N-phenyl-N'-(p-tolyl)-formamidine | 49755-13-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenyl-N'-(p-tolyl)-formamidine
• 英文别名: N-phenyl-N'-p-tolylformamidine；N-Phenyl-N'-(4-methylphenyl)formamidine；N'-(4-methylphenyl)-N-phenylmethanimidamide
• CAS: 49755-13-7
• 化学式: C₁₄H₁₄N₂
• 分子量: 210.279
• InChiKey: BJINXEZCMHYQQF-UHFFFAOYSA-N

物化性质

• 熔点：
  105-106 °C
• 沸点：
  345.3±35.0 °C(Predicted)
• 密度：
  1.00±0.1 g/cm3(Predicted)
• 保留指数：
  2122

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-phenyl-N'-(p-tolyl)-formamidine 、 异氰酸甲酯 生成 3-Methyl-1-phenyl-1-[(E)-p-tolylimino-methyl]-urea
  参考文献：
  名称：

  DE2308943

  摘要：

  公开号：
• 作为产物：
  描述：

  1-(4-甲基苯基)-3-苯基硫脲 在 镍 作用下， 以 甲醇 为溶剂， 以50%的产率得到N-phenyl-N'-(p-tolyl)-formamidine
  参考文献：
  名称：

  相应硫脲类脱硫简便合成N-取代甲脒

  摘要：

  N,N'-Di-和N,N,N'-三取代硫脲很容易被Raney镍脱硫得到相应的甲脒，而N-单取代硫脲得到N,N'-二取代甲脒。

  DOI：

  10.1246/bcsj.59.3317

文献信息

• Lewis acid catalyst free synthesis of benzimidazoles and formamidines in 1,1,1,3,3,3-hexafluoro-2-propanol
  作者：Samad Khaksar、Akbar Heydari、Mahmood Tajbakhsh、Seyed Mohammad Vahdat

  DOI：10.1016/j.jfluchem.2010.10.002

  日期：2010.12

  A simple, inexpensive, environmentally friendly and efficient route for the synthesis of benzimidazole and formamidine derivatives by the reaction of O-phenylenediamines or amines with orthoesters using hexafluoroisopropanol as a solvent/catalyst is described.

  描述了一种简单的，廉价的，环境友好的和有效的途径，其通过使用六氟异丙醇作为溶剂/催化剂通过邻苯二胺或胺与原酸酯的反应来合成苯并咪唑和甲am衍生物。
• The Magellanic System's Interactive Formations
  作者：M. E. Putman

  DOI：10.1071/as00001

  日期：——

  The interaction between the Galaxy and the Magellanic Clouds has resulted in several high-velocity complexes which are connected to the Clouds. The complexes are known as the Magellanic Bridge, an HI connection between the Large and Small Magellanic Clouds, the Magellanic Stream, a 10° × 100° HI filament which trails the Clouds, and the Leading Arm, a diffuse HI filament which leads the Clouds. The mechanism responsible for these features formation remains under some debate, with the lack of detailed HI observations being one of the limiting factors in resolving the issue. Here I present several large mosaics of HI Parkes All-Sky Survey (HIPASS) data which show the full extent of the three Magellanic complexes at almost twice the resolution of previous observations. These interactive features are connected, but unique in their spatial and velocity distribution. The differences may shed light on their origin and present environment. Dense clumps of HI along the sightline to the Sculptor Group, which may or may not be associated with the Magellanic complexes, are also discussed.

  摘要银河系和麦哲伦云之间的相互作用产生了几个与麦哲伦云相连的高速复合体。这些复合体被称为麦哲伦桥（大麦哲伦云和小麦哲伦云之间的高频连接）、麦哲伦流（一个追踪麦哲伦云的 10° × 100° 高频丝）和前臂（一个引领麦哲伦云的弥漫高频丝）。关于这些特征的形成机制仍存在一些争论，缺乏详细的高能射线观测是解决这一问题的限制因素之一。在这里，我展示了几幅大型 HI 帕克斯全天空巡天（HIPASS）数据的镶嵌图，这些数据显示了三个麦哲伦复合体的全部范围，分辨率几乎是以前观测数据的两倍。这些相互作用的特征相互关联，但在空间和速度分布上又各不相同。这些差异可能揭示了它们的起源和当前环境。此外，还讨论了沿着雕像群视线的密集 HI 团块，它们可能与麦哲伦星团有关，也可能无关。
• Amidinato complexes of dicyclopentadienylmolybdenum. Synthesis and redox properties
  作者：A.R. Dias、M.A. Queirós

  DOI：10.1016/0022-328x(90)85031-s

  日期：1990.7
• A new and green synthesis of formamidines by γ-Fe2O3@SiO2–HBF4 nanoparticles as a robust and magnetically recoverable catalyst
  作者：Mehdi Sheykhan、Mohsen Mohammadquli、Akbar Heydari

  DOI：10.1016/j.molstruc.2012.06.009

  日期：2012.11

  A series of Bronsted acids (HA) were immobilized on superparamagnetic gamma-Fe2O3@SiO2. The synthesized [gamma-Fe2O3@SiO2-HA] nanocrystallites were fully characterized by spectroscopic techniques (FT-IR, XRD, SEM, EDX) and used as solid acid catalysts in the synthesis of biologically important formamidines. The results were excellent in yield and time of reaction. Activity of various Bronsted acids on superparamagnetic support as catalyst were also evaluated and among them immobilized HBF4 showed the best catalytic properties. (C) 2012 Elsevier B.V. All rights reserved.
• Ortho Esters, Imidic Esters and Amidines. The Identity of N-Phenyl-N'-p-tolylformamidine
  作者：Royston M. Roberts

  DOI：10.1021/ja01164a078

  日期：1950.8