tris(cyclohexyl)tin azide | 29045-66-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机叠氮化物
• 英文名称: tris(cyclohexyl)tin azide
• 英文别名: tricyclohexyltin azide；Stannane, azidotricyclohexyl-；azido(tricyclohexyl)stannane
• CAS: 29045-66-7
• 化学式: C₁₈H₃₃N₃Sn
• 分子量: 410.19
• InChiKey: CVUYJEFXYFFMNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.25
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tris(cyclohexyl)tin azide 、 硫代异氰酸苯酯 以43%的产率得到
  参考文献：
  名称：

  BHATTACHARYA S. N.; RAJ P., INDIAN J. CHEM., 1978, A 16, NO 4, 337-339

  摘要：

  DOI：
• 作为产物：
  描述：

  三环己基氯化锡 、 sodium azide 以 丙酮 为溶剂， 生成 tris(cyclohexyl)tin azide
  参考文献：
  名称：

  Further study of tris(cyclohexyl)stannane compounds, Cy3SnX. Syntheses of the compounds with X=Br, I, N3 and NCS and redetermination of the crystal structures of Cy3SnX (X=Br and I)

  摘要：

  Methods of preparation and far IR data are presented for various Cy3SnX compounds. The synthesis of tris(cyclohexyl)tin hydroxide, Cy3SnOH, is also described. Redeterminations of the crystal structures of tris(cyclohexyl)tin bromide and iodide, Cy3SnBr and Cy3SnI, confirm their molecular nature and improve considerably upon the results reported earlier [S. Calogero, P. Ganis, V. Peruzzo, G. Tagliavini, G. Valle, J. Organomet. Chem. 220 (1981) 11] providing, in both cases, lower R-factors and, in particular, a revised estimate of the Sn-I bond length, now 2.7463(6) Angstrom. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.08.001

文献信息

• Further study of tris(cyclohexyl)stannane compounds, Cy3SnX. Syntheses of the compounds with X=Br, I, N3 and NCS and redetermination of the crystal structures of Cy3SnX (X=Br and I)
  作者：R. Alan Howie、Marcelo V.H. Moura、James L. Wardell、Solange M.S.V. Wardell

  DOI：10.1016/j.poly.2004.08.001

  日期：2004.9

  Methods of preparation and far IR data are presented for various Cy3SnX compounds. The synthesis of tris(cyclohexyl)tin hydroxide, Cy3SnOH, is also described. Redeterminations of the crystal structures of tris(cyclohexyl)tin bromide and iodide, Cy3SnBr and Cy3SnI, confirm their molecular nature and improve considerably upon the results reported earlier [S. Calogero, P. Ganis, V. Peruzzo, G. Tagliavini, G. Valle, J. Organomet. Chem. 220 (1981) 11] providing, in both cases, lower R-factors and, in particular, a revised estimate of the Sn-I bond length, now 2.7463(6) Angstrom. (C) 2004 Elsevier Ltd. All rights reserved.
• Awasthi; Bhattacharya; Verma, Journal of the Indian Chemical Society, 1982, vol. 59, # 2, p. 264 - 268
  作者：Awasthi、Bhattacharya、Verma

  DOI：——

  日期：——
• BHATTACHARYA S. N.; RAJ P., INDIAN J. CHEM., 1978, A 16, NO 4, 337-339
  作者：BHATTACHARYA S. N.、 RAJ P.

  DOI：——

  日期：——