Benzene, [(1Z)-5-chloro-1-pentenyl]- | 374094-69-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzene, [(1Z)-5-chloro-1-pentenyl]-
• 英文别名: 5-chloropent-1-enylbenzene
• CAS: 374094-69-6
• 化学式: C₁₁H₁₃Cl
• 分子量: 180.677
• InChiKey: CDINNLUJIQAPRY-UHFFFAOYSA-N

物化性质

• 沸点：
  283.0±19.0 °C(Predicted)
• 密度：
  1.033±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5-氯戊炔 、 四苯硼钠 在 bis-triphenylphosphine-palladium(II) chloride 、 水 、 溶剂黄146 作用下， 反应 6.0h， 以48%的产率得到(5-chloropent-1-en-2-yl)benzene
  参考文献：
  名称：

  Recyclable and reusable PdCl₂(PPh₃)₂/PEG-400/H₂O system for the hydrophenylation of alkynes with sodium tetraphenylborate

  摘要：

  已开发出一种稳定高效的PdCl₂(PPh₃)₂/PEG-400/H₂O催化体系，用于炔烃的加氢苯基化反应。在存在3 mol% PdCl₂(PPh₃)₂和2当量的HOAc的情况下，终末和内部炔烃与四苯硼酸钠在PEG-400和水的混合物中在室温或50 °C下顺利进行了苯基化反应，产率中等到较高。 产品的分离可通过石油醚萃取轻松进行，PdCl₂(PPh₃)₂/PEG-400/H₂O体系可轻松回收和重复使用六次而无明显失活。

  DOI：

  10.1177/1747519820934379

文献信息

• Method for Producing an Anion-Exchange Membrane for a Solid Polymer Electrolyte Type Fuel Cell
  申请人：Fukuta Kenji

  公开号：US20110207028A1

  公开（公告）日：2011-08-25

  An anion-exchange membrane having quaternary ammonium groups or quaternary phosphonium groups wherein halogen ions serve as the counter ions is obtained. Rather than being subjected to ion exchange with an OH-type membrane using a toxic substance such as sodium hydroxide, the halogen-type anion exchange membrane is brought into contact with a carbonate solution and/or bicarbonate solution to directly obtain an anion exchange membrane where at least some of the counterions of the quaternary ammonium groups or quaternary phosphonium groups are CO 3 2− and/or HCO 3 − .

  获得了具有季铵基或季膦基的阴离子交换膜，其中卤素离子作为对离子。与使用像氢氧化钠这样的有毒物质对OH型膜进行离子交换不同，卤素型阴离子交换膜与碳酸盐溶液和/或碳酸氢盐溶液接触，直接获得至少一些季铵基或季膦基的对离子为CO32−和/或HCO3−的阴离子交换膜。
• SEPARATION MEMBRANE FOR FUEL CELL
  申请人：Tokuyama Corporation

  公开号：EP2214240A1

  公开（公告）日：2010-08-04

  The present invention can provide an anion exchange type separation membrane used for direct liquid fuel type fuel cell, high in heat resistance, hard to deteriorate when using and capable of obtaining high battery output. A composite membrane used as the separation membrane for fuel cell can be obtained by using a porous film, composed of a hydrolysis resistant polyimide resin such as a polyimide resin having a fluorenylidene group in a main framework, as a substrate; optionally increasing water retention characteristics for example by applying a water-retentive resin to at least a part of a surface of the porous film; and then filling an anion-exchange resin such as a cross-linked hydrocarbon-based anion-exchange resin having a quaternary ammonium group as an anion exchange group into a void portion of the porous film.

  本发明可提供一种用于直接液体燃料型燃料电池的阴离子交换型分离膜，其耐热性高，使用时不易变质，并能获得较高的电池输出功率。用作燃料电池分离膜的复合膜可以通过使用多孔膜来获得，该多孔膜由耐水解的聚酰亚胺树脂（例如在主框架中具有亚芴基团的聚酰亚胺树脂）作为基材；有选择地增加保水特性，例如在多孔膜表面的至少一部分涂上保水树脂；然后在多孔膜的空隙部分填充阴离子交换树脂，例如具有季铵基团作为阴离子交换基团的交联烃基阴离子交换树脂。
• SEPARATION MEMBRANE FOR DIRECT LIQUID FUEL CELL AND METHOD FOR PRODUCING THE SAME
  申请人：Tokuyama Corporation

  公开号：EP2192645A1

  公开（公告）日：2010-06-02

  Disclosed is a method for producing a membrane for direct liquid fuel cells, wherein a polymerizable composition is brought into contact with a porous membrane so that voids of the porous membrane are filled with the polymerizable composition, then the polymerizable composition is cured by polymerization, and after that a halogenoalkyl group in the resin membrane is converted into a quaternary ammonium group. In this method, the polymerizable composition contains (a) an aromatic polymerizable monomer having an aromatic ring wherein one polymerizable group, at least one halogenoalkyl group and a group which is inert to a reaction converting the at least one halogenoalkyl group into a quaternary ammonium group, are bonded together, (b) a crosslinkable polymerizable monomer and (c) a polymerization initiator.

  本发明公开了一种用于生产直接液体燃料电池膜的方法，其中将可聚合组合物与多孔膜接触，使多孔膜的空隙充满可聚合组合物，然后通过聚合固化可聚合组合物，之后将树脂膜中的卤代烷基转化为季铵基团。在这种方法中，可聚合组合物包含：(a) 具有芳香环的芳香族可聚合单体，其中一个可聚合基团、至少一个卤代烷基和一个对将至少一个卤代烷基转化为季铵基的反应惰性的基团键合在一起；(b) 可交联的可聚合单体；(c) 聚合引发剂。
• METHOD FOR PRODUCING ANION EXCHANGE MEMBRANE FOR SOLID POLYMER ELECTROLYTE-TYPE FUEL CELL
  申请人：Tokuyama Corporation

  公开号：EP2333887A1

  公开（公告）日：2011-06-15

  Provided is a method for the simple and stable production of an anion exchange membrane for an anion exchange membrane-type fuel cell. An anion-exchange membrane having quaternary ammonium groups or quaternary phosphonium groups wherein halogen ions serve as the counter ions is obtained and rather than being subjected to ion exchange with an OH-type membrane using a toxic substance such as sodium hydroxide, the halogen-type anion exchange membrane is brought into contact with a carbonate solution and/or bicarbonate solution to directly obtain an anion exchange membrane where at least some of the counterions of the quaternary ammonium groups or quaternary phosphonium groups are CO32- and/or HCO3-.

  本发明提供了一种用于阴离子交换膜燃料电池的阴离子交换膜的简单而稳定的生产方法。这种阴离子交换膜具有季铵盐基团或季鏻基团，其中卤素离子可作为反离子，而且这种卤素型阴离子交换膜无需使用氢氧化钠等有毒物质与 OH 型膜进行离子交换，而是与碳酸盐溶液和/或碳酸氢盐溶液接触，从而直接获得一种阴离子交换膜，其中季铵盐基团或季鏻基团的反离子至少有一部分是 CO32- 和/或 HCO3-。
• PREPOLYMER, CURABLE MATERIAL, COATING COMPOSITION, NON-LINEAR OPTICAL MATERIAL, OPTICAL WAVEGUIDE AND LIGHT CONTROL DEVICE
  申请人：Asahi Glass Company, Limited

  公开号：EP2889684A1

  公开（公告）日：2015-07-01

  Provided are: a prepolymer which is capable of forming a non-linear optical material that has excellent non-linear optical effect, heat resistance, withstand voltage and transparency; a curable material which contains the prepolymer; a coating composition which contains the curable material and a solvent; a non-linear optical material which is obtained by curing the curable material; an optical waveguide which uses the non-linear optical material; and a light control device which is provided with the optical waveguide. The present invention uses a prepolymer having a crosslinkable functional group, which is obtained by reacting one or more compounds (X) that are selected from the group consisting of compounds (X1), compounds (X2) and compounds (X3), a compound (Y) that is represented by formula (Y), a compound (Z) that has three or more phenolic hydroxyl groups, and an organic compound (B) that exerts a non-linear optical effect and has a reactive group.

  本发明提供了：一种能够形成非线性光学材料的预聚物，该材料具有优异的非线性光学效果、耐热性、耐电压性和透明度；一种包含该预聚物的可固化材料；一种包含该可固化材料和溶剂的涂层组合物；一种通过固化该可固化材料而获得的非线性光学材料；一种使用该非线性光学材料的光波导；以及一种配备该光波导的光控制装置。本发明使用了一种具有可交联官能团的预聚物，该预聚物是通过将一种或多种选自化合物（X1）、化合物（X2）和化合物（X3）组成的组的化合物（X）、由式（Y）表示的化合物（Y）、具有三个或多个酚羟基的化合物（Z）和具有非线性光学效应并具有活性基团的有机化合物（B）反应而得到的。