1,6-bis(2-benzimidazolyl)-3,4-disulfidohexane | 23107-62-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1,6-bis(2-benzimidazolyl)-3,4-disulfidohexane
• 英文别名: bis(2-ethylenzimidazolyl)disulphide；Bis-(2--aethyl)-disulfid；Bis-[2-(benzimidazolyl-(2))-aethyl]-disulfid；1,6-Bis(benzimidazol-2-yl)-3,4-dithiahexane；2-[2-[2-(1H-benzimidazol-2-yl)ethyldisulfanyl]ethyl]-1H-benzimidazole
• CAS: 23107-62-2
• 化学式: C₁₈H₁₈N₄S₂
• 分子量: 354.5
• InChiKey: KAMYWDMWOFMSDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  108
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,3'-二氢氧啉酸 、 邻苯二胺 在 盐酸 作用下， 以65%的产率得到1,6-bis(2-benzimidazolyl)-3,4-disulfidohexane
  参考文献：
  名称：

  双[micro2-（苯并咪唑-2-基）-2-乙硫基-N，S，S-氯-钯（II）]二聚体[（micro2-CH2CH2NHNCC6H4） PdCl] 2.C2H5OH络合物。

  摘要：

  1,6-双（苯并咪唑-2-基）-3,4-二硫己烷（1）配体及其氯化钯（II）络合物[（micro（2）-SCH（2）CH（2）NHNCC（6） H（4））PdCl]（2）xC（2）H（5）OH（2）已合成并通过光谱方法表征。三斜晶标题化合物（P-1（编号2），a = 879.6（1）pm，b = 984.4（1）pm，c = 1471.8（2）pm;α= 94.330（6）度，的晶体结构，根据X射线单晶衍射数据求出β= 98.546（6）度，γ= 99.258（7）度，Z = 2）。在双核络合物中，每个钯原子在一个略微扭曲的方平面结构中由一个氮，两个桥联硫和一个末端氯原子配位。记录了配合物（2）的摩尔电导率，FT-拉曼光谱，FT-IR（中红外，远红外），（1）H和（13）C NMR光谱，并显示出与正方形平面良好的一致性。几何学。使用圆盘扩散法在二甲基亚砜（DMSO）中以及最小抑制浓度（MI

  DOI：

  10.1016/j.ejmech.2007.01.011

文献信息

• RUBBER COMPOSITION, AND PNEUMATIC TIRE USING SAME
  申请人：YUKIMURA Noriaki

  公开号：US20150353657A1

  公开（公告）日：2015-12-10

  The invention provides a rubber composition prepared by mixing, per 100 parts by mass of the rubber component comprising at least 50% by mass of a diene-based rubber, from 20 to 150 parts by mass of a filler, and from 0.05 to 30 parts by mass of a compound A which has a specific amidine structure and has a functional group reactive with the diene-based rubber. The rubber composition improves both a high elastic modulus and a low tan δ. The invention also provides a pneumatic tire using the rubber composition.

  本发明提供了一种橡胶组合物，其通过混合制备而成，每100质量部的橡胶组分中包括至少50质量部的二烯基橡胶、从20到150质量部的填料和从0.05到30质量部的化合物A，化合物A具有特定的酰胺结构并具有与二烯基橡胶反应的功能基团。该橡胶组合物提高了高弹性模量和低tanδ。本发明还提供了一种使用该橡胶组合物的充气轮胎。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Das; Mathur, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2001, vol. 40, # 7, p. 768 - 771
  作者：Das、Mathur

  DOI：——

  日期：——
• NON-TOXIC CORROSION PROTECTION PIGMENTS BASED ON COBALT
  申请人：UNIVERSITY OF DAYTON

  公开号：EP1472319A1

  公开（公告）日：2004-11-03