2,3:11,12-bis<4',4''-benzoylbenzo>-18-crown-6 | 67722-80-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3:11,12-bis<4',4''-benzoylbenzo>-18-crown-6
• 英文别名: 2,3:11,12-bis[4',4''-benzoylbenzo]-18-crown-6；6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecine-2,13-diylbis(phenylmethanone)；(24-benzoyl-2,5,8,15,18,21-hexaoxatricyclo[20.4.0.09,14]hexacosa-1(22),9(14),10,12,23,25-hexaen-11-yl)-phenylmethanone
• CAS: 67722-80-9
• 化学式: C₃₄H₃₂O₈
• mdl: MFCD00189266
• 分子量: 568.623
• InChiKey: HWXRXWOHIJRWCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  42
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,3:11,12-bis<4',4''-benzoylbenzo>-18-crown-6 、 对甲苯磺酰肼 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Crown ether carbenes and methods of use

  摘要：

  The invention provides a material comprising (i) a crown ether of formula (I), (ii) a crown ether of formula (II), and/or (iii) a crown ether of formula (III), or a salt thereof, wherein each m independently is an integer from 1 to 8, p is an integer from 1 to 1000, each “ ” designates an optionally present bond and/or structure, each X is an optionally present substituent, each * independently represents —H, ═O, or a bond to a remainder of the material, provided that at least one * is a bond to the remainder of the material, and wherein the remainder of the material is bound via a sp3-sp3 carbon-carbon bond, a method of making the material, and a method of using the material.

  公开号：

  US11905269B1
• 作为产物：
  描述：

  二苯并-18-冠醚-6 、 苯甲酸 在 Eaton's reagent 作用下， 以92 %的产率得到2,3:11,12-bis<4',4''-benzoylbenzo>-18-crown-6
  参考文献：
  名称：

  Crown ether carbenes and methods of use

  摘要：

  The invention provides a material comprising (i) a crown ether of formula (I), (ii) a crown ether of formula (II), and/or (iii) a crown ether of formula (III), or a salt thereof, wherein each m independently is an integer from 1 to 8, p is an integer from 1 to 1000, each “ ” designates an optionally present bond and/or structure, each X is an optionally present substituent, each * independently represents —H, ═O, or a bond to a remainder of the material, provided that at least one * is a bond to the remainder of the material, and wherein the remainder of the material is bound via a sp3-sp3 carbon-carbon bond, a method of making the material, and a method of using the material.

  公开号：

  US11905269B1

文献信息

• Modified crown ether catalysts. 2. Synthesis of alkanoyl-, aroyl-, .alpha.-hydroxyalkyl- and alkylbenzo and alkylcyclohexano crown ethers
  作者：Paul E. Stott、Jerald S. Bradshaw、W. Wesley Parish、James W. Cooper

  DOI：10.1021/jo01311a033

  日期：1980.11
• STOTT P. E.; BRADSHAW J. S.; PARISH W. W.; COPPER J. W., J. ORG. CHEM., 1980, 45, NO 23, 4716-4720
  作者：STOTT P. E.、 BRADSHAW J. S.、 PARISH W. W.、 COPPER J. W.

  DOI：——

  日期：——
• SHELTON J. I.; BRADSHAW J. S.; POTTER M. L.; BENNION D. N., VESTN. SLOVEN. KEM. DRUS., 33,(1986) N 3, 259-269
  作者：SHELTON J. I.、 BRADSHAW J. S.、 POTTER M. L.、 BENNION D. N.

  DOI：——

  日期：——
• JIAO, TIANQUAN;ZHANG, BOJUN;XU, NANPING;TAN, GANZU, J. LANZHOU UNIV., 23,(1987) N 4, 81-85
  作者：JIAO, TIANQUAN、ZHANG, BOJUN、XU, NANPING、TAN, GANZU

  DOI：——

  日期：——
• PARISH W. W.; STOTT P. E.; MCCAUSLAND C. W.; BRADSHAW J. S., J. ORG. CHEM., 1978, 43, NO 24, 4577-4581
  作者：PARISH W. W.、 STOTT P. E.、 MCCAUSLAND C. W.、 BRADSHAW J. S.

  DOI：——

  日期：——