Benzenemethanol, alpha-(2-methylenecyclopentyl)-, (R*,R*)- | 144629-62-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzenemethanol, alpha-(2-methylenecyclopentyl)-, (R*,R*)-
• 英文别名: (2-methylidenecyclopentyl)-phenylmethanol
• CAS: 144629-62-9；144629-65-2
• 化学式: C₁₃H₁₆O
• 分子量: 188.269
• InChiKey: XZOVJLZLKBXNIW-UHFFFAOYSA-N

物化性质

• 沸点：
  303.5±11.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  6-iodo-hexa-1,2-diene 、 苯甲醛 生成 Benzenemethanol, alpha-(2-methylenecyclopentyl)-, (R*,R*)-
  参考文献：
  名称：

  Cyclizations of ω-allenyl organometallic reagents

  摘要：

  Allenyl organometallic reagents of type R2C = C = CH(CH2)nCH2M undergo cyclization at the central allenic carbon for n = 2 (M = Li) and at the near allenic carbon for n = 3 (M = CuCNLi) to provide cyclopentane systems; little cyclization was observed for the n = 4 systems (M = Li, CuCNLi).

  DOI：

  10.1016/s0040-4039(00)79080-0

文献信息

• Cyclizations of ω-allenyl organometallic reagents
  作者：Jack K. Crandall、Timothy A. Ayers

  DOI：10.1016/s0040-4039(00)79080-0

  日期：1992.9

  Allenyl organometallic reagents of type R2C = C = CH(CH2)nCH2M undergo cyclization at the central allenic carbon for n = 2 (M = Li) and at the near allenic carbon for n = 3 (M = CuCNLi) to provide cyclopentane systems; little cyclization was observed for the n = 4 systems (M = Li, CuCNLi).