5,8-dihydroxy-9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acid | 61754-78-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 5,8-dihydroxy-9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acid
• 英文别名: 5,8-dihydroxy-9,10-dioxoanthracene-2,3-dicarboxylic acid
• CAS: 61754-78-7
• 化学式: C₁₆H₈O₈
• 分子量: 328.235
• InChiKey: ARGFQSQLOIFFGX-UHFFFAOYSA-N

物化性质

• 沸点：
  714.0±60.0 °C(Predicted)
• 密度：
  1.813±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  149
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  5,8-dimethoxy-9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acid 在 sodium hydroxide 、 盐酸 作用下， 以 水 为溶剂， 生成 5,8-dihydroxy-9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acid
  参考文献：
  名称：

  Tetraanthraquinonoporphyrazines: III. Synthesis and physicochemical properties of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines

  摘要：

  Methods have been developed for the synthesis of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines. The yield of the target products has been improved via complexation with the corresponding methoxy derivatives and subsequent hydrolysis of the methoxy groups. Some physicochemical properties of substituted 9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acids and tetraanthraporphyrazine metal complexes derived therefrom have been studied.

  DOI：

  10.1134/s1070363212100180

文献信息

• Tetraanthraquinonoporphyrazines: III. Synthesis and physicochemical properties of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines
  作者：A. V. Borisov、V. E. Maizlish、G. P. Shaposhnikov、A. B. Korzhenevskii、T. G. Shikova、V. V. Sokolova、O. I. Koifman

  DOI：10.1134/s1070363212100180

  日期：2012.10

  Methods have been developed for the synthesis of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines. The yield of the target products has been improved via complexation with the corresponding methoxy derivatives and subsequent hydrolysis of the methoxy groups. Some physicochemical properties of substituted 9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acids and tetraanthraporphyrazine metal complexes derived therefrom have been studied.