2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol | 51543-47-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol
• 英文别名: 2,6,2',6'-Tetrachlor-4,4'-sulfandiyl-di-phenol；Bis-(3.5-dichlor-4-hydroxy-phenyl)-sulfid；bis(4-hydroxy-3,5-dichlorophenyl)-sulfide；2,6-Dichloro-4-(3,5-dichloro-4-hydroxyphenyl)sulfanylphenol
• CAS: 51543-47-6
• 化学式: C₁₂H₆Cl₄O₂S
• 分子量: 356.056
• InChiKey: JRHRZBYASNPOOS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,6-二氯苯酚 在 四氯化碳 、 三氯化铝 、 二氯化硫 作用下， 生成 2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol
  参考文献：
  名称：

  DE583055

  摘要：

  公开号：

文献信息

• Process for producing an aromatic polyester
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0097890A2

  公开（公告）日：1984-01-11

  In a process for producing an aromatic polyester by an interfacial polycondensation reaction in which an aqueous alkaline solution containing a bisphenol represented by the general formula and phenolphthalein in a molar ratio of the former to the latter of from 10 : 90 to 97 : 3, is catalytically reacted with an organic solvent solution of isophthalic acid dichloride and/or terephthalic acid dichloride, an improvement wherein at least one compound selected from the group consisting of the following (a), (b), (c), (d) and (e) is used as the catalyst: (a) a compound represented by the general formula (b) a compound represented by the general formuld (c) a compound represented by the general formula (d) a compound represented by the general formula and (e) a compound represented by the general formula

  在一种通过界面缩聚反应生产芳香族聚酯的工艺中，含有通式所代表的双酚和酚酞的碱性水溶液（前者与后者的摩尔比为 10 : 90 至 97 : 3）与间苯二甲酸二氯化物和/或间苯二甲酸二氯化物的有机溶剂溶液进行催化反应。 和酚酞（前者与后者的摩尔比为 10 : 90 至 97 : 3）的碱性水溶液与间苯二甲酸二氯化物和/或对苯二甲酸二氯化物的有机溶剂溶液进行催化反应，其中至少一种从以下(a)、(b)、(c)、(d)和(e)组成的组中选出的化合物用作催化剂的改进： (a) 由通式表示的化合物 (b) 通式d 所代表的化合物 (c) 由通式表示的化合物 (d) 由通式代表的化合物 及 (e) 由通式代表的化合物
• Aromatic polyethers, fluorescent resin compositions containing same, and processes for preparing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0336420A2

  公开（公告）日：1989-10-11

  Aromatic polyether having a recurring unit as represented by following general formula [I]: The aromatic polyethers are excellent in mechanical properties and solvent resistance and high in glass transition temperature as well as strong in fluorescence generated. They are useful as engineering resins and suitable for use with materials for parts and display materials applicable to the electric and electronic, mechanical field, and automobile fields. The fluorescent resin compositions made of the aromatic polyethers are likewise excellent in thermal resistance and easy in manufacturing. Furthermore, they have their own ability of generating fluorescence, causing no bleeding of a fluorescent substance added. They are also extremely useful industrially as materials for parts and display materials for use in the electric, electronic, mechanical, optic, automobile and other fields as well as decorative materials and molding materials for toys.

  具有以下通式[I]所代表的递归单元的芳香族聚醚： 这种芳香族聚醚具有优异的机械性能和耐溶剂性，玻璃化温度高，荧光强度大。它们可用作工程树脂，适用于电子电气、机械和汽车领域的零件材料和显示材料。 由芳香族聚醚制成的荧光树脂组合物同样具有出色的耐热性，并且易于制造。此外，它们本身具有产生荧光的能力，不会造成添加的荧光物质渗出。在工业上，它们也非常有用，可用作电气、电子、机械、光学、汽车和其他领域的零件材料和显示材料，以及玩具的装饰材料和成型材料。
• Polycarbonate resin solution for film formation by casting
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0500128A2

  公开（公告）日：1992-08-26

  A polycarbonate resin solution for use in film formation by casting and a process for producing the same are disclosed. The polycarbonate resin solution comprising an organic solvent and dissolved therein a random copolycarbonate having a structural unit of formula (1) and a structural unit of formula (2), with the molar ratio of the structural unit of formula (1) to that of the formula (2) being from 35/65 to 65/35, and the polycarbonate resin having a viscosity average molecular weight of from 15,000 to 100,000.

  本发明公开了一种用于浇铸成膜的聚碳酸酯树脂溶液及其生产工艺。该聚碳酸酯树脂溶液由有机溶剂和溶解于其中的无规共聚碳酸酯组成，无规共聚碳酸酯具有式（1）的结构单元和式（2）的结构单元，式（1）的结构单元与式（2）的结构单元的摩尔比为 35/65 至 65/35，聚碳酸酯树脂的粘度平均分子量为 15,000 至 100,000。
• Flame-retardant polybutylene terephthalate resin composition
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0516351A2

  公开（公告）日：1992-12-02

  A flame-retardant polybutylene terephthalate resin composition suitable for a material of a contact-bearing electrical part which generates an organic gas and a halogenous corrosive gas each in a reduced amount and therefore hardly corrodes the metal constituting the contact even after prolonged use, which comprises (A) 100 parts by weight of a polybutylene terephthalate resin having an intrinsic viscosity of 0.75 to 1.5 dL/g, (B) 1 to 50 parts by weight of a halogenated phenoxy compound composed of repeating units represented by the general formula (1) and having a number-average degree of polymerisation of 6 to 30: wherein X represents a bromine or chlorine atom; and Y represents alkylene having 1 to 10 carbon atoms, alkylidene, cycloalkane, carbonyl, -O-, -S- or -SO2-, (C) 0.1 to 30 parts by weight of an antimony compound containing antimony pentoxide and an alkali metal oxide as constituents, (D) 0.01 to 10 parts by weight of a fatty acid ester of a polyhydric alcohol, and (E) 0 to 150 parts by weight of a filler.

  一种阻燃性聚对苯二甲酸丁二酯树脂组合物，适用于接点承载电气部件的材料，该组合物产生的有机气体和卤素腐蚀性气体的量都较少，因此即使长期使用也几乎不会腐蚀构成接点的金属，它包括 (A) 100 重量份的聚对苯二甲酸丁二醇酯树脂，其固有粘度为 0.75 至 1.5 dL/g、 (B) 1 至 50 重量份的卤代苯氧基化合物，该化合物由通式(1)代表的重复单 元组成，平均聚合度为 6 至 30： 其中 X 代表溴原子或氯原子；Y 代表具有 1 至 10 个碳原子的亚烷基、亚烷基、环 烷基、羰基、-O-、-S- 或-SO2-、 (C) 0.1 至 30 重量份的锑化合物，其成分含有五氧化二锑和碱金属氧化物、 (D) 以重量計 0.01 至 10 份的多元醇脂肪酸酯，及 (E) 0 至 150 份（重量比）填料。
• Flame retarded polyester resin composition
  申请人：Kanegafuchi Chemical Industry Co., Ltd.

  公开号：EP0601226A1

  公开（公告）日：1994-06-15

  The flame retarded polyester resin composition of this invention comprises (A) 10-90% by weight of a polycarbonate, (B) 10-90% by weight of a thermoplastic polyester, 0-40% by weight of an impact modifier, and based on 100 parts by weight of (A), (B) and (C) combined, (D) 1 to 50 parts by weight of a certain halogenated phenoxy resin and (E) 0-30 parts by weight of an antimony compound. The resin composition of the invention is satisfactory in moldability and provides flame-retarded moldings having very satisfactory impact resistance, heat distortion resistance, flexural modulus, weather resistance and chemical resistance.

  本发明的阻燃聚酯树脂组合物包括：(A) 10-90%（重量）的聚碳酸酯；(B) 10-90%（重量）的热塑性聚酯；0-40%（重量）的抗冲改性剂；以及以 100 份（重量）的(A)、(B)和(C)的总和为基础，(D) 1-50份（重量）的某种卤代苯氧基树脂和(E) 0-30份（重量）的锑化合物。本发明的树脂组合物具有令人满意的模塑性，可提供阻燃模塑件，其抗冲击性、抗热变形性、弯曲模量、耐候性和耐化学性都非常令人满意。