9-Phenyl-3-[9-(9-phenylcarbazol-3-yl)-2,7-di(pyren-1-yl)fluoren-9-yl]carbazole | 1207299-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 9-Phenyl-3-[9-(9-phenylcarbazol-3-yl)-2,7-di(pyren-1-yl)fluoren-9-yl]carbazole
• 英文别名: 9-phenyl-3-[9-(9-phenylcarbazol-3-yl)-2,7-di(pyren-1-yl)fluoren-9-yl]carbazole
• CAS: 1207299-20-4
• 化学式: C₈₁H₄₈N₂
• 分子量: 1049.29
• InChiKey: LNYSBWVHCDQUER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.3
• 重原子数：
  83
• 可旋转键数：
  6
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.01
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,3'-(2,7-dibromo-9H-fluorene-9,9-diyl)bis(9-phenyl-9H-carbazole) 、 1-芘硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 24.0h， 以77%的产率得到9-Phenyl-3-[9-(9-phenylcarbazol-3-yl)-2,7-di(pyren-1-yl)fluoren-9-yl]carbazole
  参考文献：
  名称：

  High-Efficiency Nondoped Deep-Blue-Emitting Organic Electroluminescent Device

  摘要：

  A new blue emitter, 9,9-bis-(3- (9-phenyl-carbazoyl))-2,7-dipryenylfluorene (DCDPF), has been synthesized and characterized. Organic light-emitting devices (OLEDs) using DCDPF as a non-doped emitter exhibits deep-blue emission with a peak at 458 nm and CIE coordinates of (0.15, 0.15). The maximum efficiency of the device is 4.4 cd/A (3.1 lm/W). The results suggest that the introduction of carbazole units at the 9-position of fluorene provides an effective way to suppress molecular aggregation which would cause red shift in emission.

  DOI：

  10.1021/cm100100w

文献信息

• ORGANIC MOLECULES FOR USE IN OPTOELECTRONIC DEVICES
  申请人：CYNORA GMBH

  公开号：US20190177303A1

  公开（公告）日：2019-06-13

  The invention relates to an organic molecule for the use in optoelectronic devices. According to the invention, the organic molecule has a first chemical moiety with a structure of formula I, and two second chemical moieties with a structure of formula II, wherein # represents the binding site of a single bond linking the first chemical moiety to the second chemical moiety; V is selected from the group consisting of CN and CF 3 ; and W is the bond linking the first chemical moiety to one of the two second chemical moieties.

  本发明涉及一种用于光电子器件的有机分子。根据本发明，该有机分子具有一个具有公式I结构的第一化学基团和两个具有公式II结构的第二化学基团，其中#表示将第一化学基团与第二化学基团连接的单键结合位点；V选自CN和CF3组成的群体；W是将第一化学基团与两个第二化学基团之一连接的键。
• High-Efficiency Nondoped Deep-Blue-Emitting Organic Electroluminescent Device
  作者：Silu Tao、Yechun Zhou、Chun-Sing Lee、Xiaohong Zhang、Shuit-Tong Lee

  DOI：10.1021/cm100100w

  日期：2010.3.23

  A new blue emitter, 9,9-bis-(3- (9-phenyl-carbazoyl))-2,7-dipryenylfluorene (DCDPF), has been synthesized and characterized. Organic light-emitting devices (OLEDs) using DCDPF as a non-doped emitter exhibits deep-blue emission with a peak at 458 nm and CIE coordinates of (0.15, 0.15). The maximum efficiency of the device is 4.4 cd/A (3.1 lm/W). The results suggest that the introduction of carbazole units at the 9-position of fluorene provides an effective way to suppress molecular aggregation which would cause red shift in emission.