2-甲氧基-6-丙基萘 | 94134-18-6

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-甲氧基-6-丙基萘
• 中文别名: 2-丙基-6-甲氧基萘
• 英文名称: 1-(6'-methoxy-2'-naphthyl)-propane
• 英文别名: 2-methoxy-6-propylnaphthalene；methyl-(6-propyl-[2]naphthyl)-ether；Methyl-(6-propyl-[2]naphthyl)-aether；6-Methoxy-2-propyl-naphthalin；2-Methoxy-6-n-propylnaphthalin
• CAS: 94134-18-6
• 化学式: C₁₄H₁₆O
• 分子量: 200.28
• InChiKey: DEMSTJLFNCGWTN-UHFFFAOYSA-N

物化性质

• 熔点：
  49-50℃
• 沸点：
  317℃
• 密度：
  1.017
• 闪点：
  125℃

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2922299090
• 储存条件：
  2-8℃

反应信息

• 作为反应物：
  描述：

  2-甲氧基-6-丙基萘 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以55.1 g的产率得到6-丙基-2-萘酚
  参考文献：
  名称：

  新規液晶性化合物及びそれを用いた液晶組成物

  摘要：

  【问题】提供一种粘度低、异构转移温度高、高相容性、高折射率异性和不易因热和光而劣化的液晶化合物。 【解决方案】提供了一种萘衍生物，其可由下式反应得到，具有一般式（1）。液晶组成物包括该萘衍生物。使用该液晶化合物的液晶组成物可提供高速响应的液晶显示器件。 【选择图】无

  公开号：

  JP2016008207A
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 、 二乙二醇 作用下， 生成 2-甲氧基-6-丙基萘
  参考文献：
  名称：

  Orientation in Friedel-Crafts Reactions with 2-Methoxy-1-methylnaphthalene

  摘要：

  DOI：

  10.1021/jo01359a015

文献信息

• Naphthalene derivative and liquid crystal composition comprising the same
  申请人：Dainippon Ink and Chemicals, Inc.

  公开号：US06468607B1

  公开（公告）日：2002-10-22

  Disclosed is a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accordingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal composition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

  本公开了一种新型液晶化合物，它是一种萘衍生物，可用作电光液晶显示材料，包含这种萘衍生物的液晶组合物以及包括它们的液晶显示装置。本发明提供的萘衍生物表现出优异的液晶性能，并且与目前广泛使用的液晶组合物或配方具有良好的相溶性。添加萘衍生物可以显著降低液晶组合物的阈值电压，同时保持其高响应速度。本发明的萘衍生物具有较大的双折射指数。此外，大多数本发明的萘衍生物分子中没有强极性基团，因此也可用于有源矩阵驱动。此外，如前述示例所示，本发明的萘衍生物易于生产，无色且化学稳定。因此，包括本发明的萘衍生物的液晶组合物非常有用，特别是在广泛温度范围内运行且需要高速响应和低电压驱动的液晶组合物。
• Process for preparing esters of aryl alkanoic acids
  申请人：Zambon S.p.A.

  公开号：US04501913A1

  公开（公告）日：1985-02-26

  Process for preparing esters of aryl alkanoic acids via oxidation of the corresponding ketones with bromine or iodine in the presence of a metal halide and an alcohol. The thus obtained esters are then easily hydrolized to give the corresponding aryl alkanoic acids which are particularly useful as anti-inflammatory, analgesic and anti-pyretic agents.

  通过在金属卤化物和醇的存在下，用溴或碘氧化相应的酮，制备芳基脂肪酸酯的过程。然后，得到的酯类化合物可以轻松水解为相应的芳基脂肪酸，这些化合物特别适用于抗炎、止痛和退热剂。
• Fluorescent Substrates for Monoamine Transporters as Optical False Neurotransmitters
  申请人：Gubernator Niko Gert

  公开号：US20100035279A1

  公开（公告）日：2010-02-11

  The present invention relates to compounds of the general structure: wherein Y is O, X is O, bond α is absent and bond β is present, or Y is H, X is CH, bond α is present, and bond β is absent; atom Z is a carbon and bonds χ, δ and γ are present, or is a nitrogen and bonds χ, δ and γ are absent; R 1 is —H, —OH, —O—R 7 , —N(H)—R 8 , —N(H)—(CH 2 ) n —NH 2 , —N(R 9 )(R 10 ), or a piperazine cation; R 2 is either covalently bound to R 9 , or is —H, or is covalently bound to R 3 so as to form a substituted or unsubstituted pyrrole or R 2 is covalently bound to R 9 or R 8 or R 7 ; or R 1 and R 2 are covalently joined to form an aromatic ring; R 3 is either covalently bound to R 2 so as to form a pyrrole, or is, inter alia, —H, —OH, alkyl, or when Z is nitrogen R 3 is ═O; R 4 is, inter alia, —H, —OH, or —R 11 NH 2 ; R 5 is, inter alia, —H, —OH, or —R 12 NH 2 , and R 6 is either is covalently bound to R 10 or is —H, or R 6 is covalently bound to R 10 or R 8 or R 7 . This invention also provides processes for making the compounds as well as methods for monitoring activity of monoamine transporters or treating monoamine transporter-associated diseases by employing the compounds.

  本发明涉及一般结构的化合物：其中Y为O，X为O，α键不存在且β键存在，或者Y为H，X为CH，α键存在且β键不存在；原子Z为碳，键χ，δ和γ存在，或为氮，键χ，δ和γ不存在；R1为-H，-OH，-O-R7，-N（H）-R8，-N（H）-（CH2）n-NH2，-N（R9）（R10）或哌嗪阳离子；R2要么与R9共价结合，要么为-H，要么与R3共价结合以形成取代或未取代的吡咯，或者R2与R9或R8或R7共价结合形成芳香环；R1和R2共价结合形成芳香环；R3要么与R2共价结合形成吡咯，要么为-H，-OH，烷基，或当Z为氮时，R3为═O；R4为-H，-OH或-R11NH2；R5为-H，-OH或-R12NH2，R6要么与R10共价结合，要么为-H，或者R6与R10或R8或R7共价结合。本发明还提供制备这些化合物的方法，以及利用这些化合物监测单胺转运体活性或治疗单胺转运体相关疾病的方法。
• FLUORESCENT SUBSTRATES FOR MONOAMINE TRANSPORTERS AS OPTICAL FALSE NEUROTRANSMITTERS
  申请人：of New York The Trustees of Columbia University in the City

  公开号：US20130190497A1

  公开（公告）日：2013-07-25

  The present invention relates to compounds of the general structure: wherein Y is O, X is O, bond α is absent and bond β is present, or Y is H, X is CH, bond α is present, and bond β is absent; atom Z is a carbon and bonds χ, δ and γ are present, or is a nitrogen and bonds χ, δ and γ are absent; R 1 is —H, —OH, —O—R 7 , —N(H)—R 8 , —N(H)—(CH 2 ) n —NH 2 , —N(R 9 )(R 10 ), or a piperazine cation; R 2 is either covalently bound to R 9 , or is —H, or is covalently bound to R 3 so as to form a substituted or unsubstituted pyrrole or R 2 is covalently bound to R 9 or R 8 or R 7 ; or R 1 and R 2 are covalently joined to form an aromatic ring; R 3 is either covalently bound to R 2 so as to form a pyrrole, or is, inter alia, —H, —OH, alkyl, or when Z is nitrogen R 3 is ═O; R 4 is, inter alia, —H, —OH, or —R 11 NH 2 ; R 5 is, inter alia, —H, —OH, or —R 12 NH 2 , and R 6 is either is covalently bound to R 10 or is —H, or R 6 is covalently bound to R 10 or R 8 or R 7 . This invention also provides processes for making the compounds as well as methods for monitoring activity of monoamine transporters or treating monoamine transporter-associated diseases by employing the compounds.

  本发明涉及以下通用结构的化合物：其中Y为O，X为O，键α不存在，键β存在，或Y为H，X为CH，键α存在，键β不存在；原子Z为碳并存在键χ，δ和γ，或为氮并不存在键χ，δ和γ；R1为—H，—OH，—O—R7，—N(H)—R8，—N(H)—(CH2)n—NH2，—N(R9)(R10)，或哌嗪阳离子；R2要么与R9共价结合，要么为—H，要么与R3共价结合以形成取代或未取代的吡咯，或R2与R9或R8或R7共价结合；或R1和R2共价结合以形成芳香环；R3要么与R2共价结合以形成吡咯，要么为—H，—OH，烷基，或者当Z为氮时，R3为═O；R4为—H，—OH，或—R11NH2；R5为—H，—OH，或—R12NH2，R6要么与R10共价结合，要么为—H，要么与R10或R8或R7共价结合。本发明还提供制备这些化合物的方法以及利用这些化合物监测单胺转运体活性或治疗单胺转运体相关疾病的方法。
• Desai; Waravdekar, Proceedings - Indian Academy of Sciences, Section A, 1946, vol. <A> 24, p. 382,385
  作者：Desai、Waravdekar

  DOI：——

  日期：——