申请人:Baker Hughes Holdings LLC
公开号:US11124692B2
公开(公告)日:2021-09-21
Methods of treating a petroleum hydrocarbon fluid are described wherein the petroleum hydrocarbon fluid is contacted with an asphaltene inhibitor composition having an ionic liquid and an asphaltene inhibitor. The ionic liquid has a cation of R1R2R3R4N+ or R1R2R3N+R8N+R5R6R7 and an anion, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, a straight or branched C1-30 alkyl group, benzyl, a C7-30 alkylbenzyl group, a C7-30 arylalkyl group, a straight or branched C3-30 alkenyl group, a C1-30 hydroxyalkyl group, a C7-30 hydroxyalkylbenzyl group, an oxyalkylene or a polyoxyalkylene group or a zwitterion; R8 is a straight or branched C1-30 alkylene, an alkylene oxyalkylene or an alkylene polyoxyalkylene; and the anion includes halides, hydroxyl, bicarbonate, carbonate, alkyl carbonates, alkoxides, carboxylates, hydroxycarboxylates or a combination thereof.
本发明描述了一种处理石油烃流体的方法,其中将石油烃流体与含有离子液体和沥青质抑制剂的沥青质抑制剂组合物接触。所述离子液体具有阳离子和阴离子,阳离子为R1R2R3R4N+或R1R2R3N+R8N+R5R6R7,阴离子为以下基团中的一种或多种:卤素阴离子、羟基、碳酸氢根、碳酸根、烷基碳酸盐、烷氧基、羧酸盐、羟基羧酸盐或其组合。其中,R1、R2、R3、R4、R5、R6和R7各自独立地选自氢、直链或支链C1-30烷基、苄基、C7-30烷基苯甲基、C7-30芳基烷基、直链或支链C3-30烯基、C1-30羟基烷基、C7-30羟基烷基苯甲基、氧亚烷基、聚氧亚烷基或双性离子;R8为直链或支链C1-30亚烷基、亚烷基氧亚烷基或亚烷基聚氧亚烷基。