bis-(dimethyl-benzoyloxymethyl-methyl)-amine | 258289-21-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(dimethyl-benzoyloxymethyl-methyl)-amine
• 英文别名: [2-[(1-Benzoyloxy-2-methylpropan-2-yl)amino]-2-methylpropyl] benzoate
• CAS: 258289-21-3
• 化学式: C₂₂H₂₇NO₄
• 分子量: 369.461
• InChiKey: BYCSOKVCXJXSTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  27
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  bis-(dimethyl-benzoyloxymethyl-methyl)-amine 、 间氯过氧苯甲酸 以 乙酸乙酯 为溶剂， 生成 bis-(dimethyl-benzoyloxymethyl-methyl)-amine-N-oxyl
  参考文献：
  名称：

  Open chain alkoxyamine compounds and their use as polymerization regulators

  摘要：

  该发明涉及用作聚合调节剂的开链烷氧胺化合物。这些开链烷氧胺化合物对乙烯基不饱和单体的聚合具有用处。本发明的化合物提供具有低聚分散度的聚合树脂产品。聚合过程具有增强的单体到聚合物转化效率。具体而言，本发明涉及稳定的自由基介导的聚合过程，提供同聚物、随机共聚物、嵌段共聚物、多嵌段共聚物、接枝共聚物等，在增强的聚合速率和增强的单体到聚合物转化率下。

  公开号：

  US06518326B1

文献信息

• OPEN CHAIN ALKOXYAMINE COMPOUNDS AND THEIR USE AS POLYMERIZATION REGULATORS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1100772A1

  公开（公告）日：2001-05-23
• US6518326B1
  申请人：——

  公开号：US6518326B1

  公开（公告）日：2003-02-11
• US6841703B2
  申请人：——

  公开号：US6841703B2

  公开（公告）日：2005-01-11
• [EN] OPEN CHAIN ALKOXYAMINE COMPOUNDS AND THEIR USE AS POLYMERIZATION REGULATORS<br/>[FR] COMPOSES D'ALKOXYAMINE A CHAINE OUVERTE ET LEUR UTILISATION COMME REGULATEURS DE POLYMERISATION
  申请人：CIBA SC HOLDING AG

  公开号：WO2000007981A1

  公开（公告）日：2000-02-17

  The invention relates to a compound of formula (Ia), (Ib) or (Ic). The open chain alkoxyamine compounds are useful for the polymerization of ethylenically unsaturated monomers. The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymers, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.
• Open chain alkoxyamine compounds and their use as polymerization regulators
  申请人：Ciba Specialty Chemicals Corporation

  公开号：US06518326B1

  公开（公告）日：2003-02-11

  The invention relates to open chain alkoxyamine compounds useful as polymerization regulators. The open chain alkoxyamine compounds are useful for the polymerization of ethylenically unsaturated monomers. The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymer, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.

  该发明涉及用作聚合调节剂的开链烷氧胺化合物。这些开链烷氧胺化合物对乙烯基不饱和单体的聚合具有用处。本发明的化合物提供具有低聚分散度的聚合树脂产品。聚合过程具有增强的单体到聚合物转化效率。具体而言，本发明涉及稳定的自由基介导的聚合过程，提供同聚物、随机共聚物、嵌段共聚物、多嵌段共聚物、接枝共聚物等，在增强的聚合速率和增强的单体到聚合物转化率下。