pyrrolidinomethylthiourea | 873543-24-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: pyrrolidinomethylthiourea
• 英文别名: N-pyrrolidinomethylthiourea；Pyrrolidinomethyl thiourea；pyrrolidin-1-ylmethylthiourea
• CAS: 873543-24-9
• 化学式: C₆H₁₃N₃S
• 分子量: 159.255
• InChiKey: AAEXRWGIAWCZQZ-UHFFFAOYSA-N

物化性质

• 沸点：
  257.0±42.0 °C(Predicted)
• 密度：
  1.181±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  73.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  K₃Na[W(CN)₄O₂]·6H₂O 、 pyrrolidinomethylthiourea 、 双(三苯基正膦基)氯化铵 在 acetic acid 作用下， 以 乙醇 、 水 为溶剂， 生成 [bis(triphenylphosphine)iminium][WO(CN)3(N-pyrrolidinomethylthiourea)]*3H2O
  参考文献：
  名称：

  Synthesis and characterization of cyano complexes of oxotungsten(IV) with morpholinomethyl urea and related ligands

  摘要：

  The synthesis and characterization of complexes, (Ph3P)(2)NH2[WO(CN)(3)L-L] center dot 3H(2)O and Cs[WO(CN)(3)L-L] center dot H2O (where L-L = morpholinomethylurea, morpholinomethylthiourea, piperidinomethylurea, piperidinomethylthiourea, pyrrolidinomethylurea, and pyrrolidinomethythiourea) are presented. The complexes have been prepared by the reaction of K3Na[WO2(CN)(4)] center dot 6H(2)O with morpholinomethylurea and related ligands in aqueous solution around a pH of 7. These have been isolated as bis(triphenylphospine)imminium or cesium salts. The complexes have been characterized by elemental analysis, IR, UV-Vis spectra, magnetic susceptibility and conductivity measurements in addition to TGA/DTA.

  DOI：

  10.1134/s0036023606090075

文献信息

• Synthesis and characterization of some oxodiperoxo molybdenum(VI) complexes of Morpholinomethyl urea and related ligands
  作者：H. N. Sheikh、A. Hussain、B. L. Kalsotra

  DOI：10.1134/s003602360605007x

  日期：2006.5

  The oxodiperoxo complexes of Mo(VI) of the type [MoO(O-2)(2)L], where L = Morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl urea, and pyrrolidinomethyl thiourea have been synthesized and characterized by elemental analysis, molar conductance, IR, UV-Vis, and TGA/DTA techniques. It is shown that the ligands coordinate to the metal ion in a symmetrical bidentate fashion through heterocyclic nitrogen and carbonyl oxygen or thiocarbonyl sulfur. Thermal studies indicate continuous weight loss until a stable oxide is formed.
• Synthesis and characterization of cyano complexes of oxotungsten(IV) with morpholinomethyl urea and related ligands
  作者：M. S. Pathania、H. N. Sheikh、B. L. Kalsotra

  DOI：10.1134/s0036023606090075

  日期：2006.9

  The synthesis and characterization of complexes, (Ph3P)(2)NH2[WO(CN)(3)L-L] center dot 3H(2)O and Cs[WO(CN)(3)L-L] center dot H2O (where L-L = morpholinomethylurea, morpholinomethylthiourea, piperidinomethylurea, piperidinomethylthiourea, pyrrolidinomethylurea, and pyrrolidinomethythiourea) are presented. The complexes have been prepared by the reaction of K3Na[WO2(CN)(4)] center dot 6H(2)O with morpholinomethylurea and related ligands in aqueous solution around a pH of 7. These have been isolated as bis(triphenylphospine)imminium or cesium salts. The complexes have been characterized by elemental analysis, IR, UV-Vis spectra, magnetic susceptibility and conductivity measurements in addition to TGA/DTA.