3-(α-Methylbenzyl)-1,2-dihydroxybenzene | 33369-95-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(α-Methylbenzyl)-1,2-dihydroxybenzene
• 英文别名: 3-(α-Methylbenzyl)pyrocatechol；3-(1'-Phenylethyl)-brenzkatechin；3-(1'-Phenyl)ethylpyrocatechol；Aivzhiigmqreqx-uhfffaoysa-；3-(1-phenylethyl)benzene-1,2-diol
• CAS: 33369-95-8
• 化学式: C₁₄H₁₄O₂
• 分子量: 214.264
• InChiKey: AIVZHIIGMQREQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  邻苯二酚 、 苯乙烯 生成 3-(α-Methylbenzyl)-1,2-dihydroxybenzene
  参考文献：
  名称：

  KOZLIKOVSKIJ, YA. B.;KOSHCHIJ, V. A.;BUTOV, S. A., ZH. ORGAN. XIMII, 1986, 22, N 3, 606-610

  摘要：

  DOI：

文献信息

• COSMETIC AND/OR DERMATOLOGICAL COMPOSITION CONTAINING A MEROCYANINE DERIVATIVE COMPRISING SPECIFIC POLAR GROUPS CONSISTING OF HYDROXYL- AND ETHER-FUNCTIONALITIES
  申请人：Richard Herve

  公开号：US20140294743A1

  公开（公告）日：2014-10-02

  The present invention relates to a cosmetic and/or dermatological composition comprising in a physiologically acceptable medium at least one merocyanine derivative of formula (1) or (2) and/or its E,E-, E,Z- or Z,Z-geometrical isomer forms: comprising specific polar groups consisting of hydroxyl- and ether-functionalities. Another object of the present invention relates to a cosmetic process for controlling and/or improving the darkening of the skin under exposure to UV radiation and the homogeneity of the colour of the complexion which comprises the application onto the skin of a cosmetic composition as above defined. Another object of the present invention relates to a cosmetic process for protecting the keratinic materials and particularly the skin against photo-ageing which comprises the application onto the keratinic material of a cosmetic composition as above defined.

  本发明涉及一种化妆品和/或皮肤科学组合物，其在生理上可接受的介质中包含至少一种公式（1）或（2）的merocyanine衍生物及/或其E，E-，E，Z-或Z，Z-几何异构体形式：包括由羟基和醚功能团组成的特定极性基团。本发明的另一个目的涉及一种化妆过程，用于控制和/或改善皮肤在紫外线照射下的变黑和肤色均匀性，包括在皮肤上涂抹上述定义的化妆品组合物。本发明的另一个目的涉及一种化妆过程，用于保护角质素材料，特别是皮肤免受光老化的影响，包括在角质素材料上涂抹上述定义的化妆品组合物。
• [EN] COSMETIC AND/OR DERMATOLOGICAL COMPOSITION CONTAINING A MEROCYANINE DERIVATIVE COMPRISING SPECIFIC POLAR GROUPS CONSISTING OF HYDROXYL- AND ETHER-FUNCTIONALITIES<br/>[FR] COMPOSITION COSMÉTIQUE ET/OU DERMATOLOGIQUE CONTENANT UN DÉRIVÉ DE MÉROCYANINE QUI COMPREND DES GROUPES POLAIRES SPÉCIFIQUES CONSTITUÉS DE FONCTIONNALITÉS HYDROXYLE ET ÉTHER
  申请人：OREAL

  公开号：WO2013010590A1

  公开（公告）日：2013-01-24

  A cosmetic and/or dermatologigal composition comprising in a physiologically acceptable medium at least one merocyanine derivative of formula (1) or (2) and/or its Ε,Ε-, Ε,Ζ- or Z, Z - geometrical isomer forms: comprising specific polar groups consisting of hydroxyl - and ether- functionalities. A cosmetic process for controlling and/or improving the darkening of the skin under exposure to UV radiation and the homogeneity of the colour of the complexion which comprises the application onto the skin of a cosmetic composition as above defined. A cosmetic process for protecting the keratinic materials and particularly the skin against photo-ageing which comprises the application onto the keratinic material of a cosmetic composition as above defined. Use of merocyanines for protecting bodycare products from photolytic and oxidative degradation.

  一种化妆品和/或皮肤科组合物，包括生理可接受介质中的至少一种公式（1）或（2）的并环氰染料衍生物及/或其Ε，Ε-，Ε，Ζ-或Z，Z-几何异构体形式：包括由羟基和醚基构成的特定极性基团。一种化妆品过程，用于控制和/或改善皮肤在紫外线照射下的黑化和肤色的均匀性，其中包括将上述定义的化妆品组合物涂抹于皮肤上。一种化妆品过程，用于保护角蛋白材料，特别是皮肤免受光老化的影响，其中包括将上述定义的化妆品组合物涂抹于角蛋白材料上。使用并环氰染料保护身体护理产品免受光解和氧化降解的影响。
• Extrudable film-forming compositions of Ziegler-Natta catalyzed olefin polymers including anti-gel and anti-block components
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0060673A1

  公开（公告）日：1982-09-22

  A non-volatile, anti-gel compound having a chain of at least about 5 repeat units of an alkylene oxide and which is soluble in olefin polymers, and an inorganic anti-block agent having a substantially neutral pH are added to a film grade Ziegler-Natta catalyzed olefin polymer composition to prevent: (1) gel streaking/pinstriping during film extrusion processes; (2) blocking of the extruded film; and (3) discoloration of the extruded film upon aging. The anti-gel compound has a molecular weight between about 200 and about 4,000,000 Daltons. A masterbatch concentrate and extrusion method are also disclosed.

  在薄膜级齐格勒-纳塔催化烯烃聚合物组合物中加入一种非挥发性抗凝胶化合物，该化合物具有至少约 5 个环氧烷重复单元的链，可溶于烯烃聚合物，同时还加入一种 pH 值基本为中性的无机抗阻塞剂，以防止：(1) 薄膜挤出过程中出现凝胶条纹/细条纹；(2) 挤出薄膜阻塞；以及 (3) 挤出薄膜老化变色。抗凝胶化合物的分子量在约 200 到约 4,000,000 道尔顿之间。 还公开了一种母料浓缩物和挤出方法。
• Metallic salts of hindered phenolic anti-oxidant as anti-gel component in transition metal-catalyzed olefin polymers containing halide residue
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0068851A1

  公开（公告）日：1983-01-05

  A non-volatile, metallic salt of a hindered phenolic anti-oxidant is added to a film- or molding-grade olefin polymer composition to prevent gel-streaking/pinstriping, oxidation and corrosion during film extrusion processes.

  在薄膜或模塑级烯烃聚合物组合物中添加一种非挥发性受阻酚类抗氧化剂金属盐，以防止在薄膜挤出过程中出现凝胶断裂/细条纹、氧化和腐蚀。
• Process and composition for extrusion of Ziegler-Natta catalyzed olefin polymers
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0054268A1

  公开（公告）日：1982-06-23

  A non-volatile, acid acceptor which is soluble in polyolefins is added to a film grade polyolefin resin composition to prevent gel streaking/pinstriping or corrosion during film extrusion processes. The acid acceptor has a molecular weight greater than 180 with less than 5% by weight volatiles at 180°C as measured by a thermal evolution analysis.

  在薄膜级聚烯烃树脂组合物中加入一种可溶于聚烯烃的非挥发性酸接受体，以防止在薄膜挤压过程中产生凝胶条纹/细条纹或腐蚀。 根据热演化分析法的测定，这种酸接受体的分子量大于 180，在 180°C 时挥发物的重量比小于 5%。