tris(2,3,4,5-tetramethylphenyl)phosphine | 66417-52-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(2,3,4,5-tetramethylphenyl)phosphine
• 英文别名: tris(tetramethylphenyl)phosphine；Tris(2.3.4.5-tetramethylphenyl)phosphin；Tris(2,3,4,5-tetramethylphenyl)phosphane
• CAS: 66417-52-5
• 化学式: C₃₀H₃₉P
• 分子量: 430.613
• InChiKey: FTBRHZVBDSDPAX-UHFFFAOYSA-N

物化性质

• 沸点：
  558.1±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-溴-2,3,4,5-四甲基苯 生成 tris(2,3,4,5-tetramethylphenyl)phosphine
  参考文献：
  名称：

  Palladium-catalyzed vinylic substitution with highly activated aryl halides

  摘要：

  DOI：

  10.1021/jo00409a001
• 作为试剂：
  描述：

  溴苯 、 反-1,3-戊二烯 在 tris(2,3,4,5-tetramethylphenyl)phosphine 哌啶 作用下， 反应 46.0h， 以38%的产率得到1-[(E)-5-phenylpent-3-en-2-yl]piperidine
  参考文献：
  名称：

  Reactions of .pi.-allylic palladium intermediates with amines

  摘要：

  DOI：

  10.1021/jo01306a009

文献信息

• Phosphonium salts and processes for production of and uses for the same, and phosphines deriving the same and processes for production of the phosphines
  申请人：KURARAY CO. LTD,

  公开号：US20020183196A1

  公开（公告）日：2002-12-05

  Phosphonium salts represented by the general formula (I) 1 wherein R 1 and R 2 each represents a phenyl group which may be substituted by a lower alkyl group, R 3 represents a phenylene group which may be substituted by a lower alkyl group, R 7 and R 8 each represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms which may be substituted and R 9 represents a hydrogen atom or a hydrocarbon group having 1 to 5 carbon atoms which may be substituted; processes for producing the same and uses for the same; phosphines providing the same, and processes for producing said phosphines.

  磷酰盐由通式（I）所代表，其中R1和R2分别代表苯基，可以被较低烷基取代，R3代表苯基，可以被较低烷基取代，R7和R8分别代表氢原子或具有1至12个碳原子的碳氢基团，可以被取代，R9代表氢原子或具有1至5个碳原子的碳氢基团，可以被取代；生产该磷酰盐的过程以及使用该磷酰盐的方法；提供该磷酰盐的磷化物以及生产该磷化物的过程。
• PROCESS FOR PRODUCING ALKADIENOL
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0605735A1

  公开（公告）日：1994-07-13

  A process for producing an alkadienol which comprises reacting a conjugated alkadiene with water in a reaction solvent in the presence of a palladium catalyst, separating the solvent from the resultant reaction mixture by distilling the mixture under the condition wherein the temperature of the bottom oil in a distillation column is 120 °C or below while directly feeding hot water and/or steam as the heat-transfer medium to the column, and subjecting the bottom to phase separation. This process causes neither the decomposition and/or polymerization of the formed alkadienol nor the metallation of the palladium catalyst, and hence serves to inhibit the loss of the alkadienol and the catalyst and provide the objective alkadienol in a high yield.

  一种生产烷二烯醇的工艺，包括在钯催化剂存在下，在反应溶剂中使共轭烷二烯与水反应，在蒸馏塔中底油温度为120℃或以下的条件下，通过蒸馏混合物，将溶剂从生成的反应混合物中分离出来，同时将热水和/或蒸汽作为传热介质直接送入蒸馏塔，并使底部进行相分离。该工艺既不会导致已形成的烷二烯醇分解和/或聚合，也不会导致钯催化剂金属化，因此可抑制烷二烯醇和催化剂的损失，并以高产率提供目标烷二烯醇。
• Anodic behavior of crowded triarylphosphines. ESR study of triarylphosphoniumyl radicals, Ar3P.bul.+
  作者：Marcel Culcasi、Yves Berchadsky、Gerard Gronchi、Paul Tordo

  DOI：10.1021/jo00011a018

  日期：1991.5

  A large number of triarylphosphines exhibiting different steric hindrance has been prepared. The pyramidalization angle alpha of these compounds was calculated with use of the MM2 force field and was shown to depend almost exclusively on the number of ortho substituents on the phenyl rings. In a series of isosteric (same alpha) phosphines, the oxidation potential correlates with the sum of the sigma+ Hammett parameters of the phenyl substituents. In the absence of oxygen, anodic oxidation of all the triarylphosphines bearing two o-methyl substituents on each phenyl ring is reversible and yields very persistent phosphoniumyl radicals. These radicals are easily detected by ESR in liquid solution and were shown to retain a pyramidal geometry that is significantly flattened compared to that of the parent phosphine.
• Phosphorus-containing molecules and processes for production of and uses for the same, and phosphines deriving the same and processes for production of the phosphines
  申请人：Kuraray Co., Ltd.

  公开号：EP1249455B1

  公开（公告）日：2005-02-16
• US5306835A
  申请人：——

  公开号：US5306835A

  公开（公告）日：1994-04-26