N,N′-bis(4-aminophenyl)-N,N′-diphenyl-1,4-benzenediamine | 111341-76-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N′-bis(4-aminophenyl)-N,N′-diphenyl-1,4-benzenediamine
• 英文别名: N,N'-bis(4-aminophenyl)-N,N'-diphenyl-1,4-phenylenediamine；N,N'-bis(4-aminophenyl)-N,N'-di-phenyl-1,4-benzenediamine；N,N'-bis(p-aminophenyl)-N,N'-diphenyl-p-phenylenediamine；N,N'-diphenyl-N,N'-bis(4-aminophenyl)-p-phenylenediamine；1,4-Benzenediamine, N,N'-bis(4-aminophenyl)-N,N'-diphenyl-；4-N-[4-(N-(4-aminophenyl)anilino)phenyl]-4-N-phenylbenzene-1,4-diamine
• CAS: 111341-76-5
• 化学式: C₃₀H₂₆N₄
• 分子量: 442.563
• InChiKey: TZHNHNHALWWXSP-UHFFFAOYSA-N

物化性质

• 沸点：
  668.7±50.0 °C(Predicted)
• 密度：
  1.242±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N′-bis(4-aminophenyl)-N,N′-diphenyl-1,4-benzenediamine 、 三光气 以 甲苯 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Multifunctional polyurethanes synthesized from different triarylamine units with electrochromic, photogeneration, memory storage and sensing properties

  摘要：

  在这里，我们报告了三种多功能聚氨酯材料，具有出色的电致变色、光电、记忆和传感特性，同时还具有良好的机械性能。

  DOI：

  10.1039/c8nj05159c
• 作为产物：
  描述：

  N,N'-二苯基-1,4-苯二胺 在 palladium on activated carbon 、 sodium hydride 、 一水合肼 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 N,N′-bis(4-aminophenyl)-N,N′-diphenyl-1,4-benzenediamine
  参考文献：
  名称：

  Multifunctional polyurethanes synthesized from different triarylamine units with electrochromic, photogeneration, memory storage and sensing properties

  摘要：

  在这里，我们报告了三种多功能聚氨酯材料，具有出色的电致变色、光电、记忆和传感特性，同时还具有良好的机械性能。

  DOI：

  10.1039/c8nj05159c

文献信息

• Poly(arylamine-imide)s Cathode Materials for Lithium-Ion Batteries with High Average Voltage and Long Cycle Life
  作者：Chengjun Zhang、Sha Chen、Guangying Zhou、Qiong Hou、Suilian Luo、Yuhai Wang、Guang Shi

  DOI：10.1149/1945-7111/abf180

  日期：2021.5.1

  lithium ion half-cells based on the polymer cathode and the lithium anode are assembled and the electrochemical properties are tested. Due to the high voltage of the DDP unit in the polymer backbone, lithium-ion half-cells based on PDDP-NI and PDDP-PI cathodes provide a high average discharge voltage of about 3.2 V. Moreover, the as-prepared polymer materials exhibit long-cycle performance, PDDP-NI remains

  两种聚（芳胺-酰亚胺），聚（N,N,N',N'-四苯基-1,4-苯二胺萘二酰亚胺）（PDDP-NI）和聚（N,N,N',N'-四苯基-通过胺单体 N,N,N',N'-四苯基-1,4-苯二胺 (DDP) 与二酐单体 1,4 缩聚成功制备 1,4-苯二胺苝二酰亚胺 (PDDP-PI)， 5,8-萘四甲酸二酐 (NTCDA) 或 3,4,9,10- 苝四甲酸二酐 (PTCDA)。聚合物中的 DDP 单元可以可逆地掺杂/去掺杂 PF 6 -阴离子，而萘二亚胺 (NI) 单元或苝二亚胺 (PI) 单元可以可逆地插入/脱出锂阳离子。组装基于聚合物正极和锂负极的锂离子半电池并测试其电化学性能。由于聚合物骨架中 DDP 单元的高电压，基于 PDDP-NI 和 PDDP-PI 阴极的锂离子半电池提供约 3.2 V 的高平均放电电压。 此外，所制备的聚合物材料表现出在长循环性能方面，PDDP-NI 在 10 C
• CHARGE-TRANSPORTING VARNISHES CONTAINING CHARGE-TRANSPORTING POLYMERS AND ORGANIC ELECTROLUMINESCENT DEVICES MADE BY USING THE SAME
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1905804A1

  公开（公告）日：2008-04-02

  A charge-transporting varnish comprising a solution or dispersion of at least one charge-transporting polymer comprising repeating units represented by the general formula (1) in at least one solvent, wherein the polymer is at least one polymer selected from among polyimide precursors having number-average molecular weights of 1,000 to 100,000 and polyimides obtained by cyclodehydration of the precursors; a charge-transporting varnish comprising a solution or dispersion in at least one solvent of both a charge-transporting substance consisting of a charge-transporting oligoaniline derivative having a number-average molecular weight of 250 to 5,000 or a charge-transporting organic material consisting of the substance and a charge-receiving dopant and at least one charge-transporting polymer comprising repeating units represented by the general formula (1); charge-transporting thin films formed by using the varnishes; and organic electroluminescent devices provided with the thin films: (1) wherein Ar1 to Ar3 are each independently monovalent aryl; Ar4 to Ar7 are each independently divalent aryl; X1 and X2 are each independently a divalent organic group; X3 and X4 are each independently a single bond, -O-, -S-, -C(O)NH-, -NHC(O)-, imino which may be substituted with a monovalent hydrocarbon group, alkylene of 1 to 5 carbon atoms which may have a branched structure, or alkylenedioxo of 1 to 5 carbon atoms which may have a branched structure; n is 0 or a positive integer of 3 or below; and i and j are each independently 0 or 1.

  一种电荷传输清漆，包括至少一种由通式(1)代表的重复单元组成的电荷传输聚合物在至少一种溶剂中的溶液或分散液，其中该聚合物为至少一种选自平均分子量为1,000至100,000的聚酰亚胺前体和通过前体环脱水得到的聚酰亚胺的聚合物；电荷传输清漆，包括电荷传输物质在至少一种溶剂中的溶液或分散液，该电荷传输物质由平均分子量为 250 至 5000 的电荷传输低聚苯胺衍生物组成，或由该物质和电荷接收掺杂剂组成的电荷传输有机材料，以及至少一种电荷传输聚合物，该聚合物由通式(1)表示的重复单元组成；使用这些清漆形成的电荷传输薄膜；以及使用这些薄膜的有机电致发光器件：(1) 其中 Ar1 至 Ar3 各自独立地为一价芳基；Ar4 至 Ar7 各自独立地为二价芳基；X1 和 X2 各自独立地为二价有机基团；X3和X4各自独立地为单键、-O-、-S-、-C(O)NH-、-NHC(O)-、可被一价烃基取代的亚氨基、可具有支链结构的1至5个碳原子的亚烷基或可具有支链结构的1至5个碳原子的亚烷基二氧代；n为0或3或以下的正整数；以及i和j各自独立地为0或1。
• Electrode for an electrochemical element with an organic electrolyte, electrochemical elements comprising the electrode and polymeric material and its use as electrode active material or as electrode binder
  申请人：VARTA Micro Innovation GmbH

  公开号：EP3032621A1

  公开（公告）日：2016-06-15

  Disclosed is an electrode comprising a polymeric material containing or being composed of subunits according to general formulae (I) and (II) wherein in these structures (I) and (II) n is an integer not smaller than 2, Y represents an amide group (-NH-CO- or -CO-NH-), an ester group (-O-CO- or -CO-O-) or a urethane group (-NH-CO-O- or -O-CO-NH-), R1, R2, R3 and R4 each independently represent H, alkyl (preferably-CH3, -C2H5), alkoxy-(preferably -OCH3, -OC2H5), -halogen or -CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl or aryl group. Further, a Lithium-ion battery and a supercapacitor with such an electrode and the use of said polymeric material as electrode active material in the electrode of a battery or in the electrode of a supercapacitor and/or as an electrode binder is disclosed.

  本发明公开了一种电极，它包含一种聚合物材料，该材料含有或由符合通式 (I) 和 (II) 的亚基组成 其中在这些结构（I）和（II）中，n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或氨基甲酸酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-OCH3、-OC2H5）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基或芳基。此外，还公开了具有这种电极的锂离子电池和超级电容器，以及在电池电极或超级电容器电极中使用所述聚合物材料作为电极活性材料和/或作为电极粘合剂。
• Composite material, electrode, method of producing the material and the electrode and electrochemical cell
  申请人：VARTA Microbattery GmbH

  公开号：US10468715B2

  公开（公告）日：2019-11-05

  A composite material includes an electrochemically active organic material and an electrochemically active inorganic material. The organic material contains subunits according to formulae (I) and/or (II) wherein n is an integer not smaller than 2, Y represents an amide group (—NH—CO— or —CO—NH—), an ester group (—O—CO— or —CO—O—) or a urethane group (—NH—CO—O— or —O—CO—NH—), R1, R2, R3 and R4 each independently represent H, alkyl (preferably —CH3, —C2H5), alkoxy-(preferably —OCH3, —OC2H5), -halogen or —CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl, alkene or aryl group.

  一种复合材料包括电化学活性有机材料和电化学活性无机材料。有机材料含有符合式 (I) 和/或 (II) 的亚基 其中 n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或聚氨酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-OCH3、-OC2H5）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基、烯基或芳基。
• Composition and solution for temporary bonding
  申请人：TAIFLEX Scientific Co., Ltd.

  公开号：US10633569B2

  公开（公告）日：2020-04-28

  A composition and a solution for temporary bonding are provided. The composition includes a dianhydride monomer, a light-absorbing monomer, and a light-absorbing material. The light-absorbing monomer includes at least one of N,N,N,N-(p-aminophenyl)-p-phenylenediamine (TPDA) and N,N-(p-aminophenyl)-p-phenylenediamine (DPDA). The light-absorbing material includes carbon black and silicon dioxide.

  提供了一种用于临时粘合的组合物和溶液。组合物包括二酐单体、光吸收单体和光吸收材料。吸光单体包括 N,N,N,N-（对氨基苯基）-对苯二胺（TPDA）和 N,N-（对氨基苯基）-对苯二胺（DPDA）中的至少一种。吸光材料包括炭黑和二氧化硅。