2-Benzoyl-benzoldiazonium | 36367-99-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Benzoyl-benzoldiazonium
• 英文别名: 2-Diazobenzophenon-Kation；2-Diazo-benzophenon；2-Diazobenzophenon；2-Benzoylbenzene-1-diazonium；2-benzoylbenzenediazonium
• CAS: 36367-99-4
• 化学式: C₁₃H₉N₂O
• 分子量: 209.227
• InChiKey: VILRWFDQMKOZGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Benzoyl-benzoldiazonium 在 sodium azide 作用下， 生成 (2-azidophenyl)(phenyl)methanone
  参考文献：
  名称：

  量热技术探讨五种邻位取代叠氮苯的热分解

  摘要：

  2-叠氮基苯基甲醇（1），2-叠氮基苯甲醛（2），1-（2-叠氮基苯基）-1-乙酮（3），（2-叠氮基苯基）（苯基）甲酮（4）和1的热分解（TD）通过DSC，TG和C80量热技术在氧化和非氧化条件下分析了-叠氮基-2-硝基苯（5）。众所周知，这些叠氮化物在溶液中的TD可以以高收率得到相应的苯并恶唑，但叠氮化物1除外。当考虑固相和“溶液相” TD反应的结果以及EI-MS实验的结果时，有足够的信息可用来估算叠氮化物的固有分子反应性（MIR）。

  DOI：

  10.1007/s10973-009-0572-8
• 作为试剂：
  描述：

  1-萘甲醇 在 2,4,6-trifluoromethylpyridine 、 RuL₃⁽²⁺⁾ 2-Benzoyl-benzoldiazonium 作用下， 以 乙腈 为溶剂， 反应 0.33h， 以61%的产率得到1-萘甲醛
  参考文献：
  名称：

  Photo-oxidation of some carbinols by the Ru(II) polypyridyl complex-aryl diazonium salt system

  摘要：

  DOI：

  10.1016/s0040-4039(01)81614-2

文献信息

• JPH07206754A
  申请人：——

  公开号：JPH07206754A

  公开（公告）日：1995-08-08
• METHOD FOR PREPARING AN ORGANIC FILM AT THE SURFACE OF SOLID SUPPORT UNDER NON-ELECTROCHEMICAL CONDITIONS, SOLID SUPPORT THUS OBTAINED AND PREPARATION KIT
  申请人：Mevellec Vincent

  公开号：US20080145706A1

  公开（公告）日：2008-06-19

  This invention relates to a method for preparing an organic film at the surface of a solid support, with a step of contacting said surface with a liquid solution including (i) at least one protic solvent, (ii) at least one adhesion primer, under non-electrochemical conditions, and allowing the formation of radical entities based on the adhesion primer. The liquid solution can also include (iii) at least one monomer different from the adhesion primer and radically polymerisable. This invention also relates to a non-electrically-conductive solid support on which an organic film according to said method is grafted, and a kit for preparing an essentially polymeric organic film at the surface of a solid support.
• METHOD FOR PREPARING AN ORGANIC FILM AT THE SURFACE OF A SOLID SUPPORT UNDER NON-ELECTROCHEMICAL CONDITIONS, SOLID SUPPORT THUS OBTAINED AND PREPARATION KIT
  申请人：Mevellec Vincent

  公开号：US20080193668A1

  公开（公告）日：2008-08-14

  This invention relates to a method for preparing an organic film at the surface of a solid support, with a step of contacting said surface with a liquid solution including (i) at least one solvent, (ii) at least one adhesion primer, under non-electrochemical conditions, and allowing the formation of radical entities based on the adhesion primer. The liquid solution can also include (iii) at least one monomer different from the adhesion primer and radically polymerizable. This invention also relates to a non-electrically-conductive solid support on which an organic film according to said method is grafted, and a kit for preparing an essentially polymeric organic film at the surface of a solid support.
• US8709542B2
  申请人：——

  公开号：US8709542B2

  公开（公告）日：2014-04-29
• US9725602B2
  申请人：——

  公开号：US9725602B2

  公开（公告）日：2017-08-08