diethyl (2-hydroxy-5-decylphenyl)phosphonate | 95206-54-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: diethyl (2-hydroxy-5-decylphenyl)phosphonate
• 英文别名: diethyl 2-hydroxy-5-n-decylphenylphosphonate；diethyl 5-decyl-2-hydroxybenzenephosphonate；4-Decyl-2-diethoxyphosphorylphenol
• CAS: 95206-54-5
• 化学式: C₂₀H₃₅O₄P
• 分子量: 370.469
• InChiKey: ALZYDYSQPPPALZ-UHFFFAOYSA-N

物化性质

• 熔点：
  28-29 °C
• 沸点：
  469.9±38.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  25
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diethyl (2-hydroxy-5-decylphenyl)phosphonate 在 三甲基溴硅烷 、 sodium hydride 作用下， 反应 2.0h， 生成 [2-(Cyclohexylmethoxy)-5-decylphenyl]phosphonic acid
  参考文献：
  名称：

  Czech, Bronislaw P.; Desai, Dhimant H.; Koszuk, Jacek, Journal of Heterocyclic Chemistry, 1992, vol. 29, # 4, p. 867 - 875

  摘要：

  DOI：
• 作为产物：
  描述：

  4-decylphenyldichlorophosphate 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 反应 18.0h， 生成 diethyl (2-hydroxy-5-decylphenyl)phosphonate
  参考文献：
  名称：

  亲脂性冠膦酸单烷基酯。合成与溶剂萃取

  摘要：

  合成了亲脂性冠膦酸单烷基酯，该酯能够独立于阴离子将金属离子从酸性和中性水溶液转移到有机介质中，并已在竞争性碱金属溶剂萃取中进行了测试。

  DOI：

  10.1039/c39840001504

文献信息

• Lipophilic crown phosphonic acid monoalkyl esters. Synthesis and solvent extraction
  作者：Jacek F. Koszuk、Bronislaw P. Czech、Wladyslaw Walkowiak、David A. Babb、Richard A. Bartsch

  DOI：10.1039/c39840001504

  日期：——

  Lipophilic crown phosphonic acid monoalkyl esters capable of anion-independent metal ion transport from acidic and neutral aqueous solutions into organic media have been synthesized and tested in competitive alkali metal solvent extraction.

  合成了亲脂性冠膦酸单烷基酯，该酯能够独立于阴离子将金属离子从酸性和中性水溶液转移到有机介质中，并已在竞争性碱金属溶剂萃取中进行了测试。
• Competitive solvent extraction of alkali metal cations into chloroform by lipophilic acyclic proton-ionizable polyethers
  作者：Wladyslaw. Walkowiak、Grace M. Ndip、Dhimant H. Desai、Han Koo. Lee、Richard A. Bartsch

  DOI：10.1021/ac00039a011

  日期：1992.8.1

  A series of lipophilic acyclic polyether carboxylic acids and a corresponding polyether phosphonic acid monoethyl ester were synthesized in which the unit that contains the lipophilic and the proton-ionizable groups is held constant, but the polyether chain and its terminal group are systematically varied, Competitive solvent extraction of alkali metal cations from aqueous solutions into chloroform was performed to assess the influence of structural variation within the extractant molecule upon the extraction selectivity and efficiency. Many of the ionophores exhibited extraction selectivity for Li+. One of the simplest chelating agents gave an extraction selectivity order of Li+ >> Na+ > K+, Rb+ > Cs+ and a Li+/Na+ selectivity ratio of 4.9, while the selectivity ratios for Li+ over K+, Rb+, and Cs+ were 12 or higher.
• A lipophilic lariat ether with different intraannular and pendent acidic functions: synthesis and metal ion extraction
  作者：Bronislaw P. Czech、Hwang Huh、Richard A. Bartsch

  DOI：10.1021/jo00028a058

  日期：1992.1

  A novel resorcinol-based, 25-crown-8 compound with an intraannular oxyacetic acid group and a pendent, lipophilic phosphonic acid monoethyl ester function has been synthesized. Competitive solvent extractions of alkali-metal, alkaline-earth, and mixed alkali-metal and alkaline-earth cations from aqueous solutions into chloroform by this lipophilic lariat ether with two different proton-ionizable groups were investigated. The lipophilic diionizable lariat ether exhibits markedly different efficiencies in the extraction of alkali-metal cations and of alkaline-earth cations from basic aqueous solutions.
• KOSZUK, J. F.;CZECH, B. P.;WALKOWIAK, W.;BABB, D. A.;BARTSCH, R. A., J. CHEM. SOC. CHEM. COMMUN., 1984, N 22, 1504-1505
  作者：KOSZUK, J. F.、CZECH, B. P.、WALKOWIAK, W.、BABB, D. A.、BARTSCH, R. A.

  DOI：——

  日期：——
• Czech, Bronislaw P.; Desai, Dhimant H.; Koszuk, Jacek, Journal of Heterocyclic Chemistry, 1992, vol. 29, # 4, p. 867 - 875
  作者：Czech, Bronislaw P.、Desai, Dhimant H.、Koszuk, Jacek、Czech, Anna、Babb, David A.、at al.

  DOI：——

  日期：——