p-sulfophenylarsonic acid | 744134-62-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-sulfophenylarsonic acid
• 英文别名: 4-arsono-benzenesulfonic acid；4-Arsono-benzolsulfonsaeure；Benzol-sulfonsaeure-(1)-arsonsaeure-(4)；4-Sulfo-phenyl-arsonsaeure；Sodium p-arsonobenzenesulphonate；4-arsonobenzenesulfonic acid
• CAS: 744134-62-1
• 化学式: C₆H₇AsO₆S
• 分子量: 282.106
• InChiKey: FDADNEVPFQUWEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.51
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  120
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  p-sulfophenylarsonic acid 在 盐酸 、 四氯化碳 、 五氯化磷 、 氨 、 水 作用下， 生成 4-dichloroarsino-benzenesulfonic acid amide
  参考文献：
  名称：

  LXXXIX.—锥虫作用和化学成分。第九部分 含酰胺基的芳香酸

  摘要：

  DOI：

  10.1039/jr9300000669
• 作为产物：
  描述：

  (4,4'-disulfanediyl-diphenyl)-bis-arsonic acid 在 硝酸 作用下， 生成 p-sulfophenylarsonic acid
  参考文献：
  名称：

  Hewitt; King; Murch, Journal of the Chemical Society, 1926, p. 1358,1369

  摘要：

  DOI：

文献信息

• Sulfophenylarsonic Acids and Certain of their Derivatives. I. p-Sulfophenylarsonic Acid
  作者：J. F. Oneto

  DOI：10.1021/ja01276a012

  日期：1938.9
• Novel lead(II) coordination polymers based on p-sulfophenylarsonic acid
  作者：Fei-Yan Yi、Tian-Hua Zhou、Jiang-Gao Mao

  DOI：10.1016/j.molstruc.2010.11.059

  日期：2011.2

  Hydrothermal reactions of lead(II) salts with p-sulfophenylarsonic acid (p-HO3S-C6H4-A(5)O(3)H(2), H3L) afforded two novel lead(II) p-sulfonate-arsonates, namely, Pb-3(L)(2)(H2O)center dot H2O (1) and Pb-3(L)(2)center dot 6.5H(2)O (2). Their structures feature two different types of three-dimensional structures. In compound 1, the interconnection of Pb(II) ions by bridging arsonate and sulfonate groups results into a 20 layer parallel to the bc plane. These layers are further cross-linked by phenyl groups into a pillared-layered architecture with small voids occupied by the lattice water. Compound 2 features a 3D open framework based on 1D lead sulfonate-arsonate chains of Pb3O4 clusters along c-axis that are further cross-linked by phenyl groups, forming large tunnels along c-axis which are occupied by a number of lattice water molecules. Introduction of 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) as the auxiliary chelating ligand into the above system led to two new mixed-ligand lead(II) sulfonate-arsonates, namely, Pb(HL)(bipy)center dot 2H(2)O (3) and Pb(HL)(phen)center dot 2H(2)O (4). Compounds 3 and 4 display a similar one-dimensional chain in which neighboring Pb2O2 units are bridged by a pair of HL2- anions. There also exists a 1D water chain in compound 3. All four compounds display strong fluorescent emission bands in the green or red light region. (C) 2010 Elsevier B.V. All rights reserved.
• LXXXIX.—Trypanocidal action and chemical constitution. Part IX. Aromatic acids containing an amide group
  作者：George Aleck Crocker Gough、Harold King

  DOI：10.1039/jr9300000669

  日期：——
• Hewitt; King; Murch, Journal of the Chemical Society, 1926, p. 1358,1369
  作者：Hewitt、King、Murch

  DOI：——

  日期：——