4-methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-sulfide | 36044-21-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-sulfide
• 英文别名: 2,3-dihydro-4-methyl-1-phenyl-1H-phosphole, 1-sulfide；1-Thio-1-phenyl-3-methyl-phospholin-2；1-Thio-1-phenyl-3-methylphospholin-2；4-Methyl-1-phenyl-1-sulfanylidene-2,3-dihydro-1lambda5-phosphole；4-methyl-1-phenyl-1-sulfanylidene-2,3-dihydro-1λ5-phosphole
• CAS: 36044-21-0
• 化学式: C₁₁H₁₃PS
• 分子量: 208.264
• InChiKey: SKFCQJBHMSKMCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-chloro-3-methyl-2-phospholene 1-oxide 在 tetraphosphorus decasulfide 作用下， 以 四氢呋喃 、 苯 为溶剂， 反应 26.0h， 生成 4-methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-sulfide
  参考文献：
  名称：

  新型1-（取代的苯氧基/苯基）-2-膦烯和膦酰基1-氧化物衍生物的合成与表征

  摘要：

  描述了新颖的1-（取代的苯氧基/苯基）-2-膦和膦酰基1-氧化物衍生物的合成，它们是具有磷原子代替普通糖的环氧的糖的类似物。所有合成的衍生物均通过多核NMR，质量和IR光谱数据，元素和X射线晶体学分析进行结构表征。

  DOI：

  10.1002/jhet.5570390109

文献信息

• MOLDING MATERIAL, METHOD FOR PRODUCING SAME, AND MASTER BATCH USED IN SAME
  申请人：Toray Industries, Inc.

  公开号：EP3048137A1

  公开（公告）日：2016-07-27

  The present invention is: a molding material comprising, 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50°C, and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C); a production method for obtaining the molding material; and a master batch suitably used in the production method.

  本发明是一种模塑材料，包括 5 至 50 份（按重量计）沉积有上浆剂（s）的增强纤维 （A）、1 至 20 份（按重量计）含有聚碳二亚胺化合物（B-1）的组分（B）（B-1 在 50°C 时为液态）以及 30 至 94 份（按重量计）热塑性树脂（C）（C-1 的主链重复单元结构中含有碳元素以外的元素）、以组分（A）至（C）的总质量为 100 份为基准，其中模塑材料为复合材料，在该复合材料中，组分（A）浸渍组分（B）的复合纤维束（D）被组分（C）覆盖；一种获得模塑材料的生产方法；以及一种适用于该生产方法的母料。
• FIBER-REINFORCED RESIN COMPOSITION, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP3064551A1

  公开（公告）日：2016-09-07

  Provided are a fiber-reinforced resin composition which includes a polyarylene sulfide (A), a carbodiimide compound (B) and carbon fibers (C) in specific blending amounts and in which the carbon fibers (C) are surface-treated with a sizing agent (D), the carbodiimide compound (B) is an aliphatic carbodiimide compound, and the sizing agent (D) is a compound having three or more specific functional groups in one molecule; and a fiber-reinforced composite material which includes a thermoplastic resin (A'), an adhesive compound (B') and reinforcing fibers (C') and in which the adhesive compound (B') is a compound having two or more specific structures in one molecule, the thermoplastic resin (A') is a thermoplastic resin containing an element other than carbon in a repeating unit structure of a main chain, and an abundance ratio Rb of the adhesive compound (B') is 1.2 or more.

  提供了一种纤维增强树脂组合物，该组合物包括特定混合量的聚芳基硫醚（A）、碳化二亚胺化合物（B）和碳纤维（C），其中碳纤维（C）用上浆剂（D）进行表面处理，碳化二亚胺化合物（B）是脂肪族碳化二亚胺化合物，上浆剂（D）是在一个分子中具有三个或更多特定官能团的化合物；一种纤维增强复合材料，包括热塑性树脂（A'）、粘合剂化合物（B'）和增强纤维（C'），其中粘合剂化合物（B'）是一种在一个分子中具有两个或两个以上特定结构的化合物，热塑性树脂（A'）是一种在主链的重复单元结构中含有碳元素以外的元素的热塑性树脂，粘合剂化合物（B'）的丰度比 Rb 为 1.2 或更多。
• Method of producing carbon fiber-reinforced polyarylene sulfide
  申请人：Toray Industries, Inc.

  公开号：US10017613B2

  公开（公告）日：2018-07-10

  A carbon fiber-reinforced polyarylene sulfide has both dynamic characteristics and molding cycle characteristics and can be produced with high productivity by preparing a polycarbodiimide-modified polyarylene sulfide using a polyarylene sulfide and a polycarbodiimide as raw materials, then melting the resulting polycarbodiimide-modified polyarylene sulfide, and combining the polycarbodiimide-modified polyarylene sulfide with carbon fibers at a specific ratio to produce a composite.

  碳纤维增强聚芳基硫醚具有动态特性和成型周期特性，可以通过以下方法以较高的生产率生产：以聚芳基硫醚和聚碳二亚胺为原料制备聚碳二亚胺改性聚芳基硫醚，然后熔化所得的聚碳二亚胺改性聚芳基硫醚，再将聚碳二亚胺改性聚芳基硫醚与碳纤维按特定比例混合制成复合材料。
• Molding material, method of producing same, and master batch used in same
  申请人：Toray Industries, Inc.

  公开号：US10093802B2

  公开（公告）日：2018-10-09

  A molding material includes 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50° C., and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C).

  一种成型材料包括 5 至 50 份（按重量计）沉积有上浆剂（s）的增强纤维（A）、1 至 20 份（按重量计）含有聚碳二亚胺化合物（B-1）的组分（B）（B-1 在 50 摄氏度时为液态）和 30 至 94 份（按重量计）热塑性树脂（C）（C-1 的主链重复单元结构中含有碳元素以外的元素）、以 100 份组分（A）至（C）的总质量为基准，30 至 94 份热塑性树脂（C），其中模塑材料是一种复合材料，在该复合材料中，组分（A）浸渍在组分（B）上的复合纤维束（D）被组分（C）覆盖。
• Fiber-reinforced resin composition, and fiber-reinforced composite material
  申请人：Toray Industries, Inc.

  公开号：US10308775B2

  公开（公告）日：2019-06-04

  A fiber-reinforced resin composition includes a polyarylene sulfide (A), a carbodiimide compound (B) and carbon fibers (C) in specific blending amounts and in which the carbon fibers (C) are surface-treated with a sizing agent (D), the carbodiimide compound (B) is an aliphatic carbodiimide compound, and the sizing agent (D) is a compound having three or more specific functional groups in one molecule; and a fiber-reinforced composite material includes a thermoplastic resin (A′), an adhesive compound (B′) and reinforcing fibers (C′) and in which the adhesive compound (B′) is a compound having two or more specific structures in one molecule, the thermoplastic resin (A′) is a thermoplastic resin containing an element other than carbon in a repeating unit structure of a main chain, and an abundance ratio Rb of the adhesive compound (B′) is 1.2 or more.

  一种纤维增强树脂组合物包括聚芳基硫醚（A）、碳化二亚胺化合物（B）和碳纤维（C），其中碳纤维（C）以上浆剂（D）进行表面处理，碳化二亚胺化合物（B）是脂肪族碳化二亚胺化合物，上浆剂（D）是在一个分子中具有三个或三个以上特定官能团的化合物；纤维增强复合材料包括热塑性树脂（A′）、粘合剂化合物（B′）和增强纤维（C′），其中粘合剂化合物（B′）是在一个分子中具有两个或两个以上特定结构的化合物、热塑性树脂(A′)是一种在主链的重复单元结构中含有碳以外元素的热塑性树脂，粘合剂化合物(B′)的丰度比Rb为1.2或更多。