benzyltrimethylammonium bicarbonate | 72872-47-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyltrimethylammonium bicarbonate
• 英文别名: trimethylbenzylammonium hydrogencarbonate；benzyl-trimethyl-ammonium bicarbonate；benzyl(trimethyl)azanium;hydron;carbonate
• CAS: 72872-47-0
• 化学式: CHO₃*C₁₀H₁₆N
• 分子量: 211.261
• InChiKey: FYFYNZWCZYQKDI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.78
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  60.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二苄基碳酸盐[脂] 在 三甲胺 作用下， 以 甲醇 、 水 为溶剂， 生成 benzyltrimethylammonium bicarbonate
  参考文献：
  名称：

  Process for producing a high purity quaternary ammonium hydroxide

  摘要：

  公开号：

  EP0269949B1
• 作为试剂：
  描述：

  methylammonium carbonate 、 环氧氯丙烷 在 benzyltrimethylammonium bicarbonate 作用下， 120.0~150.0 ℃ 、4.9 MPa 条件下， 生成 4-(氯甲基)-1,3-二氧戊环-2-酮
  参考文献：
  名称：

  Catalytic process for producing alkylene carbonates

  摘要：

  公开号：

  US02873282A1

文献信息

• CROSSLINKABLE COMPOSITION CROSSLINKABLE WITH A LATENT BASE CATALYST
  申请人：Brinkhuis Richard Hendrikus Gerrit

  公开号：US20130041091A1

  公开（公告）日：2013-02-14

  The present invention relates to a crosslinkable composition comprising at least one crosslinkable component crosslinkable by a latent base crosslinking catalyst comprising a substituted carbonate salt according to formula 1 wherein X + represents a cation and wherein R is hydrogen, alkyl, aryl or aralkyl group, and wherein the crosslinkable composition comprises 0.1-10 wt %, preferably 0.1-5, more preferably 0.2-3 and most preferably 0.5-1.5 wt % water (relative to total weight of the crosslinkable composition). The invention further relates to a coating composition comprising the crosslinkable composition according to the invention, a novel catalyst composition and to the use of said catalyst composition according to the invention as a latent base crosslinking catalyst in coating compositions, preferably in RMA crosslinkable compositions.

  本发明涉及一种交联组合物，其包括至少一种可交联组分，可由一种潜在碱交联催化剂交联，该交联催化剂包括根据式1的取代碳酸盐，其中X+代表阳离子，R为氢、烷基、芳基或芳基烷基，且所述交联组合物包括0.1-10重量％，优选0.1-5，更优选0.2-3，最优选0.5-1.5重量％的水（相对于交联组合物的总重量）。本发明还涉及一种包括根据本发明的交联组合物的涂料组合物，一种新型催化剂组合物以及所述催化剂组合物的使用作为潜在碱交联催化剂在涂料组合物中的用途，优选在RMA可交联组合物中。
• [EN] PIPERIDINE COMPOUNDS USEFUL AS MALONYL-COA DECARBOXYLASE INHIBITORS<br/>[FR] COMPOSES DE PIPERIDINE UTILES EN TANT QU'INHIBITEURS DE MALONYL-COA DECARBOXYLASE
  申请人：CHUGAI PHARMACEUTICAL CO LTD

  公开号：WO2005011693A1

  公开（公告）日：2005-02-10

  The present invention provides methods for the use of compounds as depicted by structure (I), pharmaceutical compositions containing the same, and methods for the prophylaxis, management and treatment of metabolic diseases and diseases modulated by MCID inhibition. The compounds disclosed in this invention are useful for the prophylaxis, management and treatment of diseases involving in malonyl-CoA regulated glucose/fatty acid metabolism pathway. In particular, these compounds and pharmaceutical composition containing the same are indicated in the prophylaxis, management and treatment of cardiovascular diseases, diabetes, cancer and obesity.

  本发明提供了使用结构式(I)所示的化合物的方法，包括含有该化合物的药物组成物，以及预防、管理和治疗代谢性疾病和受MCID抑制调节的疾病的方法。本发明中所披露的化合物对于预防、管理和治疗涉及丙酰辅酶A调节的葡萄糖/脂肪酸代谢途径的疾病是有用的。特别地，这些化合物和含有它们的药物组成物适用于预防、管理和治疗心血管疾病、糖尿病、癌症和肥胖症。
• Process for production of quaternary ammonium hydroxides
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US04776929A1

  公开（公告）日：1988-10-11

  A process for production of high purity quarternary ammonium hydroxides, comprising electrolyzing quarternary ammonium hydrogencarbonates represented by the general formula: ##STR1## (wherein the symbols are as defined in the appended claims) in an electrolytic cell comprising an anode compartment and a cathode compartment defined by a cation exchange membrane. In accordance with this process, high purity quarternary ammonium hydroxides can be produced with high electrolytic efficiency and further without causing corrosion of equipment. Since the quarternary ammonium hydroxides produced by the present invention are of high purity, they can be effectively used as, for example, cleaners, etchants or developers for wafers in the production of IC and LSI in the field of electronics and semiconductors.

  一种生产高纯度季铵羟化物的方法，包括在一个电解池中电解表示为通式的季铵氢碳酸盐：##STR1##（其中符号如附加权利要求中所定义），该电解池包括由阳离子交换膜定义的阳极室和阴极室。按照该方法，可以高效地生产高纯度的季铵羟化物，而且不会引起设备腐蚀。由于本发明生产的季铵羟化物具有高纯度，因此可以有效地用作电子和半导体领域中生产集成电路和大规模集成电路中晶片的清洁剂、蚀刻剂或显影剂。
• Crosslinkable composition crosslinkable with a latent base catalyst
  申请人：Brinkhuis Richard Hendrikus Gerrit

  公开号：US09181452B2

  公开（公告）日：2015-11-10

  The present invention relates to a crosslinkable composition comprising at least one crosslinkable component and a latent base crosslinking catalyst, which crosslinkable composition has a solids content of typically at least 55 wt (dry weight after crosslinking relative to the total weight of the crosslinking composition) wherein the latent base catalyst is a substituted carbonate salt according to formula 1 wherein X+represents a non acidic cation, preferably a quaternary ammonium or phosphonium, and wherein R is hydrogen, alkyl, aryl or aralkyl group.

  本发明涉及一种可交联组合物，包括至少一种可交联组分和一种潜在的碱性交联催化剂，该可交联组合物的固体含量通常至少为55重量％（交联后的干重相对于交联组合物总重量），其中潜在的碱性催化剂是根据式1的取代碳酸盐所表示的，其中X+表示非酸性阳离子，优选为季铵或膦铵，而R是氢，烷基，芳基或芳烷基。
• Process for the manufacture of alkylene carbonates
  申请人：Montedison S.p.A.

  公开号：EP0004942A1

  公开（公告）日：1979-10-31

  A new process is disclosed for the synthesis of alkylene carbonates having from 2 to 4 carbon atoms in the chain, starting from a corresponding halohydrin having the formula: wherein R., Rb, Rc and Rd are independently hydrogen or alkyl, aryl, alkylaryl or arylalkyl radicals and where X is a halogen, characterized in that said halohydrin is reacted with a bicarbonate of a quaternary -onium compound, where "-onium" means ammonium, phosphonium, arsonium or stibonium, preferably using an organic solvent as diluent and operating in the presence of carbon dioxide.

  本发明公开了一种新工艺，以相应的卤代醇为起始原料，合成链中含有 2 至 4 个碳原子的碳酸亚烷基酯，卤代醇的式为 其中 R.、Rb、Rc 和 Rd 独立地为氢或烷基、芳基、烷芳基或芳基烷基，X 为卤素，其特征在于所述卤代醇与季铵盐化合物的碳酸氢盐反应，其中 "铵 "指铵、鏻、胂或锑，最好使用有机溶剂作为稀释剂，并在二氧化碳存在下进行操作。