1,16-diphenyldodeca-1,3,5,7,9,11,13,15-octayne | 20264-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,16-diphenyldodeca-1,3,5,7,9,11,13,15-octayne
• 英文别名: diphenyl-hexadecaoctayne；Diphenyl-hexadecaoctain；Benzene, 1,1'-(1,3,5,7,9,11,13,15-hexadecaoctayne-1,16-diyl)bis-；16-phenylhexadeca-1,3,5,7,9,11,13,15-octaynylbenzene
• CAS: 20264-59-9
• 化学式: C₂₈H₁₀
• 分子量: 346.387
• InChiKey: NBEFBQWEMOSFIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 吡啶 、 氯化亚砜 、 乙醚 作用下， 生成 1,16-diphenyldodeca-1,3,5,7,9,11,13,15-octayne
  参考文献：
  名称：

  Armitage et al., Journal of the Chemical Society, 1954, p. 147,153

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Nonlinear Optical Properties of Diarylpolyynes
  作者：Thanh Luu、Erin Elliott、Aaron D. Slepkov、Sara Eisler、Robert McDonald、Frank A. Hegmann、Rik R. Tykwinski

  DOI：10.1021/ol047931q

  日期：2005.1.1

  A series of alpha,omega-diarylpolyynes has been synthesized. In addition to the synthesis of three hexaynes (3a-c), a notably improved synthesis of 1,16-diphenylhexadecaoctayne (5) is described. The third-order nonlinear optical characteristics for these molecules have been studied and show a substantial increase in molecular hyperpolarizability (gamma) as a function of increasing length. The unusual solid-state structures of compounds 3a and 3b are reported.
• Armitage et al., Journal of the Chemical Society, 1954, p. 147,153
  作者：Armitage et al.

  DOI：——

  日期：——