bis-(4-allyloxy-phenyl)-ether | 38479-35-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(4-allyloxy-phenyl)-ether
• 英文别名: Bis-(4-allyloxy-phenyl)-aether；1-Prop-2-enoxy-4-(4-prop-2-enoxyphenoxy)benzene
• CAS: 38479-35-5
• 化学式: C₁₈H₁₈O₃
• 分子量: 282.339
• InChiKey: RVEQMLJXTBMYDK-UHFFFAOYSA-N

物化性质

• 熔点：
  79-80 °C
• 沸点：
  404.6±40.0 °C(Predicted)
• 密度：
  1.068±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis-(4-allyloxy-phenyl)-ether 250.0 ℃ 、2.67 kPa 条件下， 生成 Bis-(4-hydroxy-3-allyl-phenyl)-aether
  参考文献：
  名称：

  氨基烷基苯酚作为抗疟药；简单取代的α-氨基甲酚。

  摘要：

  DOI：

  10.1021/ja01214a008
• 作为产物：
  描述：

  4,4'-二氨基二苯醚 在 potassium carbonate 、 丙酮 作用下， 生成 bis-(4-allyloxy-phenyl)-ether
  参考文献：
  名称：

  氨基烷基苯酚作为抗疟药；简单取代的α-氨基甲酚。

  摘要：

  DOI：

  10.1021/ja01214a008

文献信息

• PROCESS FOR PRODUCING ALLYL-SUBSTITUTED BISPHENOL COMPOUND
  申请人：NICCA CHEMICAL CO., LTD.

  公开号：US20180118672A1

  公开（公告）日：2018-05-03

  The present invention relates to a process for producing an allyl-substituted bisphenol compound including a step of subjecting a diallyl etherified bisphenol compound represented by the following general formula (I) to a thermal rearrangement reaction in the presence of a specific phosphine compound [in the formula, A represents a single bond, —SO 2 —, —S—, —O—, a divalent group represented by the following formula (i-1), or a divalent group represented by —CY 1 Y 2 —(Y 1 and Y 2 each independently represent hydrogen, a linear, branched, or cyclic alkyl group having 6 or less carbon atoms, a phenyl group, or an aralkyl group having 7 or 8 carbon atoms), B 1 and B 2 each independently represent a linear, branched, or cyclic alkyl group having 6 or less carbon atoms, an allyl group, a phenyl group, or an aralkyl group having 7 or 8 carbon atoms, and n 1 and n 2 each independently represent an integer from 0 to 2,

  本发明涉及一种制备烯丙基取代双酚化合物的方法，包括将以下通式（I）表示的双烯丙基化双酚化合物在特定膦化合物存在下进行热重排反应的步骤[在该式中，A表示单键，-SO2-，-S-，-O-，由以下通式（i-1）表示的二价基团，或由-CY1Y2-（其中Y1和Y2各自独立地表示氢，具有6个或更少碳原子的线性、支链或环烷基，苯基或具有7或8个碳原子的芳基烷基），B1和B2各自独立地表示具有6个或更少碳原子的线性、支链或环烷基，烯丙基基团，苯基或具有7或8个碳原子的芳基烷基，n1和n2各自独立地表示0到2的整数]。
• Thermosettable composition
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0441047A2

  公开（公告）日：1991-08-14

  A thermosettable resin composition having a viscosity that decreases during processing temperatures and increases as the temperature is raised to curing temperatures is provided. The composition comprises thermosettable resins and thermoplastic particles that are insoluble in the thermosettable resins at processing temperatures but soluble in the thermosettable resins at curing temperatures. Prepregs prepared from the thermosettable resin composition are also provided.

  本发明提供了一种热固性树脂组合物，其粘度在加工温度下会降低，而在温度升高到固化温度时会升高。该组合物包括热固性树脂和热塑性颗粒，这些颗粒在加工温度下不溶于热固性树脂，但在固化温度下可溶于热固性树脂。此外，还提供了用该热沉树脂组合物制备的预浸料。
• Funke; v. Daniken, Bulletin de la Societe Chimique de France, 1953, p. 457,459
  作者：Funke、v. Daniken

  DOI：——

  日期：——
• JPH01110649A
  申请人：——

  公开号：JPH01110649A

  公开（公告）日：1999-01-19
• CYCLODEXTRIN CONJUGATES
  申请人：Chucholowski Alexander

  公开号：US20100056475A1

  公开（公告）日：2010-03-04

  It has been discovered that the uptake of anionic charged species into cells can be enhanced by noncovalently associating such species with specifically modified forms of cyclodextrin. The invention modified forms of cyclodextrin form well defined stoichiometric complexes with anionic charged molecules. This discovery enables one to produce various compositions containing anionic charged molecules and facilitates methods for enhancing the cellular uptake of double-stranded or hairpin nucleic acid.