phenoxy-tripropyl-silane | 17902-83-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenoxy-tripropyl-silane
• 英文别名: Phenoxy-tripropyl-silan；Tri-n-propylphenoxysilan；Tripropyl-phenoxy-silan；Tripropyl-silyloxybenzene；phenoxy(tripropyl)silane
• CAS: 17902-83-9
• 化学式: C₁₅H₂₆OSi
• 分子量: 250.456
• InChiKey: CHVZRUTUEJALOM-UHFFFAOYSA-N

物化性质

• 沸点：
  283.9±9.0 °C(Predicted)
• 密度：
  0.890±0.06 g/cm3(Predicted)
• 保留指数：
  1604.1

计算性质

• 辛醇/水分配系数(LogP)：
  5.24
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三正丙基硅烷 、 苯酚 在 nickel dichloride 作用下， 生成 phenoxy-tripropyl-silane
  参考文献：
  名称：

  Dolgow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 1238,1241; engl. Ausg. S. 1195, 1197

  摘要：

  DOI：

文献信息

• Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes
  作者：Shinsuke Nii、Jun Terao、Nobuaki Kambe

  DOI：10.1016/j.tetlet.2003.12.101

  日期：2004.2

  A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at −20 °C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.

  通过使用Cp 2 TiCl 2作为催化剂，已经开发出一种新的烯丙基醚与氯硅烷甲硅烷基化的方法。使用正丁基氯化镁，该反应在-20°C的THF中有效地进行。提出了通过烯丙基钛茂新中间体的合理反应途径。
• Appealing to Good Students in Introductory Economics
  作者：Elizabeth J. Jensen、Ann L. Owen

  DOI：10.1080/00220480309595225

  日期：2003.1

  The authors examine the effectiveness of different teaching techniques using a unique data set that allows them to match student and instructor characteristics to assess their impact on students' interest in economics. They find that devoting less class time to lecture and more to discussion is effective for all types of students. However, the magnitude of the effects of these two techniques varies considerably by type of student, as does the impact of several other teaching techniques. They conclude that using a variety of teaching techniques is the most successful strategy to appeal to the broad range of learning styles adopted by "good" students.