3,3',3''-(1,3,5-苯甲三基三-2,1-乙炔二基)三[5-(1,1-二甲基乙基)-6-羟基苯甲醛 | 705930-83-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 中文名称: 3,3',3''-(1,3,5-苯甲三基三-2,1-乙炔二基)三[5-(1,1-二甲基乙基)-6-羟基苯甲醛
• 英文名称: 1,3,5-tris[(5-tert-butyl-3-formyl-4-hydroxyphenyl)ethynyl]benzene
• 英文别名: 5,5',5''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)；5-[2-[3,5-bis[2-(3-tert-butyl-5-formyl-4-hydroxyphenyl)ethynyl]phenyl]ethynyl]-3-tert-butyl-2-hydroxybenzaldehyde
• CAS: 705930-83-2
• 化学式: C₄₅H₄₂O₆
• 分子量: 678.825
• InChiKey: ZDPXAFWKNLTUNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  51
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (1R,2S)-1-氨基-2-茚醇 、 3,3',3''-(1,3,5-苯甲三基三-2,1-乙炔二基)三[5-(1,1-二甲基乙基)-6-羟基苯甲醛 以 乙醇 为溶剂， 反应 0.08h， 以93%的产率得到
  参考文献：
  名称：

  Asymmetric sulfoxidation of prochiral sulfides using aminoalcohol derived chiral C3-symmetric trinuclear vanadium Schiff base complexes

  摘要：

  A series of trimeric variants of the efficient and well known Bolm's chiral vanadium salen catalysts are reported. These C-3-symmetric trinuclear chiral Schiff bases were synthesized by condensing a variety of trialdehydes with optically active aminoalcohols. The catalytic activity of the chiral vanadium complexes of these ligands was investigated for the enantio selective oxidation of prochiral sulfides using hydrogen peroxide as an oxidant. The procedure afforded the corresponding sulfoxide in good yield and the enantioselectivities were comparable to those obtained with the mononuclear complexes. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2007.11.005
• 作为产物：
  描述：

  1,3,5-三乙炔苯 、 3-叔丁基-2-羟基-5-碘苯甲醛 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 反应 24.0h， 以51%的产率得到3,3',3''-(1,3,5-苯甲三基三-2,1-乙炔二基)三[5-(1,1-二甲基乙基)-6-羟基苯甲醛
  参考文献：
  名称：

  基于Salen的共价有机框架

  摘要：

  Salen 单元代表配位化学中最重要的配体之一。我们在此报告了基于 Salen 的共价有机框架 (COF) 的第一个例子，其中 COF 结构的构建和 Salen 部分的功能化都在一个步骤中实现。由于其结构独特，所获得的COF材料Salen-COF具有高结晶度和优异的稳定性。在此基础上，通过金属化制备了一系列金属-Salen 基 COFs 以供进一步应用。

  DOI：

  10.1021/jacs.7b01523

文献信息

• TRIS(FORMYLPHENYL) AND NEW POLYNUCLEAR POLYPHENOL DERIVED THEREFROM
  申请人：Yoshitomo Akira

  公开号：US20100099908A1

  公开（公告）日：2010-04-22

  A novel tris(formylphenyl) according to the following general formula and polynuclear phenol derived therefrom, which are useful as a material for heat resistant materials, material for photosensitive resist compositions, epoxy resin material or hardener, developer or anti-fade agent for thermosensitive recording materials, or sterilizer, fungicide, antioxidant, etc: In the formula, Y represents a hydrogen atom or —R 2 COOR 3 group, R 2 represents a monocyclic or condensed cyclic aromatic hydrocarbon group with a carbon atom number of 6 to 15 or an aliphatic hydrocarbon group with a carbon atom number of 1 to 8 that may have in its main chain a monocyclic or condensed cyclic aromatic hydrocarbon group with a carbon atom number of 6 to 15, and R 3 represents a hydrogen atom or alkyl group with a carbon atom number of 1 to 6. R 1 s may be the same or different and respectively represent a hydrogen atom, alkyl group with a carbon atom number of 1 to 8 or alkoxyl group with a carbon atom number of 1 to 8. R B and R C may be the same or different, where R A , R B and R C respectively represent a hydrogen atom or alkyl group with a carbon atom number of 1 to 6 and n and m are respectively an integer of 0 or 1 to 3.

  根据以下一般公式的新型三酰基苯和由此衍生的多核酚，可用作耐热材料、光敏抗蚀组合物的材料、环氧树脂材料或硬化剂、热敏记录材料的显影剂或抗褪色剂，或者用作杀菌剂、杀真菌剂、抗氧化剂等：在该公式中，Y代表氢原子或—R2COOR3基团，R2代表具有6至15个碳原子数的单环或紧凑环芳烃基团，或者具有1至8个碳原子数的脂肪烃基团，其主链中可能具有具有6至15个碳原子数的单环或紧凑环芳烃基团，而R3代表1至6个碳原子数的氢原子或烷基基团。R1可能相同也可能不同，分别代表氢原子、具有1至8个碳原子数的烷基基团或具有1至8个碳原子数的烷氧基团。RB和RC可能相同也可能不同，其中RA、RB和RC分别代表具有1至6个碳原子数的氢原子或烷基基团，n和m分别为0或1至3的整数。
• Formation and Structure of Conjugated Salen-Cross-Linked Polymers and Their Application in Asymmetric Heterogeneous Catalysis
  作者：Morten Nielsen、Anne�H. Thomsen、Torben�R. Jensen、Hans�J. Jakobsen、J�rgen Skibsted、Kurt�V. Gothelf

  DOI：10.1002/ejoc.200400451

  日期：2005.1

  condensation polymer was obtained by the reaction of 1,3,5-tris[(5-tert-butyl-3-formyl-4-hydroxyphenyl)ethynyl]benzene (1) with ethylenediamine. Solid-state 13C1H} CP/MAS NMR analysis showed that the polymer was pure and highly cross-linked and powder synchrotron X-ray diffraction indicated some degree of local structural order in the polymer. A chiral manganese−salen-bridged polymer was obtained

  1,3,5-三[(5-叔丁基-3-甲酰基-4-羟基苯基)乙炔基]苯(1)与乙二胺反应得到一种新型交联缩聚物。固态 13C1H} CP/MAS NMR 分析表明聚合物是纯的和高度交联的，粉末同步加速器 X 射线衍射表明聚合物具有一定程度的局部结构有序。通过 1 与 (1R,2R)-1,2-二苯基-1,2-二氨基乙烷 (3a) 或 (1R,2R)-1,2-二氨基环己烷 (3b ) 在 Mn(OAc)2 存在下。这些刚性手性金属-salen 聚合物可以催化顺式 2-甲基苯乙烯的环氧化反应，具有高转化率、非对映选择性和高达 67% ee 的对映选择性。聚合物催化剂可以重复使用多次而不会降低活性或选择性。
• METHOD FOR PRODUCING NEW POLYNUCLEAR POLY(FORMYLPHENOL)
  申请人：Yoshitomo Akira

  公开号：US20090182175A1

  公开（公告）日：2009-07-16

  Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.

  在工业环境中，通过在酸的存在下使多核聚氢甲基酚或多核聚烷氧甲基酚与六亚甲基四胺反应，然后水解所得的反应产物，轻松高纯度地制备目标物质或由通式（2）表示的多核聚甲酰苯酚。
• Asymmetric sulfoxidation of prochiral sulfides using aminoalcohol derived chiral C3-symmetric trinuclear vanadium Schiff base complexes
  作者：Paulsamy Suresh、Sankareswaran Srimurugan、Balaji Babu、Hari N. Pati

  DOI：10.1016/j.tetasy.2007.11.005

  日期：2007.11

  A series of trimeric variants of the efficient and well known Bolm's chiral vanadium salen catalysts are reported. These C-3-symmetric trinuclear chiral Schiff bases were synthesized by condensing a variety of trialdehydes with optically active aminoalcohols. The catalytic activity of the chiral vanadium complexes of these ligands was investigated for the enantio selective oxidation of prochiral sulfides using hydrogen peroxide as an oxidant. The procedure afforded the corresponding sulfoxide in good yield and the enantioselectivities were comparable to those obtained with the mononuclear complexes. (c) 2007 Elsevier Ltd. All rights reserved.
• US7750190B2
  申请人：——

  公开号：US7750190B2

  公开（公告）日：2010-07-06