/j.cattod.2014.07.004

  日期：2015.6

  Rh-m-TPPTC complex was successful immobilized onto a hydrotalcite Zn-Al to convert selectively in aqueous media both the symmetric and nonsymmetric alkynes into functionalized alkenes, with boronic acids. The complex preserved its activity after the ionic exchange, leading to excellent results (similar to 87%) for the symmetric alkynes and also for the non-symmetrical alkynes (up to 99%). (C) 2014 Elsevier B.V. All rights reserved.