3-methoxycarbonyl-2,6-dichlorobenzoyl chloride | 196820-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-methoxycarbonyl-2,6-dichlorobenzoyl chloride
• 英文别名: methyl 3-chlorocarbonyl-2,4-dichlorobenzoate；2,6-dichloro-3-methoxycarbonyl benzoic acid chloride；methyl 3-carbonochloridoyl-2,4-dichlorobenzoate
• CAS: 196820-01-6
• 化学式: C₉H₅Cl₃O₃
• 分子量: 267.496
• InChiKey: QYNPWZZIEKLZJM-UHFFFAOYSA-N

物化性质

• 沸点：
  345.4±42.0 °C(Predicted)
• 密度：
  1.505±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-methoxycarbonyl-2,6-dichlorobenzoyl chloride 、 1-(亚氨基氧基)氯化丙烷 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 methyl 2,4-dichloro-3-propoxyaminocarbonylbenzoate
  参考文献：
  名称：

  Substituted 4-benzoylpyrazoles

  摘要：

  这项发明涉及公式I的4-苯甲酰吡唑及其在农业上有用的盐，其工艺和中间体；其组合物；以及用于控制不良植物的用途。

  公开号：

  US06028035A1
• 作为产物：
  描述：

  methyl 2,4-dichloro-3-hydroxycarbonylbenzoate 在 氯化亚砜 作用下， 以 N-甲基乙酰胺 、 甲苯 为溶剂， 生成 3-methoxycarbonyl-2,6-dichlorobenzoyl chloride
  参考文献：
  名称：

  Substituted 4-benzoylpyrazoles

  摘要：

  这项发明涉及公式I的4-苯甲酰吡唑及其在农业上有用的盐，其工艺和中间体；其组合物；以及用于控制不良植物的用途。

  公开号：

  US06028035A1

文献信息

• Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
  申请人：BASF Aktiengesellschaft

  公开号：US06576596B1

  公开（公告）日：2003-06-10

  The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.

  该发明涉及式I的2-苯甲酰环己烷-1,3-二酮，其中R1、R2分别为氢、硝基、卤素、氰基、硫氰酸基、烷基、卤代烷基、烷氧基烷基、烯基、炔基、—OR5、—OCOR6、—OSO2R6、—SH、—S(O)nR7、—SO2OR5、—SO2NR5R8、—NR8SO2R6或—NR8COR6；R3为氢、氰基、烷基、卤代烷基、—OR7、—SR7或—NR7R10；R4为氢、取代或未取代的烷基、环烷基、烯基、环烯基、炔基、—COR9、—CO2R9、—COSR9或—CONR8R9；X为氧或NR8；n为0、1或2；R5为氢、烷基、卤代烷基、烷氧基烷基、烯基或炔基；R6为烷基或卤代烷基；R7为烷基、卤代烷基、烷氧基烷基、烯基或炔基；R8为氢或烷基；R9为烷基、烯基、炔基、苯基或苄基；R10为烷基、卤代烷基、烯基或炔基；Q是2位连接的带有或不带取代的环己烷-1,3-二酮环；及其在农业上有用的盐；用于制备式I化合物的工艺和中间体；包含它们的组合物；以及用于控制不良植物的这些衍生物或包含它们的组合物的用途。
• 3-(isoxazol-5-yl)-substituted benzoic acid derivative and method for
  申请人：Nippon Soda Co., Ltd.

  公开号：US05948917A1

  公开（公告）日：1999-09-07

  This invention concerns a benzoic acid represented by the formula \x9bI! ##STR1## or a benzoic acid derivative and a method for the production of a compound represented by the formula \x9bI!. The compound represented by the formula \x9bI! is an intermediate for the production of a herbicidally active pyrazole compound represented by the formula \x9bB! ##STR2##

  本发明涉及一种由公式\x9bI!表示的苯甲酸或苯甲酸衍生物，以及一种用于生产由公式\x9bI!表示的化合物的方法。公式\x9bI!表示的化合物是生产由公式\x9bB!表示的除草活性吡唑化合物的中间体。
• 3-aminocarbonyl/3-aminothiocarbonyl-substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
  申请人：BASF Aktiengesellschaft

  公开号：US06310245B1

  公开（公告）日：2001-10-30

  The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, alkyl, haloalkyl, alkenyl or alkynyl; R4 is hydrogen, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or sulfur; Z is oxygen or NR8; m is 0 or 1; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is an unsubstituted or substituted cyclohexane-1,3-dione ring which is linked in the 2-position; where m is 1 if R3 is hydrogen; and the agriculturally useful salts thereof; processes and intermediates for the preparation of the compounds of the formula I; compositions comprising them; and the use of these derivatives or compositions comprising them for controlling undesired plants.

  本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮，其中R1，R2为氢，硝基，卤素，氰基，硫氰酸基，烷基，卤代烷基，烷氧基烷基，烯基，炔基，—OR5，—OCOR6，—OSO2R6，—SH，—S（O）nR7，—SO2OR5，—SO2NR5R8，—NR8SO2R6或—NR8COR6; R3为氢，烷基，卤代烷基，烯基或炔基; R4为氢，未取代或取代的烷基，环烷基，烯基，环烯基，炔基，—COR9，—CO2R9，—COSR9或—CONR8R9; X为氧或硫; Z为氧或NR8; m为0或1; n为0,1或2; R5为氢，烷基，卤代烷基，烷氧基烷基，烯基或炔基; R6为烷基或卤代烷基; R7为烷基，卤代烷基，烷氧基烷基，烯基或炔基; R8为氢或烷基; R9为烷基，烯基，炔基，苯基或苄基; R10为烷基，卤代烷基，烯基或炔基; Q为在2位连接的未取代或取代的环己烷-1,3-二酮环; 当R3为氢时，m为1; 以及其对农业有用的盐；制备式I化合物的过程和中间体；包含它们的组合物；以及使用这些衍生物或包含它们的组合物来控制不受欢迎的植物的用途。
• HETEROCYCLE-SUBSTITUTED BENZENE DERIVATIVES AND HERBICIDES
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0894792A1

  公开（公告）日：1999-02-03

  The present invention is directed to heterocycle-substituted benzene derivatives represented by a general formula [I]; Wherein R1 is halogeno, C1-C4 alkyl, C1-C4 alkoxy, nitro, cyano, C1-C4 haloalkyl or the like; R2 is halogeno, nitro, cyano, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 haloalkyl, C1-C4 haloalkoxy, C1-C4 alkylthio or the like; R3 and R4 each independently represent hydrogen, C1-C4 alkyl or the like; T represents cyclohexanedione-1,3-dione cyclic group represented by a general formula [II]; wherein R5, R6, R7, R8, R9 and R10 are each independently halogeno, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or the like, or either R5 or R6 and either R7 or R8 may together form C1-C5 alkylene chain, and the salts thereof. The compounds according to the present invention have excellent herbicidal activity, and the herbicidal formulations prepared according to the present invention containing the inventive compounds are useful as hercicides being selectively-safe to objective agricultural crops.

  本发明涉及通式 [I] 所代表的杂环取代苯衍生物； 其中 R1 是卤代、C1-C4 烷基、C1-C4 烷氧基、硝基、氰基、C1-C4 卤代烷基或类似物；R2 是卤代、硝基、氰基、C1-C4 烷基、C1-C4 烷氧基、C1-C4 卤代烷基、C1-C4 卤代烷氧基、C1-C4 烷硫基或类似物； R3 和 R4 各自独立地代表氢、C1-C4 烷基或类似物； T 代表由通式[II]代表的环己二酮-1,3-二酮环状基团； 其中 R5、R6、R7、R8、R9 和 R10 各自独立地为卤素、C1-C4 烷基、C1-C4 卤代烷基、C1-C4 烷氧基或类似物，或者 R5 或 R6 与 R7 或 R8 可共同形成 C1-C5 亚烷基链，以及它们的盐。根据本发明制备的化合物具有优异的除草活性，根据本发明制备的含有本发明化合物的除草制剂可用作对目标农作物选择性安全的除草剂。
• 3-(ISOXAZOL-5-YL)-SUBSTITUTED BENZOIC ACID DERIVATIVES AND PROCESS FOR PRODUCING THE SAME
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0891972A1

  公开（公告）日：1999-01-20

  This invention concerns a benzoic acid represented by the formula [I] or a benzoic acid derivative and a method for the production of a compound represented by the formula [I]. The compound represented by the formula [I] is an intermediate for the production of a herbicidally active pyrazole compound represented by the formula [B]

  本发明涉及一种由式[I]表示的苯甲酸 或苯甲酸衍生物，以及生产式[I]所代表化合物的方法。式[I]代表的化合物是生产式[B]代表的具有除草活性的吡唑化合物的中间体。