5-chloro-3-[(3-trifluoromethyl)phenyl]-4-thiazolidinone | 109051-80-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-chloro-3-[(3-trifluoromethyl)phenyl]-4-thiazolidinone
• 英文别名: 5-chloro-3-[3-(trifluoromethyl)phenyl]-4-thiazolidinone；5-chloro-3-(3-trifluoromethyl)phenyl-4-thiazolidinone；5-chloro-3-(3-trifluoromethylphenyl)-4-thiazolidinone；5-Chloro-3-[3-(trifluoromethyl)phenyl]-1,3-thiazolidin-4-one
• CAS: 109051-80-1
• 化学式: C₁₀H₇ClF₃NOS
• 分子量: 281.686
• InChiKey: MGVOETVFXRHEEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  45.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  5-chloro-3-[(3-trifluoromethyl)phenyl]-4-thiazolidinone 在 水 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 生成 5-hydroxy-3-(3-trifluoromethyl)phenyl-4-thiazolidinone
  参考文献：
  名称：

  A novel thiazolidinone herbicide is a potent inhibitor of glucose incorporation into cell wall material†

  摘要：

  DOI：

  10.1002/(sici)1096-9063(199812)54:4<368::aid-ps845>3.0.co;2-6
• 作为产物：
  描述：

  3-[3-(Trifluoromethyl)phenyl]-4-thiazolidinone 以 盐酸 、 二氯甲烷 为溶剂， 生成 5-chloro-3-[(3-trifluoromethyl)phenyl]-4-thiazolidinone
  参考文献：
  名称：

  Substituted thiazolidinones useful as plant growth regulators

  摘要：

  揭示了具有结构式##STR1##的化合物，其中R是氢、氯、溴、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4烷氧基、--CH.sub.2 COOH、--CH.sub.2 COO (C.sub.1 -C.sub.4烷基)、--CH.sub.2 CONHN (C.sub.1 -C.sub.2烷基).sub.2、--CH.sub.2 CONR.sup.4 R.sup.5、--SPS(C.sub.1 -C.sub.4烷氧基).sub.2或--SPO(C.sub.1 -C.sub.4烷氧基).sub.2 (C.sub.1 -C.sub.4烷硫基).sub.2；R.sup.1、R.sup.2和R.sup.3相同或不同，分别是氢、羟基、氟、氯、溴、碘、C.sub.1 -C.sub.6烷基、C.sub.1 -C.sub.6烷氧基、C.sub.1 -C.sub.6烷硫基、C.sub.1 -C.sub.4烷基磺酰基、C.sub.1 -C.sub.6氟代烷基、C.sub.1 -C.sub.6氯代烷基、C.sub.1 -C.sub.6氟代烷氧基、C.sub.1 -C.sub.6氯代烷氧基、C.sub.1 -C.sub.6氟代烷硫基、C.sub.1 -C.sub.6氯代烷硫基、C.sub.7 -C.sub.9芳基烷基、苯基、苯氧基、苯硫基、C.sub.2 -C.sub.5烷氧羰基、羧基、硝基或氰基；R.sup.4和R.sup.5相同或不同，分别是氢或C.sub.1 -C.sub.6烷基；或者R.sup.4和R.sup.5共同为C.sub.4 -C.sub.6亚烷基或C.sub.4 -C.sub.6氧二烷基；n为0、1或2。该化合物在调节植物生长方面具有用途，并可形成用于此应用的组合物。该组合物包括具有上述结构式的化合物和其惰性载体。还介绍了形成上述化合物的方法。

  公开号：

  US04664694A1

文献信息

• [EN] LAZOLIDINE DERIVATIVES AS HERBICIDAL AGENTS<br/>[FR] DERIVES D'AZOLIDINE EN TANT QU'AGENTS HERBICIDES
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2005000824A1

  公开（公告）日：2005-01-06

  Novel azolidine derivatives of the formula (I) wherein R1 represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy, haloalkylthio or haloalkylene-dioxy, m represents 0, 1, 2, 3, 4 or 5, the R1 substituents are identical or different each other, when m represents 2, 3, 4 or 5, R2 represents alkyl, X represents alkylidene, oxygen atom or sulfur atom, and A represents one of the groups described in the specification and their use as herbicides.

  (I)式的新型氮杂环丙烷衍生物，其中R1代表卤素、烷基、烷氧基、卤代烷基、卤代烷氧基、卤代烷硫基或卤代烷二氧基，m代表0、1、2、3、4或5，R1取代基彼此相同或不同，当m代表2、3、4或5时，R2代表烷基，X代表烷基烯、氧原子或硫原子，A代表规范中描述的一种基团，以及它们作为除草剂的用途。
• Substituted thiazolidinones useful as plant growth regulators
  申请人：Uniroyal Chemical Company, Inc.

  公开号：US04664694A1

  公开（公告）日：1987-05-12

  A compound is disclosed having the structural formula ##STR1## where R is hydrogen, chlorine, bromine, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CH.sub.2 COOH, --CH.sub.2 COO (C.sub.1 -C.sub.4 alkyl), --CH.sub.2 CONHN (C.sub.1 -C.sub.2 alkyl).sub.2, --CH.sub.2 CONR.sup.4 R.sup.5, --SPS(C.sub.1 -C.sub.4 alkoxy).sub.2 or --SPO(C.sub.1 -C.sub.4 alkoxy).sub.2 (C.sub.1 -C.sub.4 alkylthio).sub.2 ; R.sup.1, R.sup.2 and R.sup.3 are the same or different and are hydrogen, hydroxy, fluorine, chlorine, bromine, iodine, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.6 chloroalkyl, C.sub.1 -C.sub.6 fluoroalkoxy, C.sub.1 -C.sub.6 chloroalkoxy, C.sub.1 -C.sub.6 fluoroalkylthio, C.sub.1 -C.sub.6 chloroalkylthio, C.sub.7 -C.sub.9 aralkyl, phenyl, phenoxy, phenylthio, C.sub.2 -C.sub.5 alkoxycarbonyl, carboxy, nitro or cyano; and R.sup.4 and R.sup.5 are the same or different and are hydrogen or C.sub.1 -C.sub.6 alkyl; alternatively R.sup.4 and R.sup.5 together are C.sub.4 -C.sub.6 alkylene or C.sub.4 -C.sub.6 oxydialkylene; and n is 0, 1 or 2. This compound is useful in regulating the growth of plants and can be formed int a composition, useful in this application. The composition comprises the compound having the structural formula given above and an inert carrier therefor. A process for forming the compound set forth above is also taught.

  揭示了具有结构式##STR1##的化合物，其中R是氢、氯、溴、C.sub.1 -C.sub.4烷基、C.sub.1 -C.sub.4烷氧基、--CH.sub.2 COOH、--CH.sub.2 COO (C.sub.1 -C.sub.4烷基)、--CH.sub.2 CONHN (C.sub.1 -C.sub.2烷基).sub.2、--CH.sub.2 CONR.sup.4 R.sup.5、--SPS(C.sub.1 -C.sub.4烷氧基).sub.2或--SPO(C.sub.1 -C.sub.4烷氧基).sub.2 (C.sub.1 -C.sub.4烷硫基).sub.2；R.sup.1、R.sup.2和R.sup.3相同或不同，分别是氢、羟基、氟、氯、溴、碘、C.sub.1 -C.sub.6烷基、C.sub.1 -C.sub.6烷氧基、C.sub.1 -C.sub.6烷硫基、C.sub.1 -C.sub.4烷基磺酰基、C.sub.1 -C.sub.6氟代烷基、C.sub.1 -C.sub.6氯代烷基、C.sub.1 -C.sub.6氟代烷氧基、C.sub.1 -C.sub.6氯代烷氧基、C.sub.1 -C.sub.6氟代烷硫基、C.sub.1 -C.sub.6氯代烷硫基、C.sub.7 -C.sub.9芳基烷基、苯基、苯氧基、苯硫基、C.sub.2 -C.sub.5烷氧羰基、羧基、硝基或氰基；R.sup.4和R.sup.5相同或不同，分别是氢或C.sub.1 -C.sub.6烷基；或者R.sup.4和R.sup.5共同为C.sub.4 -C.sub.6亚烷基或C.sub.4 -C.sub.6氧二烷基；n为0、1或2。该化合物在调节植物生长方面具有用途，并可形成用于此应用的组合物。该组合物包括具有上述结构式的化合物和其惰性载体。还介绍了形成上述化合物的方法。
• Substituted thiazolidinones
  申请人：UNIROYAL CHEMICAL COMPANY, Inc.

  公开号：EP0200415A1

  公开（公告）日：1986-12-10

  A compound is disclosed having the structural formula where R is hydrogen, chlorine, bromine, C1-C4 alkyl, C1-C4 alkoxy, -CH2COOH, -CH2COO(C1-C4 alkyl), -CH2CONHN(C1-C2 alkyl)2, -CH2CONR4R5, - SPS(C1-C4 alkoxy)2 or -SPO(C1-C4 alkoxy) (C,-C4 alkylthio); R', R2 and R3 are the same or different and are hydrogen, hydroxy, fluorine, chlorine, bromine, iodine, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C4 alkylsulfonyl, C1-C6 fluoroalkyl, C1-C6 chloroalkyl, C,-C6 fluoroalkoxy, C,-C6 chloroalkoxy, C1-C6 fluoralkyl- thio, C1-C6 chloroalkylthio, C1-C9 aralkyl, phenyl, phenoxy, phenylthio, C2-C5 alkoxycarbonyl, car- boxy, nitro or cyano; and R4 and R5 are the same or different and are hydrogen or C1-C6 alkyl; alternatively R4 and R5 together are C1-C6 alkylene or C4-C6 oxydialkylene; and n is 0, 1 or 2. This compound is useful in regulating the growth of plants and can be formed into a composition, useful in this application. The composition comprises the compound having the structural formula given above and an inert carrier therefor. A process for forming the compound set forth above is also taught.

  公开了一种化合物，其结构式为 其中 R 是氢、氯、溴、C1-C4 烷基、C1-C4 烷氧基、-CH2COOH、-CH2COO(C1-C4 烷基)、-CH2CONHN(C1-C2 烷基)2、-CH2CONR4R5、-SPS(C1-C4 烷氧基)2 或-SPO(C1-C4 烷氧基) (C,-C4 烷硫基)； R'、R2 和 R3 相同或不同，并且是氢、羟基、氟、氯、溴、碘、C1-C6 烷基、C1-C6 烷氧基、C1-C6 烷硫基、C1-C4 烷磺酰基、C1-C6 氟烷基、C1-C6 氯烷基、C,-C6 氟烷氧基、C,-C6 氯烷氧基、C1-C6 氟烷基硫代、C1-C6 氯烷基硫代、C1-C9 芳烷基、苯基、苯氧基、苯硫基、C2-C5 烷氧基羰基、羧基、硝基或氰基；和 R4 和 R5 相同或不同，并且是氢或 C1-C6 烷基；或者 R4 和 R5 同为 C1-C6 亚烷基或 C4-C6 氧二亚烷基；以及 n 为 0、1 或 2。 这种化合物可用于调节植物的生长，并可制成在此应用中有用的组合物。该组合物包括具有上述结构式的化合物及其惰性载体。还教导了形成上述化合物的工艺。
• HERBICIDES
  申请人：ZENECA LIMITED

  公开号：EP0672038A1

  公开（公告）日：1995-09-20
• SUBSTITUTED PYRROLIDONE, THIAZOLIDONES OR OXAZOLIDONES AS HERBICIDES
  申请人：ZENECA LIMITED

  公开号：EP0763020A1

  公开（公告）日：1997-03-19