N,N-diphenyl-N-(4-t-butyl-2,6-dimethylphenyl)-amine | 854952-66-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-diphenyl-N-(4-t-butyl-2,6-dimethylphenyl)-amine
• 英文别名: 4-tert-Butyl-2,6-dimethyl-N,N-diphenylaniline
• CAS: 854952-66-2
• 化学式: C₂₄H₂₇N
• 分子量: 329.485
• InChiKey: BHPKDYPALUMKIY-UHFFFAOYSA-N

物化性质

• 沸点：
  436.5±44.0 °C(Predicted)
• 密度：
  1.030±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-diphenyl-N-(4-t-butyl-2,6-dimethylphenyl)-amine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 正己烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 N,N-bis(4-bromophenyl)-N-(4-t-butyl-2,6-dimethylphenyl)-amine
  参考文献：
  名称：

  WO2006/132357

  摘要：

  公开号：
• 作为产物：
  描述：

  2-溴-5-叔丁基-1,3-二甲基苯 、 二苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 7.0h， 生成 N,N-diphenyl-N-(4-t-butyl-2,6-dimethylphenyl)-amine
  参考文献：
  名称：

  WO2006/132357

  摘要：

  公开号：

文献信息

• Polymer Compound and Polymer Light-Emitting Device Using the Same
  申请人：Oguma Jun

  公开号：US20080233429A1

  公开（公告）日：2008-09-25

  A polymer compound comprising a repeating unit of the following formula (1) and which is useful as a light emitting material or charge transporting material and excellent in heat resistance, fluorescent intensity and the like: (wherein, ring A and ring B represent each independently an aromatic hydrocarbon ring optionally having a substituent, at least one of ring A and ring B is an aromatic hydrocarbon ring composed of a plurality of condensed benzene rings, R w and R x represent each independently a hydrogen atom, alkyl group, alkoxy group or the like, and R w and R x may mutually bond to form a ring).

  一种聚合物化合物，包含以下公式（1）的重复单元，可用作发光材料或电荷传输材料，并具有良好的耐热性、荧光强度等特性：（其中，环A和环B各自独立地表示具有取代基的芳香族碳氢环，环A和环B中至少一个为由多个融合苯环组成的芳香族碳氢环，Rw和Rx各自独立地表示氢原子、烷基、烷氧基或类似物，且Rw和Rx可以相互结合形成环）。
• Polymer Compound and Polymer Light Emitting Device Using the Same
  申请人：Agata Katsumi

  公开号：US20080274303A1

  公开（公告）日：2008-11-06

  A polymer compound comprising a repeating unit of the following formula (1) and a repeating unit selected from the following formulae (2-1) and (2-2): (wherein, Ar 1 and Ar 2 represent an arylene group or divalent heterocyclic group. a and b represent each independently 0 or 1, E 1 , E 2 and E 3 represent an aryl group having three or more substituents selected from alkyl groups, alkoxy groups and the like, or a monovalent heterocyclic group having one or more substituents and in which the sum of the number of the substituents and the number of hetero atoms of the heterocycle is 3 or more. A ring, B ring, C ring and D ring represent an aromatic ring, X represents —O—, —S— and the like, and Y represents —C≡C— and the like).

  一种聚合物化合物，包含以下式子（1）的重复单元和以下式子（2-1）和（2-2）中选择的重复单元： （其中，Ar1和Ar2代表芳基或二价杂环基。a和b各自独立地表示0或1，E1、E2和E3代表具有三个或更多取代基的芳基，所述取代基选择自烷基，烷氧基等，或具有一个或多个取代基的一价杂环基，在其中杂环的取代基数和杂原子数之和为3或更多。环A、环B、环C和环D表示芳香环，X表示—O—、—S—等，Y表示—C≡C—等）。
• Aromatic Graft Polymer
  申请人：Ohuchi Kazuei

  公开号：US20090096355A1

  公开（公告）日：2009-04-16

  An aromatic graft polymer containing one or more kinds of repeating units represented by the following formula (1). (In the formula, Ar 1 represents a divalent residue of a π-conjugated cyclic compound having a side chain represented by the following formula (2), the side chain being bonded to a carbon atom which is included in the ring structure of the divalent π-conjugated-cyclic-compound residue represented by Ar 1 and has an sp 2 hybrid orbital: (wherein Ar 2 represents a divalent group having a residue of a π-conjugated cyclic compound; X 1 represents a direct bond or a divalent group selected from the group consisting of NQ 1 -, —PQ 2 -, and —BQ 3 -, wherein Q 1 to Q 3 each independently represents a substituent; Z represents a direct bond or a divalent connecting group; k is an integer of 3 or larger; and E 1 represents hydrogen, halogeno, or a monovalent organic group, provided that when two or more Ar 2 's, X 1 's, and Z's are present, then they each may be the same or different and when two or more side chains represented by the formula (2) are present, then they may be the same or different.))

  含有由以下公式（1）所表示的一种或多种重复单元的芳香嫁接聚合物。（其中，Ar1表示具有以下公式（2）所表示的侧链的π-共轭环状化合物的二价残基，侧链与包括在由Ar1表示的二价π-共轭环状化合物残基的环结构中的碳原子结合，并具有sp2杂化轨道：（其中，Ar2表示具有π-共轭环状化合物残基的二价基团；X1表示直接键或从由NQ1-，-PQ2-和-BQ3-组成的二价基团中选择的基团，其中Q1到Q3各自独立地表示取代基；Z表示直接键或二价连接基团；k是大于等于3的整数；E1表示氢，卤素或一价有机基团，但当存在两个或更多的Ar2，X1和Z时，它们可以各自相同或不同，当存在两个或更多的由公式（2）表示的侧链时，则它们可以相同或不同。））
• Process for producing polymer
  申请人：Ohuchi Kazuei

  公开号：US20090209715A1

  公开（公告）日：2009-08-20

  A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): —Ar 1 — (wherein Ar 1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C—H bond on the aromatic ring) is used as a raw material and one or more of the C—H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar 2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C—H bonds on the aromatic ring of Ar 1 have been converted into a C—X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)). (B) A step in which the polymer having the characteristic group (X) produced in the step (A) is reacted with a compound having a characteristic group (Y) which reacts with the characteristic group (X) to form a bond.

  一种制备聚合物的方法，其特征在于包括以下步骤（A）和步骤（B）。 （A）使用具有由通式（1）表示的重复单元的聚合物作为原料，并将芳香环上的一个或多个C-H键转化，从而产生具有一个或多个特征基团X的重复单元的聚合物，该聚合物由通式（2）表示：（其中X表示特征基团；Ar2表示具有n+2价的芳香族、杂环族或芳香胺基团，其中每个基团的Ar1芳香环上的n个C-H键已转化为C-X键；n是1-4的整数）（以下简称具有特征基团（X）的聚合物）。 （B）将在步骤（A）中生产的具有特征基团（X）的聚合物与具有与特征基团（X）反应形成键的特征基团（Y）的化合物反应。
• POLYMER AND POLYMERIC LUMINESCENT ELEMENT COMPRISING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1724294A1

  公开（公告）日：2006-11-22

  A polymer compound comprising a repeating unit of the following formula (1) and a repeating unit selected from the following formulae (2-1) and (2-2): (wherein, Ar1 and Ar2 represent an arylene group or divalent heterocyclic group. a and b represent each independently 0 or 1, E1, E2 and E3 represent an aryl group having three or more substituents selected from alkyl groups, alkoxy groups and the like, or a monovalent heterocyclic group having one or more substituents and in which the sum of the number of the substituents and the number of hetero atoms of the heterocycle is 3 or more. A ring, B ring, C ring and D ring represent an aromatic ring, X represents -O-, -S- and the like, and Y represents -C=C- and the like).

  一种聚合物化合物，包含下式（1）的重复单元和选自下式（2-1）和（2-2）的重复单元： (其中，Ar1 和 Ar2 代表芳基或二价杂环基团，a 和 b 独立地分别代表 0 或 1，E1、E2 和 E3 代表具有三个或三个以上选自烷基、烷氧基等的取代基的芳基，或具有一个或一个以上取代基的一价杂环基团，其中取代基的数目与杂环的杂原子数目之和为 3 或 3 以上。A环、B环、C环和D环代表芳香环，X代表-O-、-S-等，Y代表-C=C-等）。