6-{4-[4,6-bis(4-biphenylyl)-1,3,5-triazin-2-yl]phenyl}-2,2'-bipyridyl | 927898-52-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6-{4-[4,6-bis(4-biphenylyl)-1,3,5-triazin-2-yl]phenyl}-2,2'-bipyridyl
• 英文别名: 2,4-bis(4-phenylphenyl)-6-[4-(6-pyridin-2-ylpyridin-2-yl)phenyl]-1,3,5-triazine
• CAS: 927898-52-0
• 化学式: C₄₃H₂₉N₅
• 分子量: 615.737
• InChiKey: VRARHCCYTLUZKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  48
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  64.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  6-溴-2,2'-联吡啶 、 2,4-二(4-联苯基)-6-(4-溴苯基)-1,3,5-三嗪 在 四(三苯基膦)钯 正丁基锂 、 二氯(N,N,N',N'-四甲基乙二胺)锌(II) 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 6.42h， 以67%的产率得到6-{4-[4,6-bis(4-biphenylyl)-1,3,5-triazin-2-yl]phenyl}-2,2'-bipyridyl
  参考文献：
  名称：

  1,3,5-TRIAZINE DERIVATIVE, METHOD FOR PRODUCING SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE CONTAINING SAME AS COMPONENT

  摘要：

  公开号：

  EP1930329B1

文献信息

• 1,3,5-TRIAZINE DERIVATIVE, PRODUCTION METHOD THEREOF AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THIS AS A COMPOSING COMPONENT
  申请人：Yamakawa Tetsu

  公开号：US20090281311A1

  公开（公告）日：2009-11-12

  Since the conventional electron transporters have low thermal stability, the organic electroluminescent devices using them are not sufficient in terms of the compatibility of their luminance and luminous efficiency with device lifetime. A 1,3,5-triazine derivative of formula (1) is obtained by a metal catalyst-aided coupling reaction of a compound of formula (2) with a compound of formula (3), and this is used as a composing component of an organic electroluminescent device. [In the formulae, Ar 1 and Ar 2 represent phenyl group or the like, R 1 and R 2 represent hydrogen atom or the like, R 3 represents methyl or the like, m is an integer of 0 to 2, X represents 2,4-pyridylene or the like, p is 1 or 2, a and b are 1 or 2, a+b is 3, q is 0 or an integer of p or less, M represents —MgR 4 group or the like, R 4 represents chlorine atom or the like, r is p-q, and Y represents a leaving group.]

  由于传统的电子传输体具有低热稳定性，使用它们的有机电致发光器件在亮度和发光效率与器件寿命的兼容性方面不足。通过化合物（2）和化合物（3）的金属催化偶联反应获得式（1）的1,3,5-三嗪衍生物，并将其用作有机电致发光器件的组成部分。[在公式中，Ar1和Ar2代表苯基或类似基团，R1和R2代表氢原子或类似原子团，R3代表甲基或类似基团，m为0至2的整数，X代表2,4-吡啶基或类似基团，p为1或2，a和b为1或2，a+b为3，q为0或小于等于p的整数，M代表-MgR4基团或类似基团，R4代表氯原子或类似原子团，r为p-q，Y代表离去基团。]
• 1,3,5-triazine derivative, production method thereof and organic electroluminescence device comprising this as a composing component
  申请人：Tosoh Corporation

  公开号：US07994316B2

  公开（公告）日：2011-08-09

  Since the conventional electron transporters have low thermal stability, the organic electroluminescent devices using them are not sufficient in terms of the compatibility of their luminance and luminous efficiency with device lifetime. A 1,3,5-triazine derivative of formula (1) is obtained by a metal catalyst-aided coupling reaction of a compound of formula (2) with a compound of formula (3), and this is used as a composing component of an organic electroluminescent device. [In the formulae, Ar1 and Ar2 represent phenyl group or the like, R1 and R2 represent hydrogen atom or the like, R3 represents methyl or the like, m is an integer of 0 to 2, X represents 2,4-pyridylene or the like, p is 1 or 2, a and b are 1 or 2, a+b is 3, q is 0 or an integer of p or less, M represents —MgR4 group or the like, R4 represents chlorine atom or the like, r is p-q, and Y represents a leaving group.]

  由于传统的电子传输体的热稳定性较低，使用它们的有机电致发光器件在亮度和发光效率与器件寿命的兼容性方面不足。式（1）的1,3,5-三嗪衍生物是通过式（2）的化合物与式（3）的化合物的金属催化偶联反应获得的，并用作有机电致发光器件的组成部分。【在式中，Ar1和Ar2代表苯基或类似基团，R1和R2代表氢原子或类似基团，R3代表甲基或类似基团，m是0到2的整数，X代表2,4-吡啶基或类似基团，p是1或2，a和b为1或2，a+b为3，q为0或小于等于p的整数，M代表—MgR4基团或类似基团，R4代表氯原子或类似基团，r为p-q，Y代表离去基团。】
• US7994316B2
  申请人：——

  公开号：US7994316B2

  公开（公告）日：2011-08-09
• 1,3,5-TRIAZINE DERIVATIVE, METHOD FOR PRODUCING SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE CONTAINING SAME AS COMPONENT
  申请人：TOSOH CORPORATION

  公开号：EP1930329B1

  公开（公告）日：2012-10-24