2-苯甲酰基-N,N-双(2-羟乙基)苯甲酰胺 | 6265-88-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-苯甲酰基-N,N-双(2-羟乙基)苯甲酰胺
• 英文名称: 2-benzoyl-N,N-bis-(2-hydroxy-ethyl)-benzamide
• 英文别名: 2-Benzoyl-n,n-bis(2-hydroxyethyl)benzamide
• CAS: 6265-88-9
• 化学式: C₁₈H₁₉NO₄
• 分子量: 313.353
• InChiKey: FUOQNBFLMZOEQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  77.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(苯甲酰基)苯甲酰氯 、 二乙醇胺 以 四氢呋喃 为溶剂， 反应 20.0h， 生成 2-苯甲酰基-N,N-双(2-羟乙基)苯甲酰胺
  参考文献：
  名称：

  [EN] DEGRADATION ACCELERATOR FOR POLYMERS AND POLYMER ARTICLE COMPRISING IT
  [FR] ACCÉLÉRATEUR DE DÉGRADATION POUR DES POLYMÈRES ET ARTICLE POLYMÈRE LE COMPRENANT

  摘要：

  公开了一种改善天然和/或合成聚合物或由这些聚合物制成的聚合物制品在光线和/或热量和/或湿度作用下降解的方法，包括将式(I)的化合物并入所述天然和/或合成聚合物中：式(I)；其中m为1或2，n为1至100，X从特定苯基酮衍生物中选择，R，R1，R2分别从特定残基列表中选择；所述式(I)的新化合物和在存在光线和/或热量和/或湿度时具有改善降解性能的聚合物制品由包括以下成分的组合物制成：A) 天然和/或合成聚合物和B) 一种降解加速剂，该加速剂是所述式(I)的化合物。

  公开号：

  WO2009016083A1

文献信息

• NOVEL POLYMERIC PHOTOINITIATORS AND PHOTOINITIATOR MONOMERS
  申请人：Coloplast A/S

  公开号：US20150148441A1

  公开（公告）日：2015-05-28

  The present invention provides polymeric photoinitiators being co-polymers of photoinitiator monomers and at least one further monomer, as well as photoinitiator monomers being intermediates in the preparation of such polymeric photoinitiators. Additionally, there is provided polyacrylate obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of such polymeric photoinitiators. In the photoinitiator monomers and polymeric photoinitiators, a photoinitiator moiety, a hydrolytic stable linker and two polymerisable functional groups are incorporated into the photoinitiator structure.

  本发明提供了聚合物光引发剂，其为光引发剂单体与至少一种进一步单体的共聚物，以及作为这种聚合物光引发剂制备过程中的中间体的光引发剂单体。此外，还提供了通过在存在这种聚合物光引发剂的情况下，通过至少一种丙烯酸酯单体（Ac）的自由基聚合得到的聚丙烯酸酯。在光引发剂单体和聚合物光引发剂中，光引发剂基团、水解稳定连接物和两个可聚合功能基团被结合到光引发剂结构中。
• DEGRADATION ACCELERATOR FOR POLYMERS AND POLYMER ARTICLE COMPRISING IT
  申请人：Sala Massimiliano

  公开号：US20100222454A1

  公开（公告）日：2010-09-02

  Disclosed are a method for improving the degradation of natural and/or synthetic polymers or a polymer article made from such polymer(s) by light and/or heat and/or humidity, comprising the incorporation of a compound of formula (I) into said natural and/or synthetic polymers: Formula (I); wherein m is 1 or 2, n is 1 to 100, X is selected from certain benzophenone-derived moieties and R, R1; R2 are each selected from list of certain residues; novel compounds of said formula (I) and polymeric articles of improved degradability in the presence of light and/or heat and/or humidity being made of a composition comprising: A) a natural and/or a synthetic polymer and B) a degradation accelerator being a compound of said formula (I).

  本发明涉及一种改善天然和/或合成聚合物或由这些聚合物制成的聚合物制品在光、热和/或湿度下降解的方法，包括将式(I)的化合物引入所述天然和/或合成聚合物中：式(I)；其中m为1或2，n为1至100，X选自某些苯并酮衍生物基团，R，R1和R2各自选自某些残基列表；所述式(I)的新化合物和改进的降解性能的聚合物制品由以下组成：A）天然和/或合成聚合物和B）一种降解加速剂，该加速剂是式(I)的化合物。
• NOVEL POLYMERIC PHOTOINITIATORS
  申请人：Madsen Niels Joergen

  公开号：US20130289155A1

  公开（公告）日：2013-10-31

  A polymeric photoinitiator, most suitably a polyurethane photoinitiator, is obtained by step-growth co-polymerization of at least one monomer (A) with at least one monomer (B). Monomer (A) includes a photoinitiator moiety, while monomer (B) is a monomer reactive with monomer (A) to form a polymer. A method produces the polymeric photoinitiator, a method cross-links the polymeric photoinitiator, and the polymeric photoinitiator is used as a photoinitiator of radical polymerization.

  一种聚合物光引发剂，最适宜的是聚氨酯光引发剂，通过至少一种单体（A）与至少一种单体（B）的步骤生长共聚反应获得。单体（A）包括光引发剂基团，而单体（B）是与单体（A）反应形成聚合物的单体。一种方法用于生产聚合物光引发剂，一种方法用于交联聚合物光引发剂，并且聚合物光引发剂用作自由基聚合的光引发剂。
• ROUTES TO POLYACRYLATES
  申请人：Madsen Niels Jørgen

  公开号：US20130296454A1

  公开（公告）日：2013-11-07

  A polyacrylate is obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of a polymeric photoinitiator. The polymeric photoinitiator is a co-polymer of at least one photoinitiator monomer (A) with at least one monomer (B), and optional additional monomers (C). Rapid polymerization of the acrylate monomer is provided. A method produces a polyacrylate using the polymeric photoinitiator as described, and a polymeric photoinitiator is used as the photoinitiator of radical polymerization of acrylate monomers.

  通过在聚合物光引发剂的存在下，通过自由基聚合至少一种丙烯酸酯单体（Ac）获得聚丙烯酸酯。聚合物光引发剂是由至少一种光引发剂单体（A）与至少一种单体（B）以及可选的其他单体（C）共聚而成的共聚物。提供了丙烯酸酯单体的快速聚合。一种方法使用上述聚合物光引发剂制备聚丙烯酸酯，以及使用聚合物光引发剂作为丙烯酸酯单体的自由基聚合的光引发剂。
• Polymers Comprising Photoinitiator Moieties and Dye Moieties
  申请人：Lambson Limited

  公开号：US20140316060A1

  公开（公告）日：2014-10-23

  The invention relates to a polymer (P) comprising at least one photoinitiator moiety (PI) and at least one dye moiety (DYE), wherein said at least one photoinitiator moiety (PI) and at least one dye moiety (DYE) are covalently linked to said polymer (P). Additionally, the invention relates to said polymer (P) being end-functionalized with optionally substituted acryloyi groups. The fact that both of these moieties are tightly bonded within the polymer, and the cross-linked polymer, means that the opportunities for leaching/migration of these components is reduced or even eliminated. Inks comprising at least one of said polymers are also provided. Methods for the manufacture of the polymers, and for printing are provided.

  本发明涉及一种聚合物（P），其包括至少一个光引发剂基团（PI）和至少一个染料基团（DYE），其中所述至少一个光引发剂基团（PI）和至少一个染料基团（DYE）与所述聚合物（P）共价连接。此外，本发明涉及所述聚合物（P）末端官能化，其具有可选的取代丙烯酰基团。这些基团都被紧密结合在聚合物中，交联的聚合物意味着这些组分的渗出/迁移机会减少甚至消除。本发明还提供了包含至少一种所述聚合物的油墨。提供了制造聚合物和印刷的方法。