3-(3-溴苯基)荧蒽 | 1233141-68-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 3-(3-溴苯基)荧蒽
• 英文名称: 3-(3-bromophenyl)fluoranthene
• CAS: 1233141-68-8
• 化学式: C₂₂H₁₃Br
• 分子量: 357.249
• InChiKey: MNJMBVHRXXIFSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9'-苯基-2,3'-联咔唑 、 3-(3-溴苯基)荧蒽 在 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 、 tri tert-butylphosphoniumtetrafluoroborate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 8.0h， 以73%的产率得到3-[9-(3-Fluoranthen-3-ylphenyl)carbazol-2-yl]-9-phenylcarbazole
  参考文献：
  名称：

  BISCARBAZOLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

  摘要：

  公开号：

  EP2674418B1
• 作为产物：
  描述：

  荧蒽-3-硼酸 、 1-溴-3-碘苯 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 10.0h， 以89%的产率得到3-(3-溴苯基)荧蒽
  参考文献：
  名称：

  BISCARBAZOLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

  摘要：

  公开号：

  EP2674418B1

文献信息

• [EN] NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICES CONTAINING THEM<br/>[FR] COMPOSÉS HÉTÉROCYCLIQUES AZOTÉS ET DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES CONTENANT CEUX-CI
  申请人：IDEMITSU KOSAN CO

  公开号：WO2017109722A1

  公开（公告）日：2017-06-29

  The present invention relates to compounds of the general formula (11), to a material for an organic electroluminescence device comprising ot least one of these compounds, to an organic electroluminescence device comprising at least one of these compounds, and to the use of a compound according to general formula (11) in an organic electroluminescence device as a host material or an electron transporting material.

  本发明涉及通式（11）的化合物，涉及包含至少其中一种化合物的有机电致发光器件材料，涉及包含至少其中一种化合物的有机电致发光器件，以及涉及将通式（11）的化合物用作有机电致发光器件中的主体材料或电子传输材料。
• [EN] ELECTRONIC DEVICE INCLUDING A FLUORANTHENE DERIVATIVE<br/>[FR] DISPOSITIF ÉLECTRONIQUE COMPRENANT UN DÉRIVÉ DE FLUORANTHÈNE
  申请人：DU PONT

  公开号：WO2015061074A1

  公开（公告）日：2015-04-30

  There is provided a compound having Formula I In Formula I: R1 - R10 are the same or different and are H, D, alkyl, silyl, aryl, deuterated alkyl, deuterated silyl, or deuterated aryl, where no more than two of R1 - R10 are biphenyl and where at least two of R1 - R10 have Formula II In Formula II: Ar is phenyl, naphthyl, heteroaryl, spirofluorenyl, or a deuterated analog thereof; R11 is the same or different at each occurrence and is D, alkyl, silyl, aryl, deuterated alkyl, deuterated silyl, or deuterated aryl, where adjacent R11 groups can join to form a fused aromatic ring or fused deuterated aromatic ring; m is an integer from 0-4; n is an integer from 1-5; and the asterisk represents a point of attachment.

  提供一种具有化学式I的化合物，在化学式I中：R1-R10相同或不同，可以是H、D、烷基、硅基、芳基、重氘代烷基、重氘代硅基或重氘代芳基，其中R1-R10中不超过两个是联苯基，并且至少两个具有化学式II，在化学式II中：Ar是苯基、萘基、杂环芳基、螺芴基或其重氘类似物；R11在每次出现时相同或不同，可以是D、烷基、硅基、芳基、重氘代烷基、重氘代硅基或重氘代芳基，相邻的R11基团可以连接形成融合芳香环或融合重氘芳香环；m是0-4的整数；n是1-5的整数；星号代表一个连接点。
• ORGANIC LIGHT EMITTING DEVICE AND COMPOUNDS FOR USE IN SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US20200227652A1

  公开（公告）日：2020-07-16

  Specific polycyclic compounds of the general formula (I) and a process for its preparation, an electronic device comprising at least one of these compounds, an emitting layer, preferably present in an electronic device, comprising at least one compound of general formula (I) and the use of compounds according to general formula (I) in an electronic device as a host material, a charge transporting material, charge and/or exciton blocking material, preferably as a host material or an electron transporting material.

  本发明涉及一种通式（I）的特定多环化合物及其制备方法，包括至少一种这些化合物的电子器件，包括至少一种通式（I）的化合物的发射层，通常存在于电子器件中，以化合物通式（I）在电子器件中作为主体材料、电荷传输材料、电荷和/或激子阻挡材料的用途，通常作为主体材料或电子传输材料。
• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2018151470A1

  公开（公告）日：2018-08-23

  The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound according to the present disclosure is contained in an electron transport layer and/or an electron buffer layer, so that an organic electroluminescent device having improved light-emitting efficiency can be manufactured.

  本公开涉及一种有机电致发光化合物及包括该化合物的有机电致发光装置。根据本公开的有机电致发光化合物包含在电子传输层和/或电子缓冲层中，从而可以制造出具有改善发光效率的有机电致发光装置。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Kawamura Yuichiro

  公开号：US20120153268A1

  公开（公告）日：2012-06-21

  An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “E T b >E T h ” (where, E T h is the triplet energy of the host material, and E T b is the triplet energy of the barrier material).

  一种有机电致发光器件包括阳极、发光层、电子传输区和阴极，阳极、发光层、电子传输区和阴极依次堆叠，发光层包括主体材料和发射荧光的掺杂材料，其主峰波长为550nm或更低，电子传输区包括邻近发光层的阻挡层，该阻挡层包括具有电子传输结构部分和包括融合的多环芳香族碳化合物的三重态阻挡结构部分的阻挡材料，并满足“ETb>ETh”的关系（其中，ETh是主体材料的三重态能量，而ETb是阻挡材料的三重态能量）。