-4-((2-(diphenylphosphanyl)benzylidene)amino)phenol | 476629-71-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: -4-((2-(diphenylphosphanyl)benzylidene)amino)phenol
• 英文别名: Phenol, 4-[[[2-(diphenylphosphino)phenyl]methylene]amino]-；4-[(2-diphenylphosphanylphenyl)methylideneamino]phenol
• CAS: 476629-71-7
• 化学式: C₂₅H₂₀NOP
• 分子量: 381.414
• InChiKey: CPUCJVBXJKLUSD-UHFFFAOYSA-N

物化性质

• 沸点：
  555.1±35.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  -4-((2-(diphenylphosphanyl)benzylidene)amino)phenol 、 O,O-bis(4-((2-(dichlorophosphorothioyl)-2-methylhydrazineylidene)methyl)phenyl) ((4-((E)-2-(diethoxyphosphoryl)vinyl)phenyl)diphenyl-l5-phosphaneylidene)phosphoramidothioate 在 CsCO₃ 作用下， 以 四氢呋喃 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  磷基树突的合成及核和表面反应性

  摘要：

  从独特的前体 (EtO)2P(O)CH=CHC6H4PPh2 (3-G0) 开始合成了一系列含磷树枝，其 X 射线晶体结构显示两种磷之间的扩展平面性。与膦基上官能化叠氮化物的施陶丁格反应是树突生长的第一步，使用发散方法继续进行。几种类型的反应在多种尺寸的树枝上进行，无论是在核心水平还是在表面水平。在核心水平将三氟甲磺酸甲酯特别添加到 P=S 和三甲基甲硅烷基三氟甲磺酸酯到 P=O，提供了双阳离子物质。13C NMR 光谱研究表明电荷离域的程度。磷烷接枝在第二代树突的表面，用于络合 PdCl2。这两种化合物都具有五种不同类型的磷原子，这有助于通过 31P NMR 光谱对其进行表征。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200400016
• 作为产物：
  描述：

  2-二苯基膦苯甲醛 、 对氨基苯酚 以 乙醇 为溶剂， 生成 -4-((2-(diphenylphosphanyl)benzylidene)amino)phenol
  参考文献：
  名称：

  Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions

  摘要：

  The specific functionalization of hexachlorocyclotriphosphazene with one function different from the five others was used for the synthesis of bifunctional dendrimers having one protected amine linked to the core and either 5 phosphines or 10 phosphine imines (P,N ligands) as terminal groups. In the latter case, reaction with PdCl2(COD) affords the corresponding complexes of the P, N ligands. All compounds were characterized by multinuclear NMR, and particularly by P-31 NMR, which proved to be a very precious tool for the characterization of sophisticated structures such as dendrimers. (C) 2013 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.05.021

文献信息

• Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions
  作者：Mar Tristany、Régis Laurent、Hanna Dib、Luca Gonsalvi、Maurizio Peruzzini、Jean-Pierre Majoral、Anne-Marie Caminade

  DOI：10.1016/j.ica.2013.05.021

  日期：2014.1

  The specific functionalization of hexachlorocyclotriphosphazene with one function different from the five others was used for the synthesis of bifunctional dendrimers having one protected amine linked to the core and either 5 phosphines or 10 phosphine imines (P,N ligands) as terminal groups. In the latter case, reaction with PdCl2(COD) affords the corresponding complexes of the P, N ligands. All compounds were characterized by multinuclear NMR, and particularly by P-31 NMR, which proved to be a very precious tool for the characterization of sophisticated structures such as dendrimers. (C) 2013 Elsevier B. V. All rights reserved.
• Synthesis and Core and Surface Reactivity of Phosphorus‐Based Dendrons
  作者：Rosa‐María Sebastián、Laurent Griffe、Cédric‐Olivier Turrin、Bruno Donnadieu、Anne‐Marie Caminade、Jean‐Pierre Majoral

  DOI：10.1002/ejic.200400016

  日期：2004.6

  phosphorus-containing dendrons is synthesized starting from a unique precursor (EtO)2P(O)CH=CHC6H4PPh2 (3-G0), whose X-ray crystal structure shows an extended planarity between both phosphorus. Staudinger reactions with functionalized azides on the phosphino group are the first step for the growth of the dendrons, which is continued using a divergent method. Several types of reactions are performed on dendrons of

  从独特的前体 (EtO)2P(O)CH=CHC6H4PPh2 (3-G0) 开始合成了一系列含磷树枝，其 X 射线晶体结构显示两种磷之间的扩展平面性。与膦基上官能化叠氮化物的施陶丁格反应是树突生长的第一步，使用发散方法继续进行。几种类型的反应在多种尺寸的树枝上进行，无论是在核心水平还是在表面水平。在核心水平将三氟甲磺酸甲酯特别添加到 P=S 和三甲基甲硅烷基三氟甲磺酸酯到 P=O，提供了双阳离子物质。13C NMR 光谱研究表明电荷离域的程度。磷烷接枝在第二代树突的表面，用于络合 PdCl2。这两种化合物都具有五种不同类型的磷原子，这有助于通过 31P NMR 光谱对其进行表征。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)