N,N’-bis(1H,1H-perfluoropentyl)pyromellitic diimide | 1075706-57-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: N,N’-bis(1H,1H-perfluoropentyl)pyromellitic diimide
• 英文别名: N,N-di(1H,1H-perfluoropentyl)pyromellitic diimide；2,6-Bis(2,2,3,3,4,4,5,5,5-nonafluoropentyl)pyrrolo[3,4-f]isoindole-1,3,5,7-tetrone；2,6-bis(2,2,3,3,4,4,5,5,5-nonafluoropentyl)pyrrolo[3,4-f]isoindole-1,3,5,7-tetrone
• CAS: 1075706-57-8
• 化学式: C₂₀H₆F₁₈N₂O₄
• 分子量: 680.25
• InChiKey: XURPGNBNNARQFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  44
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  22

反应信息

• 作为产物：
  描述：

  1H,1H-全氟戊胺 、 均苯四甲酸二酐 以 N,N-二甲基甲酰胺 为溶剂， 以91%的产率得到N,N’-bis(1H,1H-perfluoropentyl)pyromellitic diimide
  参考文献：
  名称：

  均苯四甲酸二酰亚胺：用于高迁移率 n 沟道晶体管半导体的最少内核

  摘要：

  通过均苯四酸二酐与各种胺之间的一种常规反应，以高产率合成了三种均苯四酸二酰亚胺。由这些均苯四酸二亚胺衍生物制成的薄膜表现出高达 0.079 cm2/(Vs) 的迁移率。此外，n 沟道器件的开/关比高达 1 000 000。

  DOI：

  10.1021/ja805746h

文献信息

• Pyromellitic Diimides: Minimal Cores for High Mobility n-Channel Transistor Semiconductors
  作者：Qingdong Zheng、Jia Huang、Amy Sarjeant、Howard E. Katz

  DOI：10.1021/ja805746h

  日期：2008.11.5

  Three pyromellitic diimides were synthesized in high yields by one conventional reaction between pyromellitic dianhydride and various amines. The films made from these pyromellitic diimides derivatives exhibit a mobility up to 0.079 cm2/(V.s). In addition, the on/off ratios of n-channel devices are as high as 1 000 000.

  通过均苯四酸二酐与各种胺之间的一种常规反应，以高产率合成了三种均苯四酸二酰亚胺。由这些均苯四酸二亚胺衍生物制成的薄膜表现出高达 0.079 cm2/(Vs) 的迁移率。此外，n 沟道器件的开/关比高达 1 000 000。
• [EN] PYROMELLITIC DIIMIDE ORGANIC SEMICONDUCTORS AND DEVICES<br/>[FR] SEMI-CONDUCTEURS ORGANIQUES À BASE DE DIIMIDE PYROMELLITIQUE ET DISPOSITIFS
  申请人：UNIV JOHNS HOPKINS

  公开号：WO2010011658A3

  公开（公告）日：2010-05-14
• PYROMELLITIC DIIMIDE ORGANIC SEMICONDUCTORS AND DEVICES
  申请人：Katz Howard Edan

  公开号：US20110163301A1

  公开（公告）日：2011-07-07

  n-type organic semiconductors have a pyromellitic diimide structure and electronic or electro-optic devices include pyromellitic diimide compounds as organic semiconductors. Specific semiconductors include pyromellitic diimide compounds have sidechains comprising fluorine substituted aliphatic or aromatic moieties linked to the pyromellitic diimide structure by an alkylene or heteroalkylene linking group. An electronic or electro-optic device includes a first electrode, a second electrode space apart from the first electrode, and an organic semiconductor layer arranged between the first and second electrodes. The organic semiconductor layer comprises a pyromellitic diimide compound.
• US8269215B2
  申请人：——

  公开号：US8269215B2

  公开（公告）日：2012-09-18
• Effect of side chain length on film structure and electron mobility of core-unsubstituted pyromellitic diimides and enhanced mobility of the dibrominated core using the optimized side chain
  作者：Ming-Ling Yeh、Szu-Ying Wang、Josué F. Martínez Hardigree、Vitaly Podzorov、Howard E. Katz

  DOI：10.1039/c4tc02611j

  日期：——

  Film structures and mobilities of pyromellitic diimides (PyDIs) were investigated; perfluorobutylmethyl chain on 3,6-dibromo PyDI showed exceptional packing and mobility.

  对吡啶二酰亚胺（PyDIs）的薄膜结构和运动性进行了研究；3,6-二溴PyDI上的全氟丁基甲基链显示出异常的堆积和运动性。