1,3-bis[2-(m-phenoxybenzylideneamino)ethyl]adamantane | 482356-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis[2-(m-phenoxybenzylideneamino)ethyl]adamantane
• 英文别名: 1,3-Bis[2-(m-phenoxybenzylideneamino)ethyl]-adamantane；1-(3-phenoxyphenyl)-N-[2-[3-[2-[(3-phenoxyphenyl)methylideneamino]ethyl]-1-adamantyl]ethyl]methanimine
• CAS: 482356-74-1
• 化学式: C₄₀H₄₂N₂O₂
• 分子量: 582.786
• InChiKey: IHICVBNAWFFULT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  44
• 可旋转键数：
  12
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-bis[2-(m-phenoxybenzylideneamino)ethyl]adamantane 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以81%的产率得到N-[(3-phenoxyphenyl)methyl]-2-[3-[2-[(3-phenoxyphenyl)methylamino]ethyl]-1-adamantyl]ethanamine
  参考文献：
  名称：

  摘要：

  New Schiff bases containing both adamantyl and phenyl fragments in a single molecule were synthesized by condensation of appropriate diamines with aromatic aldehydes. The condensation products were brought into reduction and nucleophilic addition reactions.

  DOI：

  10.1023/a:1016321823035
• 作为产物：
  描述：

  1,3-金刚烷二乙胺 、 间苯氧基苯甲醛 以 乙醇 为溶剂， 以92%的产率得到1,3-bis[2-(m-phenoxybenzylideneamino)ethyl]adamantane
  参考文献：
  名称：

  摘要：

  New Schiff bases containing both adamantyl and phenyl fragments in a single molecule were synthesized by condensation of appropriate diamines with aromatic aldehydes. The condensation products were brought into reduction and nucleophilic addition reactions.

  DOI：

  10.1023/a:1016321823035

文献信息

• ——
  作者：Yu. V. Popov、T. K. Korchagina、G. V. Chicherina、T. A. Ermakova

  DOI：10.1023/a:1016321823035

  日期：——

  New Schiff bases containing both adamantyl and phenyl fragments in a single molecule were synthesized by condensation of appropriate diamines with aromatic aldehydes. The condensation products were brought into reduction and nucleophilic addition reactions.